ZIONSOLUTIONSLLC

ZIONSOLUTIONSLLC
An Emr
dtloSfl Company
April 28, 2014
ZS-2014-0100
U.S. Nuclear Regulatory Commission
ATTN: Document Control Desk
Washington, DC 20555-0001
Zion Nuclear Power Station, Units I and 2
Facility Operating License Nos. DPR-39 and DPR-48
NRC Docket Nos. 50-295, 50-304 and 72-1037
Subject:
Radioactive Effluent Release Report, Radioactive Effluent Control Program Report,
Offsite Dose Calculation Manual and Process Control Program for 2013.
In accordance with Facility Operation License Nos. DPR-39 and DPR-48, Appendix A,
Technical Specification 5.7.3, "Radioactive Effluent Release Report," for Zion Nuclear Power
Station, Units 1 and 2, this is the submittal of a Radioactive Effluent Release Report for the year
2013. The report is required to be submitted prior to May 1, 2014 and is provided as
Attachments 1 through 6 to this letter. A listing of commitments contained in this submittal is
provided in Attachment 1. Certificate of Compliance No. 1031 for the MAGNASTOR
SYSTEM, Appendix A, Technical Specifications 5.1.1 and 5.1.3 require submittal of an Annual
Radioactive Effluent Control Program report which is included in this document.
Pursuant to 10 CFR 50.4 and Technical Specification 5.6.1 .c. there were changes made to the
Zion Station Offsite Dose Calculation Manual (ODCM) during the period of January through
December 2013. Attachment 1, Supplemental Information, summarizes the changes made to the
ODCM during the calendar year of 2013. Attachment 7 is a copy of Zion Station ODCM, current
as of December 31, 2013.
There are no new regulatory commitments in this submittal.
If you have any questions about this submittal please contact Mr. Christopher Keene at
(224)789-4073.
Respectfully,
VP Operations & Engineering & Decommissioning Plant Manager
ZionSolutions, LLC
A 00
101 Shiloh Boulevard, Zion - IL60099
(224) 789-4016 • Fax: (224) 789-4008 • www.zionsolutionscompany.com
ZionSolutions, LLC
ZS-2014-0 100
Page 2 of 2
Attachments:
1. Supplemental Information
2. Effluent & Waste Disposal Summary
2.1. Unit 1 Gaseous Effluent
2.2. Unit 2 Gaseous Effluent
2.3. Liquid Effluent
2.4. Direct Radiation
2.5. LLIYs
2.6. Error Estimation
3. Solid Waste and Irradiated Fuel Shipments
4. Radiological Impact on Man
4.1. 40CFR190 & 1OCFR72 Compliance summary
4.2. Unit 1
4.3. Unit 2
4.4. ISFSI
4.5. Combined 40CFR190 report
5. Meteorology Data
6. Errata Data from previous years
7. Zion Station ODCM
8. ZS-WM-123 Process Control Program Requirements
cc: John Hickman, U.S. NRC Senior Project Manager
Service List
Zion Nuclear Power Station, Unit 1 and 2 License Transfer Service List
cc:
Alan Parker
President Projects Group
EnergySolutions
1009 Commerce Park Drive, Ste. 100
Oak Ridge, TN 37830
Russ Workman
General Counsel
EnergySolutions
423 West 300 South, Ste. 200
Salt Lake City, UT 84101
John Sauger
Senior VP & General Manager
ZionSolutions, LLC
101 Shiloh Boulevard
Zion, IL 60099
Alwyn C. Settles
Section Head, Nuclear Facility Inspection
Bureau of Nuclear Facility Safety
Illinois Emergency Management Agency
1011 North St., PO Box 250
Mazon, IL 60444
Gary Bouchard
VP Ops, Engineering, and
Decommissioning Plant Manager
ZionSolutions, LLC
101 Shiloh Boulevard
Zion, IL 60099
Gerard van Noordenmen
VP Regulatory Affairs
ZionSolutions, LLC
101 Shiloh Boulevard
Zion, IL 60099
Dan Shrum
Senior VP Regulatory Affairs
EnergySolutions
423 West 300 South, Ste. 200
Salt Lake City, UT 84101
Kent McKenzie
Emergency Management Coordinator
Lake County Emergency Management Agency
1303 N. Milwaukee Avenue
Libertyville, IL 60048-1308
Regional Administrator
U.S. NRC, Region III
2443 Warrenville Road
Lisle, IL 60532-4352
John E. Matthews
Morgan, Lewis & Bockius LLP
1111 Pennsylvania Avenue, NW
Washington, DC 20004
ZionSolutions LLC
ZS-2014-0100: Attachment I - Supplemental Information
1. Regulatory Limits: The dose to a member of the public fi'om direct radiation, liquid and
gaseous effluents released friom each unit to areas at or beyond site boundary shall be
limited to the following:
a. Fission and Activation products:
i. Tech Spec Whole Body:
500 norero/year
ii. Tech Spec Skin:
3000 morem/year
b. Particulates with half-lives > 8 days, tritium and Iodine:
i. Tech Spec Organ:
1500 orero/year
ii. 1OCFR50 Organ:
7.5 mrem/quarter, 15 mrem/year
c. Liquid Effluents:
i. IOCFR50 Whole body:
1.5 mrem/quarter, 3 mrem/year
ii. IOCFR50 Organ:
5 torem/quarter. 10 torem/year
d. Combined dose to real individual beyond controlled area:
i. 10CFR72 Whole body:
25 torem/year
ii. IOCFR72 Thyroid:
75 mrem/year
iii. 1OCFR72 Organ:
25 mrem/year
2.
Effluent Concentration Limits (ECL): Limits used in determining allowable release rates
or concentrations.
a. Gaseous Effluents: I OCFR20 Appendix B Table 2 Column 1.
b. Liquid Effluents: 10 X IOCFR20 Appendix B Table 2 Column 2.
3. Measurements and Approximations of Total Radioactivity.
a. Fission and Activation Products: 100% Kr-85 is assumed in calculations since
other isotopes have decayed. Vent stack activity is continuously monitored for
fission and activation gases.
b. Particulate and tritium releases are continuously monitored and samples collected
and analyzed weekly. Particulate filters are sent to an independent lab for
quarterly composite analysis. Tritium activity is monitored in gaseous releases
from evaporation of water in the spent fuel pool and water filled reactor cavities.
c. Liquid effluents are continuously monitored and isotopic analysis performed
weekly.
d. Occupancy factors to accurately estimate dose due to habits of the real individual
that are used to calculate maximum exposed member of the public are discussed
in ES&H Technical Support Document 13-009 "Member of the Public Dose from
All Onsite Sources."
4. Batch Releases:
a. Liquid: There were no liquid batch releases in 2013.
b. Gaseous: There were no gaseous batch releases in 2013.
5. Abnormal Releases:
a. Liquid: There were no liquid abnormal releases in 2013.
b. Gaseous: there were no gaseous abnormal releases in 2013.
ZionSolutions LLC
ZS-2014-01 00: Attachment I - Supplemental Information
6. Gaseous and Liquid Waste Treatment Systems and Process Control Program
Zion Station ODCM Section 12.7.2 pursuant to ODCM Section 12.7.4 requires major
changes to the Gaseous and Liquid Waste Treatment Systems to be reported in the
Annual Radioactive Effluent Release Report. There are major changes ongoing with the
physical configuration of the liquid radwaste system. along with associated DSAR and
ODCM descriptive changes; however the changes were not completed and further
revisions were being evaluated as of Dec. 3 1, 2013; therefore the completed change
package will be submitted in the reporting year during which the change was complete.
Zion Station ODCM Section 12.6.2 requires major changes to the Process Control
Program(PCP) to be submitted in the Annual Radioactive Effluent Release Report. There
were no major changes to the PCP.
The Waste Gas Hold-up System was permanently vented. In Zion's defueled
configuration this system is no longer applicable.
In Zion's defueled configuration, the charcoal iodine removal system is no longer
applicable.
Due to radioactive decay and no means of production, radioactive iodine is not a concern
at Zion.
7. Limiting Conditions of Operation (LCOs)
Zion Station ODCM Section 12.7.2 requires explanation as to why the inoperability of
liquid or gaseous monitoring instrumentation was not corrected within the time specified
in the ODCM to be submitted with the Annual Radioactive Effluent Release Report.
There are no such occurrences.
8. Liquid Holdup Tanks and Gas Storage Tanks
Zion Station ODCM Section 12.7.2 requires a description of events leading to liquid
holdup tanks or gas storage tanks exceeding technical specification limits to be included
in the Annual Radioactive Effluent Release Report.
The contents of the six gas decay tanks have been sampled and determined to have
negligible activity. The Gas Decay Tanks have been abandoned in place.
No liquid holdup tanks exceeded the limits of Permanently Defueled Technical
Specifications 5.6.3 during 2013.
9. Offsite Dose Calculation Manual (ODCM)
Changes to the ODCM are required by Zion Station Permanently Defueled Technical
Specification 5.6. 1. and ODCM Section 12.6.3 to be submitted as part of, or concurrent
with, the Annual Radioactive Effluent Release Report.
ZionSolutions LLC
ZS-2014-0100: Attachment I - Supplemental Information
A summary of changes made to the ODCM during 2013 and an entire copy of tile
ODCM, current as of December 31, 2013 are required to be submitted.
Revisions to ODCM and Process Control Program are listed below:
a. ODCM Revisions:
Chapter
10
Section
10.2.1
Description
Grammatical change
10
10.2.1 .1
10
10.2.1.2
10
10.2.2.1
10
10.2.3.1
10
10
II
12
I1
II
10.2.3.2.1
10.2.4
Table I I-I.b
Table 12.5-1.b
Table I-I .2.b
Table I I-1.2.c & II1.2.d
II
Figure I1-1
11
12
12
Figure I l-lb.
Table 12.5-1
Table 12.3-2.A &
12.3-2.B
Table 12.4-1.C &
12.4- 1.D
Renamed Boric Acid Monitor Tank to Lake Release Tank;
There are 2 Lake Release tanks in the new system each with a
nominal capacity of 35,000 gallons.
Added section: The existing Holdup Tanks are added as the
dedicated location to receive and store unprocessed liquid
waste.
Revised the discussion of monitoring releases. The new
radiation monitor OR-PRO4 monitors the release from the Lake
Release tank that is discharging. Previously, the radiation
monitor was located in the AB at the 542' elevation and the
isolation valve was approximately 250 feet downstream of the
radiation monitor which provided a margin of time for the
monitor to process an alarm and close the valve prior to the
release entering the discharge canal. This was necessary due to
the discharge line connecting to the discharge canal
downstream of the dilution flow stream. As such, any water
thatentered the canal would be released to the lake with the
dilution flow such that when the release is terminated, that
water is stagnant in the canal and does not enter into the
dilution stream.
Changed "condenser cooling" water to "service" water.
Renamed Boric Acid Monitor Tank to Lake Release Tank.
Renamed Boric Acid Monitor Tank to Lake Release Tank
Renamed Boric Acid Monitor Tank to Lake Release Tank.
Section b. added to include new control air sample location
Section b. added to include new control air sample location
Added control TLD location
Added sections c. and d. To include TLD's placed for ISFSI
background trending. Added section to re-establish 5 mile ring
REMP TLD's.
Renamed to figure I 1-la. and updated with new REMP
monitoring locations
Figure added to show5 mile ring TLD placement locations
Updated table for new TLD locations.
Removed Sr-89 from analysis, added Ni-63
12
Removed Sr-89 friom analysis, added Ni-63
ZionSolutions LLC
ZS-2014-0100: Attachment 1 - Supplemental Information
Chapter
12
12
Section
Table 12.4-1 Note c.
Table 12.2-1. .A
12
12
12
10 r 15
12
Table 12.2- 1. I.A. 1
Table 12.2-1.3.A
Table 12.2-1.3.B &
12.2-1.3.B. I
Table 12.2-2. I.A &
12.2-2. I.A. 1
Table 12.2-2.3.A
12.2-2.3.b & 12.22.3.b. 1
Table 12.3-2.1 .A
Table 12.2-4.3.A.4
Table 12.2-4 Note 3
Table 12.2-3.3.A.4
Table 12.2-3
Surveillance 13
Table 10-2
Table 12.2-3.3.A.2
App.
App.
App.
App.
App.
App.
A.0
A.4
A.4.1.2)
A.5.1 .1
A.5.1.2
A.5.2
12
12
12
12
12
12
12
12
A
A
A
A
A
A
App. A
A.5.2
App. A
A.5.3
App. A
App. A
12
App. A
Table A-I
Table A-4
Table 12.2-4
Section A.5.3
12
12
Table 12.2-1
Table 12.2-2
Description
Removed Sr-89 from analysis, added Ni-63
Renamed Boric Acid Monitor Tanks (BAMT) to Lake Release
Tanks.
Changed OR-PRO5 to OR-PRO4
Renamed Boric Acid Monitor Tank to Lake Release Tank #1
Added Item 3.B and 3.B.1I Lake Release tank #2 is monitored
for flow from new flow meter OFI-WD-006
Renamed Boric Acid Monitor Tank to Lake Release Tank.
Renamed Boric Acid Monitor Tank to Lake Release Tank #1
Lake Release Tank #2 is monitored for flow from new flow
meter OFI-WD006
Renamed Boric Acid Monitor Tank to Lake Release Tank.
Added Item A.4 to include 0RT-AR24
Changed note to include ORT-AR24
Added section 4 to include ORT-AR24
Deleted surveillance 13 subsections 1-4 and added surveillance
for ORT-AR24
Corrected inadvertently changed table from previous revision.
Surveillance requirement of 0RT-AR22 changed from 14 to 12
to match ORT-AR21.
Added instance of I OCFR72
Added several instances of IOCFR72"
Added *ISFSI" to clarify contained sources
Added requirements for Zion to comply with I OCFR72
Added instance of"IOCFR72"
Added instance of IOCFR72.104 and added "ISFSI" to
example of sources
Added instance of I OCFR72 to compliance assessment
requirements
Added ISFSI direct dose contribution in compliance
methodology, provided references to ISFSI NAC dose
calculation for methodology, added reference to TSD#1 3-002
for occupancy factor determinations and additional regulatory
requirements of IOCFR72 as additional regulations requiring
compliance.
Added IOCFR72 to Compliance matrix.
Added IOCFR72.104(a) dose limit requirements.
Changed ORT-AR24 Channel function chest to Q
Paragraphs l&3: Changed wording referring to TSD#13-002
to: TSD 13-008 "Evaluation of Independent Spent Fuel
Storage Installation and Associated Process Dose Rates" and
TSD 13-009 "Member of the Public Dose from All Onsite
sources"
Added item 4.A Dilution flow instrument OFIT-SW54
Item 3.A. I Changed "channel calibration to include sensor
ZionSolutions LLC
ZS-2014-0100: Attachment I - Supplemnental Information
Chapter
12
12
12
Section
12.2-2
12.2-2
12.2-I
Chapter
II
12
11
II
Section
Table 1I-1 .b
Table 12.5-I .b
Table 11-1.2.b
Table I I-1.2.c & I11.2.d
II
Figure I I-1
II
12
12
Figure I1-I b.
Table 12.5-1
Table 12.3-2.A &
12.3-2.B
Table 12.4-1.C &
12.4- 1.D
Table 12.4-1 Note c.
Table 12.2-1. I .A
12
12
12
12
12
12
10 r 15
12
Table 12.2-1 I.A.1
Table 12.2-1.3.A
Table 12.2-1.3.B &
12.2-1.3.B. I
Table 12.2-2. I.A &
12.2-2.1 .A. 1
Table 12.2-2.3.A
12.2-2.3.b & 12.22.3.b. I
Table 12.3-2. .A
Table 12.2-4.3.A.4
Table 12.2-4 Note 3
Table 12.2-3.3.A.4
Table 12.2-3
Surveillance 13
Table 10-2
Table 12.2-3.3.A.2
App.
App.
App.
App.
App.
A.0
A.4
A.4.1.2)
A.5.1.1
A.5.1.2
12
12
12
12
12
12
12
12
A
A
A
A
A
Description
Item 3.B.1 Changed "channel calibration" to include sensor
Added Item 4.A OFIT-SW54 dilution flowrate instrument.
Modified surveillance 1. Added Plant Manager Approval
required for all releases without a rad monitor.
Description
Section b. added to include new control air sample location
Section b. added to include new control air sample location
Added control TLD location
Added sections c. and d. To include TLD's placed for ISFSI
background trending. Added section to re-establish 5 mile ring
REMP TLD's.
Renamed to figure 1 I -Ia. and updated with new REMP
monitoring locations
Figure added to show 5 mile ring TLD placement locations
Updated table for new TLD locations.
Removed Sr-89 from analysis, added Ni-63
Removed Sr-89 from analysis, added Ni-63
Removed Sr-89 from analysis, added Ni-63
Renamed Boric Acid Monitor Tanks (BAMT) to Lake Release
Tanks.
Changed OR-PRO5 to OR-PRO4
Renamed Boric Acid Monitor Tank to Lake Release Tank #I
Added Item 3.B and 3.B. I Lake Release Tank #2 is monitored
for flow from new flow meter OFI-WD-006
Renamed Boric Acid Monitor Tank to Lake Release Tank.
Renamed Boric Acid Monitor Tank to Lake Release Tank # I
Lake Release Tank #2 is monitored for flow from new flow
meter OFI-WD006
Renamed Boric Acid Monitor Tank to Lake Release Tank.
Added Item A.4 to include ORT-AR24
Changed note to include ORT-AR24
Added section 4 to include ORT-AR24
Deleted surveillance 13 subsections 1-4 and added surveillance
for ORT-AR24
Corrected inadvertently changed table from previous revision.
Surveillance requirement of ORT-AR22 changed from 14 to 12
to match ORT-AR2 1.
Added instance of IOCFR72
Added several instances of"IOCFR72"
Added "ISFSI" to clarify contained sources
Added requirements for Zion to comply with IOCFR72
Added instance of"IOCFR72"'
ZionSolutions LLC
ZS-2014-01 00: Attachment I - Supplemental Information
Chapter
App. A
Section
A.5.2
App. A
A.5.2
App. A
A.5.3
App. A
App. A
12
App. A
Table A-I
Table A-4
Table 12.2-4
Section A.5.3
12
12
12
12
12
Table 12.2-1
Table 12.2-2
12.2-2
12.2-2
12.2-1
Description
Added instance of IOCFR72.104 and added "ISFSI" to
example of sources
Added instance of 1OCFR72 to compliance assessment
requirements
Added ISFSI direct dose contribution in compliance
methodology, provided references to ISFSI NAC dose
calculation for methodology, added reference to TSD# 13-002
for occupancy factor determinations and additional regulatory
requiremnents of IOCFR72 as additional regulations requiring
compliance.
Added 10CFR72 to Compliance matrix.
Added IOCFR72.104(a) dose limit requirements.
Changed ORT-AR24 Channel function chest to Q
Paragraphs 1&3: Changed wording referring to TSD 13-002
to: TSD 13-008 "Evaluation of Independent Spent.uel
Storage Installation and Associated Process Dose Rates" and
TSD 13-009 "Meemberof the Public Dose from All Onsite
sources"
Added item 4.A Dilution flow instrument OFIT-SW54
Item 3.A. I Changed "channel calibration to include sensor
Item 3.B. 1 Changed "channel calibration" to include sensor
Added Item 4.A OFIT-SW54 dilution flowrate instrument.
Modified surveillance 1. Added plant Manager Approval
required for all releases without a rad monitor.
b. Process Control Program (PCP) ZS-WM-123 Revisions:
Section
3.8
4.2.1.7
5.10
Attachment 3
Section 2.0
Attachment 3
Section 3.0
Section
3.8
4.2.1.7
5.10
Attachment 3
Section 2.0
Attachment 3
Section 3.0
Description of change
Definition of Process Control Program revised for clarity and to match Reg.
guide 1.21 rev.1
Revised notation to references
Revised Reference
Bead ion exchange resin dewatering criteria wording revised.
Miscellaneous metals and irradiated hardware dewatering criteria wording
revised.
Description of change
Definition of Process Control Program revised for clarity and to match Reg.
guide 1.21 rev.l
Revised notation to references
Revised Reference
Bead ion exchange resin dewatering criteria wording revised.
Miscellaneous metals and irradiated hardware dewatering criteria wording
revised.
ZionSolutions, LLC
ZS-2014-0100: Attachment 2- Effluent & Waste Disposal Summary
Attachment 2.1 - Unit I Gaseous Releases
GASEOUS EFFLUENTS -
SUMMATION OF ALL RELEASES
Unit 1 Vent Stack
QTR 1
QTR 2
QTR 3
QTR 4
YEAR
Fission and Activation Gases
Ci
1. Total Release
uCi/sec
2. Avg. Release Rate
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
Iodine-131
1. Total Release
2. Avg. Release Rate
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
Particulates Half Life >= 8 days
<LLD
Ci
1. Total Release
uCi/sec <LLD
2. Avg. Release Rate
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
Tritium
1. Total Release
2. Avg. Release Rate
6.5OE-03
0.00E+00
7.50E-03
9.10E-03
3.25E-02
0.OOE+00
0.00E+00
0.00E+00
YEAR
Units
REPORT FOR 2013
GASEOUS EFFLUENTS
-
REPORT FOR 2013
Ci
uCi/sec
Ci
uCi/sec
9.35E-03.
0.D0E+00
GROUND RELEASES
Units
-
CONTINUOUS
QTR 1
Fission and Activation Gases
<LLD
<LLD
Iodines
Particulates Half Life >= 8 days<LLD
MODE
QTR 2
QTR 3
QTR
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
4
<LLD
<LLD
Tritium
H-3
Ci
9.35E-03
6.50E-03
7. SE-03
9. 10E-03
3.25E-02
Totals for Period
Ci
9.35E-03
6.50E-03
7. 50E-03
9. lOE-03
3. 25E-02
QTR 3
QTR 4
YEAR
GASEOUS EFFLUENTS
REPORT FOR 2013
-
GROUND RELEASES
Units
-
QTR 1
No Batch Releases.
LLD values are listed on attachment
2.5
BATCH MODE
QTR 2
ZionSohittions. LLC
ZS-2014-0100: Attachment 2- Effluent & Waste Disposal Summary
Attachment 2.2 - Unit 2 Gaseous Releases
GASEOUS EFFLUENTS -
SUMMATION OF ALL RELEASES
Unit 2 Vent Stack
QTR 1
QTR 2
QTR 3
QTR 4
YEAR
Fission and Activation Gases
Ci
1. Total Release
uCi/sec
Avg. Release Rate
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
Iodine-131
1. Total Release
2. Avg. Release Rate
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
Particulates Half Life >= 8 days
<LLD
Ci
1. Total Release
<LLD
uCi/sec
2. Avg. Release Rate
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
Tritium
1. Total Release
2. Avg. Release Rate
6.50E-03
0.OOE-i00
7.50E-03
0.OOE+00
9.10E-03
0.OOE+00
3.25E-02
0.OOE+D0
QTR 4
YEAR
REPORT FOR 2013
GASEOUS
EFFLUENTS -
REPORT FOR 2013
Units
Ci
uCi/sec
Ci
uCi/sec
9.35E-03
).OOE+00
GROUND RELEASES
Units
CONTINUOUS MODE
-
QTR 1
QTR 2
QTR
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
6.50E-03
7.50E-03
9. lOE-03
3. 25E-02
Ci
9.35E-03
6.50E-03
Totals for Period
GASEOUS EFFLUENTS - GROUND RELEASES - BATCH MODE
7. 50E-03
9. IOE-03
3.25E-02
QTR 3
QTR 4
YEAR
Fission and Activation Gases
<LLD
Iodines
<LLD
Particulates Half Life >= 8 days<LLD
Tritium
H-3
REPORT FOR 2013
Ci
Units
9.35E-03
QTR 1
No Batch Releases.
LLD values are listed
on attachment 2.5
QTR 2
3
ZionSolutions, LLC
ZS-2014-01 00: Attachment 2- Effluent & Waste Disposal Summary
Attachment 2.3 - Liquid Effluent Releases
LIQUID EFFLUENTS -
SUMMATION OF ALL RELEASES
QTR 1
QTR 2
QTR 3
QTR 4
YEAR
Fission and Activation Gases
1. Total Release
Ci
2. Avg. Release Rate
uCi/sec
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
Iodine-131
1. Total Release
2. Avg. Release Rate
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
Particulates Half Life >= 8 days
Ci
<LLD
1. Total Release
uCi/sec <LLD
2. Avg. Release Rate
<LLD
<LLD
<LLD
<LLD
REPORT FOR 2013
Units
Ci
uCi/sec
Volume of liquid waste gallons
Volume of dil.
water
gallons
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
<LLD
8.91E+05
9.50E+05
7.09E+05
6.27E+05
3.18E+06
3.24E+08
3.28E+08
3.31E+08
3.31E+08
1.31E+09
LIQUID EFFLUENTS - BATCH MODE
REPORT FOR 2013
Units
QTR 1
No batch releases.
LLD values are listed
in
attachment 2.5
QTR 2
QTR 3
QTR 4
YEAR
ZionSohitions, LLC
ZS-2014-0100: Attachment 2- Effluent & Waste Disposal Summary
Attachment 2.4-Direct Radiation
Unit
Unit i
Unit 2
ISFSI
Qtr I
dose(rnrero)
2.34E+00
2.34E+00
O.OOE+00
Qtr 2
cdose(mremn)
0.OOE+00
O.OOE+00
0.OOE+00
Qtr 3
dose(rnrem)
O.OOE+00
O.OOE+00
0.OOE+00
Qtr 4
dose(mrem)
0.OOE+00
0.OOE+00
0.OOE+00
2013 annual
dose(mrern)
2.34E+00
2.34E+00
0.OOE+00
ZionSohltions, LLC
ZS-2014-0100: Attachment 2- Effluent & Waste Disposal Sumnmnary
Attachment 2.5-LLD's
Various detectors were used on different counting platforms for the gaseous and liquid weekly
effluent samples. The lower limit of detection(LLD) accompanies each counted sample and is
verified to meet the following maximum LLD's:
A. Liquid
Sample frequency
Type of analysis
Weekly/prior to each release
Principal Gamma Emitters:
Dissolved and Entrained
Gases
Tritium
Gross Alpha
Sr-90
Monthly composite
Quarterly composite
Lower Limit of Detection
(LLD) uCi/mL
<5.OOE-07
< 1.00E-05
<I .OOE-05
<l.OOE-07
5.OOE-08
Fe-55, Ni-63
1.OOE-06
Sample frequency
Type of analysis
Continuous/daily/weekly
Continuous
Monthly
Principle gamma emitters
Noble gas
Noble Gas / Principle gamma
emitters
Tritium
Sr-90
Lower Limit of Detection
(LLD) uCi/mL
<1 .OOE-i I
< .OOE-06
<1.OOE-04
B. Gaseous
Quarterly composite
1.OOE-06
<1.OOE-l I
Fe-55
Ni-63
<3.OOE- II
<I.OOE- I1
Gross Alpha
<1.OOE-1 I
ZionSolutions, LLC
ZS-2014-0100: Attachment 2- Effluent & Waste Disposal Summary
Attachment 2.6-Error Estimation
Estimates of Total Error
The following is a calculated estimate of the maximum potential total error associated
with reported values in the Annual Radioactive Effluent Release Report. The Total Error
is determined by calculating the square root of the sum of the squares of the individual
errors.
a.
Gaseous Effluents
Sampling Error
Calibration Error
Counting Statistics Error
5%
10%
17%
Total Error
23%
Ssninle Vcinhrn FErrnr
b.
10%
Liquid Effluents
Sampling Error
Calibration Error
Counting Statistics Error
Sample Volume Error
Total Error
5%
10%
16%
2%
20%
ZionSolutions. LLC
ZS-2014-0100: Attachment 3- Solid Waste and Irradiated Fuel Shipments
A. Solid Waste Shipped Offsite for Burial or Disposal (Not irradiated fuel)
1. Types of Waste
Types of Waste
a.
Spent resins, filter sludges,
evaporator bottoms, etc.
b. Dry compressible waste.
contaminated equip, etc.
c. Irradiated components, control
rods, etc.
d. Other (describe)
Est. Total
Total
Quantity
(m 3)
3.78E+02
2.26E+01
2013
2.50E+01
90'E+04
l.38E+0
2013
2.50E+0l
4.40E+03
1.73E+03
2013
2.50E+0I
0.OOE+00
O.O0E+00
2013
0.OOE+00
Total
Activity
Period
(Ci)
Error %
ZionSolutions. LLC
ZS-2014-0100: Attachment 3- Solid Waste and Irradiated Fuel Shipments
2.
Estimate of major nuclide composition (by waste type)
Major Nuclide
Composition
Waste Type a.
Resins, sludges
bottoms (%)
Waste Type b.
DAW
contaminated
equipment (%)
Waste Type d.
Irradiated
components (%)
Waste Type d.
Other %
Ag-I 1i0m
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
Am-241
1.20E-03
5.48E-02
O.OOE+00
O.OOE+00
C- 14
1.93E-02
1.47E-01
4.97E-02
O.OOE+00
Ce- 144
5.20E-03
3.07E-0 I
O.OOE+00
O.OOE+00
Cm-242
O.OOE+00
3.OOE-04
O.OOE+00
O.OOE+00
Cm-243
5.OOE-04
1.81 E-02
O.OOE+00
O.OOE+00
Cm-244
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
Co-60
1.51E+O1
3.53 E+OI
5.80E+O1
O.OOE+00
Cs- 134
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
Cs-137
3.42E+00
2.28E+0 I
5.30E-03
O.OOE+00
Fe-55
9.28E-02
1.77E+OI
8.67E+00
O.OOE+00
H-3
5.OOE-03
3.44E-01
1.20E-0I
O.OOE+00
1-129
4.OOE-04
1.25E-02
O.OOE+00
O.OOE+00
Mn-54
O.OOE+00
3.80E-02
2.80E-03
O.OOE+00
Nb-94
2.40E-02
6.69E-02
1.00E-03
O.OOE+00
Ni-59
1.01E+00
4.51E-0I
3.03E-01
O.OOE+00
Ni-63
8.OOE+O1
2.16E+OI
O.OOE+00
O.OOE+00
Ni-63am
O.OOE+00
O.OOE+00
3.28 E+O I
O.OOE+00
Np-237
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
Pu-238
6.OOE-04
5.37E-02
O.OOE+00
O.OOE+00
Pu-239
3.OOE-04
1.73E-02
O.OOE+00
O.OOE+00
Pu-240
O.OOE+00
0.00E+00
O.OOE+00
O.OOE+00
Pu-241
1.41E-01
1.70E-0I
2.OOE-04
O.OOE+00
Pu-242
O.OOE+00
8.OOE-04
O.OOE+00
O.00E+00
Ra-226
O.OOE+00
O.OOE+00
7.OOE-04
O.OOE+00
Sb-125
3.68E-02
2.43E-0I
3.OOE-04
O.OOE+00
Sr-89
8.90E-03
8.24E-02
O.OOE+00
O.OOE+00
Sr-90
I. II E-0 I
2.09E-0 I
1.00E-04
O.OOE+00
Tc-99
4.60E-03
2.03 E-01
I.OOE-04
O.OOE+00
Zn-65
5.58E-02
2.01E-0I
O.OOE+00
O.OOE+00
ZionSolutions, LLC
ZS-2014-0100: Attachment 3- Solid Waste and Irradiated Fuel Shipments
3. Solid Waste Disposition
Number of Shipments
10
22
I
Mode of Transportation
Truck
Rail
Truck
Destination
Clive CWF
Clive BWF
WCS
B. Irradiated Fuel Shipments (disposition)
Number of Shipments
0
Mode of Transportation
N/A
Destination
N/A
C. Changes to the Process Control Program:
Changes to the PCP are included in Attachment I along with changes to the ODCM.
I
ZionSolttions, LLC
ZS-2014-0100: Attachment 4- Radiological Impact on Man
Attachment 4.1 -40CFRI90 & IOCRF72 Compliance Summary
UNIT 1, 2 & ISFSI (DOCKET Numbers 50-295, 50-304 & 72-1037)
EXECUTIVE SUMMARY
A review of 2013 effluent data indicates that the activity released from the station was far below
any regulatory limit. There was no noble gas released in 2013. This trend can be attributed to the
shutdown of both units since late September 1997.
Airborne
Gamma Air
Beta Air
Total Body
Skin
Organ
Dose to Maximally
Exposed Receptor fi'om
Unit I
0.OOE+00 mrad
0.OOE+00 mrad
0.OOE+00 nirem
0.OOE+00 mrem
8.25E-05 mrem (Child
Liver)
Dose to Maximally
Exposed Receptor from
Unit 2
0.00E+00 mrad
0.OOE+00 mrad
0.00E+00 mrem
0.OOEE+00 mrem
8.25E-05 mrem (Child
Liver)
Aquatic
There was NO Aquatic release of radioactivity from Zion Station for 2013.
Total Body
Organ
Dose to Maximally
Exposed Receptor (Any)
from Unit I
0 mrem
0 mrem
Dose to Maximally
Exposed Receptor (Any)
from Unit 2
0 mrem
0 mrem
Direct Radiation
Dose to Maximally
Exposed Member of the
public from Unit I
Total Body
2.34E+00mrem
Dose to Maximally
Exposed Member of the
public from Unit 2
2.34E+00mrem
Dose to
Maximally
Exposed Member
of the public from
ISFSI
0.00E+00mrem
ZionSolutions. LLC
ZS-2014-0100: Attachment 4- Radiological Impact on Man
Attachment 4.2 - Unit I
I.
Unit I (Docket Number 50-295)
A. 10 CFR20 & 40CFRI90 Compliance Assessment: The demonstration of compliance
with 40CFR 190 will be used to demonstrate compliance with IOCFR20.
1.
2.
3.
4.
5.
6.
Total Effective Dose Equivalent
40 CFR 190 Whole body limit
40 CFR 190 Max exposed organ
% Whole body limit
% Max exposed organ
TEDE
2.34+00 torero/year
25 mrem/year
25 mrem (75 nirem thyroid)
9.36E+00%
9.36E+00% child liver (3.12E+00% thyroid)
Quarter I
Quarter 2
Quarter 3
Quarter 4
Total
2.34E+00
imll
rex poe R
1.65E-05
reetr
1.91 E-05
mrem
4.63E-05
mrem
2.34E+00
rnrern
B. Maximally Exposed Receptor:
I. Airborne
Gamma air (mrad)
Beta Air (mrad)
Total Bodv (mnrem)
Skin imrem)
Organ lmrem)
Qtr Obi
I" Qtr
2 ,,d
5.0
10.0
7.5
7.5
7.5
0.OOE+00
O.00E+00
2 38E-05
0 00E+00
3" Qtr
4'• Qtr
2.38E-05
0.00E+00
0.00E+00
1.65E-05
0.00E+00
1.65E-05
0 (i0E+00
O.00E+00
1.91E-05
0.i00E+00
1.91E-05
0.(iE+00
0.00E+i00
4.63E-05
0.00E+00
4.,3E-05
Child liver
Child liver
Child liver
Child liver
Qtr Obi
I" Qtr
2"' Qtr
3O Qtr
4" Qtr
2.5
2.5
O.0(E+00
0.OOE+00
NA
(l.0IE+0(i
(lOOE+00
NA
0.00E+001
(i.00E+tV{}
NA
0.00E+00
0.00E+00
NA
3' Qr
4dQtr
Critical Organ
Qtr
Yearly limit
IOCFR 50
App. 1
10.0
20.0
15.0
15.0
15.0
2(113
20p1
% of
Yearly
limit
O.00E+00
O.OOE+00
8.25E-05
0 0(F+00+1
8.25E-05
Child liver
0.00E+00
O.OOE+00
5.50E-06
0.OOE+00
5 50E-06
Child
2. Aquatic
Total Body (mireml
Organ (mi1relnl
Critical Organ
Yearly limit
10CFR 50
Total Dose
3.0.
10(0
0.0E+00
% of
Yearl,
Y
limit
App. I
j(OE+G0
NA
O.OOE+0 }
0.00E+00
NA
3. Direct
OiJtr I" Qtr
Total body (mremr
6.25
2.34E+
Qir
G.OOF--E+00 ).OE+00
IF
l 0.0(E+(10
Ialy
4 eary
limit
Total Dose
22013
% of
Yearly
limit
25 V
2.34E+i1
9.36E-02
ZionSolutions. LLC
ZS-20 14-0100: Attachment 4- Radiological Impact on Man
Attachment 4.3 - Unit 2
II. Unit 2 (Docket Number 50-304)
A. 10 CFR20 & 40CFR190 Compliance Assessment: The demonstration of compliance
with 40CFRI90 will be used to demonstrate compliance with IOCFR20.
1. Total Effective Dose Equivalent
2. 40 CFR 190 Whole body limit
3. 40 CFR 190 Max exposed organ
4. % Whole body limit
5. % Max exposed organ
TEDE
2.34E+00 mrem/year
25 mrem/year
25 mrem (75 mrem thyroid)
9.36E+00%
9.36E+00% child liver (3.12E+00% thyroid)
Quarter I
Quarter 2
Quarter 3
Quarter 4
Total
2.34E+00
mrem
1.65E-05
mrem
1.9 iE-05
m re11i
4.63E-05
mrem
2.34E+00
mnrem
B. Maximally Exposed Receptor:
1. Airborne
Gamma air (mrad)
Beta Air (mrad)
Total Body (mremn
Skin (tmremr)
Organ (mrem)
Critical Organ
Qtr Obi
I" Qtr
2'' Qtr
50
10.(0
75
7.5
7.5
0.OOE+O0
0.00E+00
2.38E-05
0 00E++00
2.38E-05
Child liver
0.00E+00
0.00E+00
1.65F-05
3'' Qtr
4h QIr
______
Yearly limit
I OCFR 50
App.l I
0.00E+00
O.00El00
1.91E-05
.00E±0('
0.E
.OE+-ioo
1.65E-05
1.91E-05
Child liver
Child liver
0.00E+00
0.0OE+00
4.63E-05
0.)O-E+10
4.63E-05
Child liver
4' Qtr
I OCFR 50
App. I
10.0(.00E+00
20.0
150
15.0
15.0
___
_
Total
2013 Dose
%
mof
limit
early
0.OOE+00
8.25E-05
0 00E+00
8.25E-05
Child liver
O.00E+00
(i.OOE+-00
5.50E-06
( ()OE+0-()
5.50E-06
Child liver
2. Aquatic
Total Body (itoern)
Organ Imrem)
Critical Orian
I" Qtr
Qtr rYearly
Qtr
3
2.5
2.5
0 OOE+00
0.OF+00Et
NA
0.00E+00
O.O(Fi00
NA
O.OO0E+
0.O.E+O0
NA
0.00E+00
010FE+00
NA
30
10.0
0 OOE+00
E
O0.OOE+IO
0.OOE+00
0.00E+00
NA
NA
3 d'
I.
Qt
4' QtrI
Yearly limit
Qtr Ob
Total Dose
2013
O.OOE+O0
25.C0.E00
3. Direct
Tlotal body, i nrem )
limit
Qtr Obj
oil
r1 625
I
"Qtr
0
2.34E+00
2
'
tr
__2__t_3__
I
IO.00E+O00
d
Otr
t
O.OOE+ )O
Total Dose
2013
% of
Yearly
limit
[40C
% of
e19l.
lim it
O.OOE+00.0.E+I
ZionSolutions, LLC
ZS-2014-0 100: Attachment 4- Radiological Impact on Man
Attachment 4.4 - ISFSI
Ill. ISFSI (Docket Number 72-1037)
A. 1OCFR72 & 40CFR190 Compliance Assessment:
1.
2.
3.
4.
5.
TEDE
Total Effective Dose Equivalent
40 CFRI90 / IOCFR72 Whole body limit
40 CFRI190 / IOCFR72 Max exposed organ
% Whole body limit
% Max exposed organ(child liver/thyroid)
0.00+00 mrem/year
25 morem/year
25 mrem (75 nirem thyroid)
0.OOE+00%
0.OOE+00% / O.OOE+00%
Quarter I
Quarter 2
Quarter 3
Quarter 4
Total
0.OOE+00
m rem
0.OOE+00
mrem
0.OOE+00
m rem
iIre
0.OOE+00
m
0.OOE+00
Irenm
B. Maximally Exposed Receptor:
I. Direct
Total body (torem)
Qtr Obj
I" Qtr
2
6.25
O.O0E+00 I
O.OOE+O
,d Qtr
3 rdQtr
4h Qtr
O.OOE+00
0 OOE+00
Yearly limit
40CFR9/
Total Dose
213
IOCFR72.104
25.1)
O.OOE+00
% of
Yearly
limit
I0.0(E+O(,
ZionSolutions, LLC
ZS-2014-01 00: Attachment 4- Radiological Impact on Man
Attachment 4.5 - Combined 40CRF 190 Report
IV. Combined 40CFR190 Report:
40CFR190 URANIUM FUEL CYCLE DOSE REPORT
GAS ANNUAL DOSE SUMMARY
Year .....................
From Unit ................
To Unit ................
Coefficient Type .......
Gas Receptor ............
Distance (meters) .....
Compass Point ..........
2013
1
2
Hist orical
5 Cot mposite Crit.
0.00
NA
=== MAXIMUM PERIOD DOSE TO LIMIT
Dose
Dose
Age
(mrem)
Period
Group Organ
Quarter
Quarter
Quarter
Quarter
1
2
3
4
Annual
CHILD
CHILD
CHILD
CHILD
LIVER
LIVER
LIVER
LIVER
CHILD
LIVER
Annual
1
2
3
4
CHILD
CHILD
CHILD
CHILD
T-ODY
TBODY
TBODY
TBODY
CHILD
TBODY
IP
(Any Organ)--------========
Admin % T.Spec
Limit
Admin
of Limit
Limit
Period
Limit
4.76E-05
3.30E-05
3.82E-05
Quarter
Quarter
Quarter
4.63E-05
1.65E-04
Quarter 5.63E+00 8.24E-04
Annual
1.13E+01 1.47E-03
=== MAXIMUM PERIOD DOSE TO LIMIT
Dose
Dose
Age
(mrem)
Period
Group Organ
Quarter
Quarter
Quarter
Quarter
Receptor -
5.63E±00 8.46E-04
5.63E+00 5.87E-04
5.63E+00 6.79E-04
7.50E+00
7.50E+00
7.50E+00
7.50E+00
1.50E+01
(Tot Body))-----------=-----Admin
% T.Spec
Limit
Admin
of Limit
Limit
Period
Limit
4.76E-05
3.30E-05
3.82E-05
Quarter 5.25E±00 9.O-E-04
Quarter 5.25E+00 6.29E-04
Quarter 5.25E+00 7.28E-04
4.63E-05
1.65E-04
Quarter 5.25E+00
Annual
1.05E+0l
8.82E-04
1.57E-03
7.50E+00
7.50E+00
7.50E+00
7.50E+00
1.50E+01
T.Spec 0
of Limit
6.35E-04
4.41E-04
5.10E-04
6.18E-04
1.10E-03
T.Spec %
of Limit
6.35E-04
4.41E-04
5.10E-04
6.18E-04
1.10E-03
ZionSolutions, LLC
ZS-2014-0100: Attachment 4- Radiological Impact on Man
Attachment 4.5(continued) - Combined 40CRF 190 Report
40CFRi90 URANIUM FUEL CYCLE DOSE REPORT
COMBINED MAXIMUM ANNUAL DOSE SUMMARY
Year .............
From Unit ........
To Unit ..........
Liquid Receptor..
Coefficient Type.
Gas Receptor ..... ......
Distance (meters)
Compass Point ....
2013
..
Historical
5 Composite Crit.
0.00
..
NA
MAXIMUM PERIOD DOSE TO LIMIT
Age
Dose
Dose
Group Organ
Period
(ntrem)
Quarter
Quarter
Quarter
Quarter
1
2
3
4
Annual
CHILD
CHILD
CHILD
CHILD
LIVER
LIVER
LIVER
LIVER
CHILD
LIVER
Quarter
Quarter
Quarter
Quarter
Annual
1
2
3
4
(Any Organ)
Admin
Limit
Period Limit
4. 76E-Q 5
5
3. 30E-0 5
3.82E-0 5
4.63E-0
1.65E-0 4
=== MAXIMUM PERIOD DOSE TO LIMIT
Age
Dose
Dose
Group Organ
Period
(mrem)
Receptor
T-ODY
TBODY
TBODY
TBODY
5
4. 76E-0 5
3.30E-0 5
3. 82E-0 5
CHILD
TBODY
1. 65E-0 4
4.63E-0
% T. Spec
Admin
of Limit
Limit
Quarter 5.63E+00
8.46E-04
Quarter 5.63E+00
Quarter 5.63E+00 5. 87E-04
Quarter 5.63E+00 6.79E-04
8.24E-04
1.13E+01 1.47E-03
Annual
(Tot Body) )
Admin
Limit
Period Limit
CHILD
CHILD
CHILD
CHILD
IP
%
Admin
of Limit
Quarter 5.25E+00
9. 06E-04
Quarter 5.25E+00
Quarter 5.25E+00 6.29E-04
Quarter 5.25E+00 7.28E-04
8.82E-04
1.05E+01 1. 57E-03
Annual
T.Spec
of Limit
7.50E+00 6. 35E-04
7. 50E+00 4.41E-04
7. 50E+00 5. l0E-04
7. 50E+00 6. 18E-04
1.50E+01 1. lOE-03
T. Spec
Limit
T.Spec %
of Limit
7. 50E+00
7. 50E+00
7. 50E+00
7. 50E+00
1.50E+01
6. 35E-04
4 .41E-04
5. l0E-04
6. 18E-04
1. l0E-03