PROTECTIVE COATINGS FOR STRUCTURAL STEEL Second Progress Report
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PROTECTIVE COATINGS FOR STRUCTURAL STEEL Second Progress Report
PROTECTIVE COATINGS FOR STRUCTURAL STEEL Second Progress Report A. J. Permoda. R. L. Snider Research Laboratory Division Office of Testing and Research Report No. 361 · Research Project 49 G-50 Michigan State Highway Department John C. Mackie, Commissioner Lansing, August 1961 PROTECTIVE COATINGS FOR STRUCTURAL STEEL This progress report describes the performance, in accelerated laboratory tests, of a number of specification and proprietary structural steel primers and coatings. These materials were received for evaluation by the Resllarch Laboratory Division from 1956 through early 1960. A previous and initial test series was .conducted as part of the same Research Project49 G-50, and reported in July 1956, in Research Report No. 260. Primers and coatings received early in this four-year period were evaluated in 30 primer-topcoat systems as Series 2 in 1958, and those received later were tested as 42 additional systems in 1960 in Series 3. In addition to primers and coatings received after the Series 2 tests began, the Series 3 tests included colored, non-aluminum topcoats especially evaluated as possible finish paints then being considered for the Houghton-Hancock bridge, and ten systems being field performancetested on steel girders of two bridges on M 7 8 relocation in Shiawassee County. The M 7 8 field tests are to be reported as Research Project 49 G-50(4). Laboratory Test Procedure Tested primers and coatings were applied on steel panels and evaluated in laboratory equipment as two-coat systems of a primer and a topcoat. The evaluated coatings were applied on duplicate 3- by 5-in. panels, cut from flat, 20-gage, hot-rolled steel sheeting. The hot-rolled grade was selected because bridge structural steel and hand railings are of this particular type. After occasional rust spots were removed with abrasive paper, the test panels were degreased in a trichloroethylene vapor bath prior to application of primers. All paints were applied by brushing, the method of application used in maintenance coating of Department bridges .. After a suitable period of at least six days for drying of primers, the panels were topcoated and allowed to dry in the laboratory for a period of about three weeks, before testing. After drying, the better panel of each set of two was selected for testing, while the other was set aside to serve as a control for comparison purposes at end of weathering tests, and the selected test panel received a vertical scratch through the coating to the metal. A complete test cycle consisted of 200 hours exposure in the Weather-Ometer, fc:>llowed by 50 hours exposure in a salt-spray and humidity cabinet. The coated panels of each series were exposed to seven such cycles for a total exposure of 1400 hours of Weather-Ometer and. 350 hours in the salt-spray and humidity cabinet. At the conclusion of the laboratory tests, panels for the coating systems listed in Tables 1 and 2 were photographed beside their respective control panels to show the amounts of degradation during the test exposures (Figs. 1 and 2). Performance Ratings To assign numerical values to the conditions of coating systems after laboratory exposure, two observers, S. M. Cardone and A. J. Permoda, rated the panels for three factors : 1) topcoat. appearance as to fading, chalking, and gloss change; 2) amount· of coating breakdown on panel face; and 3) extent of rusting and rust creepage at the vertical scratch. Each factor was rated numerically on basis of 10 to 0 scale, with 10 denoting perfect condition, decreasing to 0, denoting complete failure. For convenience, these three ratings were added into a single total value indicating the overall merit of the coating system, with the highest total representing the most satisfa<;tory system. These totals are tabulated in Tables 1 and 2, as are the three individual factor ratings, the relative ranks of the paint systems, and sources of proprietary coatings. Test Results: Series 2 The coatings systems listed in Table 1 and shown in Fig. 1 may be ranked by performance quality in the following order, starting with the best system: 1. MSHD 1A red lead primer and proprietary silicone-alkyd aluminum topcoat (System 8--26 points). 2. MSHD lCred leadprimerand MSHD 5Baluminumtopcoat(System points). 9-~25 -2- 3. MSHD 1A red lead primer and MSHD 5B aluminum topcoat--the · Departmental standard (System 1--24.5 points). 3. MSHD 1A red lead primer and proprietary leaded aluminum gray topcoat (System 29--24. 5 points) . . 4. Proprietary alkyd-linseed oil red-brown primer and proprietary silicone-alkyd gray enamel topcoat (System 13--23 points). 5. MSHD 1A red lead primer and proprietary chlorinated-rubber green topcoat (System 7--21. 5 points). 6. Proprietary basic lead silico.chromate orange primer and proprietary basic lead silicochromate green topcoat (System 27--21 points). 7. MSHD 1A red lead primer and proprietary basic lead silico chromate green topcoat '(System 6--20.5 points). 8. Proprietary epoxy-ester red-brown primer and proprietary epoxy-ester gray topcoat (System 14--20 points). 8. Proprietary urethane brown primer and proprietary urethane green topcoat (System 19--20 points). 8. Proprietary zinc-rich gray priiner and proprietary gray topcoat (System 26--20 points). Nineteen other systems ranked lower, earning less than 20 points. These included neoprene,. thiokol, rubber, epoxy-ester, and two-component epoxy primed systems. The four best-rated systems were red lead-primed with aluminum topcoats. By contrast, five other systems (Systems 2, 3, 4, 5, '10) also red lead-primed but with topcoats based on non-aluminum pigments and oil vehicles obtained poor ratings, largely because of po\)r appearance and scratch rusting. ·Four other systems (Systems 6, 7, 19, 27) with proprietary non-aluminum topcoats based on chalk-resisting pigments and improved vehicles, earned good ratings. Test Results: Series 3 The coatings systems listed in Table 2 and shown in Fig. 2 may be ranked by performance quality in the following order, starting with the best system: -3- 1.. MSHD 1C red lead primer and proprietary silicone-alkyd aluminum topcoat (System 9--26 points). 1. Proprietary zinc-rich gray primer and MSHD 5B aluminum topcoat (System 36--26 points). 2. Proprietary basic l~Jad silico chromate orange and proprietary basic lead silico chromate gray (System 14--25.5 points). 3. MSHD 1A. red lead primer and MSHD 5B aluminum topcoat, the Department's standard (System 1--25 points). 3. MSHD 1C red lead primer andMSHD5B aluminum topcoat (System 6--25 points). 3. Proprietary zinc-rich gray primer and MSHD 5B aluminum topcoat (System 33-25 points). 4. Proprietary epoxy red chromate pigment primer and proprietary epoxy gray topcoat, both two-component (System 31--24.5 points). 4. Proprietary zinc -rich two-component gray primer and proprietary vinyl gray topcoat (System 34--24.5 points). 4. Proprietary zinc-rich gray primer and proprietary gray topcoat (System 35--24.5 points). Performance ratings for Series 3 were somewhat higher than for Series 2, because these systems were especially selected for quality. Following the nine best systems, the "good" and ''fair" systems rated from 24 to 17 points, a higher general level than in the earlier series. Among the "poor" systems were : 1. Proprietary metal black primer with bituminous vehicle and proprietary aluminum topcoat, at normal film thickness (System 15--0 points). 2. Proprietary tar emulsion primer and MSHD 5B aluminum topcoat, at normal film thickness (System 21--11 points). 3. Proprietary brown and black furan topcoat (System37--0 points). -4- Five of the six best-rated systems were topcoated with aluminum paint. Some topcoats, also applied over red lead primers, but based on non-aluminum pigments and oil vehicles, performed poorly (Green:_ System 2; Gray: Systems 3, 11). Others did well, notably proprietary non-aluminum topcoats based on chalk resisting pigments and improved vehicles (Green: Systems 8, 13, 42; Gray: 5, 14, 31, 34, 35, 41). Series 3 systems undergoing field testing on -steel girders of two bridges on M 7 8 in Shiawassee County tested well in the laboratory, all receiving scores in the range of 26 to 22 points. The MSHD standard system of 1A primer and 5B aluminum topcoat rated 25 points. The ten systems involved are denoted in Table 2 by parenthesized system numbers. Test ratings for many systems exposed in both Series 2 and 3 were similar, indicating good duplication of test results. The MSHD standard system of 1A primer and 5B aluminum topcoat received 24. 5 points as System 1 in Series 2, and 25 points as System 1 in Series 3. MSHD 1C primer plus 5B topcoat had identical ratings of 25 points in both series. Systems with topcoats based on non -aluminum pigments, however, gave less reproducible results. Conclusions 1. On structural steel, performance of the Department's current system of 1A(1) red lead primer and 5B aluminum topcoat was equalled by very few of the tested paint systems, and surpassed significantly by none. This primer has other advantages in being one-package and easy to prepare, having long pot life, and being easy to apply. This is less consistently true of other systems evaluated in these tests, i. e. ; epoxies and urethanes. 2. Zinc-rich, cold-galvanizing primers evaluated in the tests earned very good ratings and appear to have potential as superior primers. The tests indicated that specially designed topcoats are required with these primers, which_need sandblasting on hot-rolled steel to provide protection cathodically. 3. Few colored topcoats had ratings equivalent to 5B Aluminum. Ratings of the good colored topcoats seemed to depend more on being matched with particularly compatible primers than does 5B aluminum. -5- Recommendations 1. · On the basis of performance in these laboratory tests, the Department should continue its current specification of lA(l) primer and 5B topcoat on bridge structural steel. 2. Performance evaluation of coatings under field test on two bridges on the Jill 78-relocation inShiawassee County should continue, and results subsequently be compared with laboratory performance. The field test results should have greater weight in dictating paint specification revisions. -6- 2 3 4 5 6 7 8 9 10 II 12 13 14 15 17 18 19 20 21 22 23 24 25 26 27 28 29 30 /- 1 I I I I I I I I I ' /- 1 lo I wtll l~_j l:cW I!;(~ Is: lwa. I -.;] 16 Figure 1. Series 2 panels with unexposed control panel above in each pair, and test-weathered panel with vertical scratch below (identification and performance ratings in Table 1). Figure 2. Series 3 panels with unexposed control panel above in each pair, and test-weathered panel with vertical scratch below (identification and performance ratings in Table 2). TABLE 1 IDENTIFICATION AND PERFORMANCE OF TEST COATING SYSTEMS(!) Series 2 Coatings (Received 1956-1958) Test ~'ystcm Drying ldentifica~ion Composition Tim~. hr ~'ystem -/-rruckness -'PI"'><mils anct' I; Ratings•• Face Rusting JScratc~ I Rusting Total Rank Remarks . . Primt•r: 57 PR-7:l Topcoat: 57 PR-151 MSHD ~o. lA rt!d lead MSHD No. 58 aluminum with .-\\'-:1 vl•hicle Primer: 57- PR-7:r !'.tsHO No. 1:\ red lead '-!SHU No. a gray Topcoat: ;,~ PR-110 Primer: .:.7 PR-73 ;:;!'\ PR-Iu,-, ,, PR-<:~ ... 7 5 9.0 ••• ::!4.5 ' :l. 6 .'i.5 '·0 4. 0 17 5 12 :1.6 :1.0 9.0 5.0 17.0 1:1 :w :!, 9 ;;,o 9. ;) (J l!LU 9 4' :uJ a.o !<_:; 5.0 1"-" 10 :u; 1;.:; ~~- 0 :) 0 ~0. 5 7 T?pcoat from National Lead Laboratories, Brooklyn :1. ;j ~-ii 9.0 '-" 21. 5 5 Topcoat from Valdura Division of American-Marietta Co. , Chicago t. 7 !.'1.0 \L5 ... :; 26.0 1 Topcoat from Dow-Corning Corp., 'Midland 9.0 ,.0 25.0 2 -!~"> 4' :w MSHD No. IA red lt•ad 4• Topcuat: ,:, ... PR-14::1 =--LL Pnm!.'r· 57 PR-7:1 Topt•oat · 57 PR-1 :;o MSlHl ~"- lA red lt•ad Laboratory mudif.it·d ~"- ·lA Kn"t·n Prtrnt·r: 57 PH.-7:1 Topcoat: 5(i PR-l·Hi ~LL ~t-·.-,o ~rt·t.m ;I() ~tsHIJ i'i~•- ,, ~~-.-.u ~ISHU Primer: ;ii PR-7:1 Topcoat· :; .. PR-IO:m I 5 --~~ MSUD ~"- lA rt.>d lead Labora«·~- mU:..tified No. :lA gray Topc~•at: Prirnt:r· 57 4' 1• g-ray :w ,, r-.;,,. l A n-d It• ad IA n.•d il•3d \'al-Cht:m ~u. tiii6 Krt-en \nth t•hlormat.od rubbt..•r Vl•hicle 1< :\tsHJl ~o. 1.-\ red lead XP-7 -1\t~:! alummum with silicune alkyd vehicle 4< ~ (I" I Pr1mer: :-.; PR-7:~ Top:.·ont: 5~ PR-lol- (prt•mixt.'lil ' Primt•r: .i::-! PR-1/H Topcoat: .37 PR-151 lP Primer: 5" PR-lU4 Topo::uat: .:;~ PR-lll::i 11 12 13 M,..;;HD So. lC red lead MSHD No. :;a aluminum · Primer: 5~ PR-94 Topcoat: 5!:1 PR-9;) Primer: 5tl PR-9-t Topcoat: 5~ PR-103 5~ PR-76 Topcoat': 58 PR-~0 Primer: ·~nth " " " AV -:1 n•h.tdc 15 16 4' ao 3.6 2. 0 9.·0 ;),0 16.0 14 LL\ So. :.!tiH red lead UA (Gliddt..'ft &.tft-l9) light gray " 4.0 :::. 5 !-1.0 4.0 14.S 16 2.2 6.0 4.0 3.5 13.5 17 3.1 5.0 9.0 9.~ 23.0 4 .3.5 4.0 ••• 7.0 20.0 ' '-2 3.0 1.5 1.0 5.5.. 20 2.2 2.0 0.5 1.0 3.5 22 UA So. . LlA No. ~614 ~615 .." 30 red lead aluminum RLtst resistant red-brown with al-kyd-linseed oil 30 Gray enamel with silicone alkyd \'ebicle 24"' Priruer: 58 PR-7-'!! Topcoat: 51'1 PR-79 .Rw.."t iolaibitive red-browD with epoxy-ester vehicle Gray ecame-1 !llri.th epoJ~.Y-e.ster ...-eb:icle 24 24 Primer: 58 PR-IOlA 5~ PR-lQlC No. 101-damp-proof red-bl"'WD No. 60-6 silver-gray 24 T~:rt: Primer: 5S PR-SIA Topcoat: 5tl PR-S2D No. CP-1 bl"QW'Illead With~ vehicle No. CN -14 gray with neoprene vebie1e 24 ... 24 Pear bnlrah3bility .lbU.Uigs Oft~ or l-6 '·· MSHD So. IC red lead Lab:.~r.U.ory mr)(ilfied N-o. :lA gray ..,-efticle H 2. 7 w o. with 10 deaot.iDg AI;J ~ aad .g ~ fai.bare. Standard MSHD system Topcoat from !\ational Lead Laboratories, Brooklyn Both coats from Lead Industries AssoeiatioD, N.Y., N.Y. Both coats .from Lead Industries Association, N.Y., N. Y: Both .coats from BobeeoD Preservo Co., Port Huron Both eoats from Robeson Preservo Co .• Port Huron Bc:d:h coats from bst-8ele Co. , Cl<mohmd Both eoats Cbarc:oCe from Charleston .Rubber Co. , CharlestDD, s.-c. (1• Cycle coesis&N of l-iDO Ju- eyd.ic-al c~ in w~~r-Ome~ 'C9 mm •-ak·r spray pe-r 60 miD ~1. aJid :WO hr t•.-n.- ln ,..;dt lqWa}' ad bollillidity =biAcl at 9.:;. 1-' • TABLE 1 (Con't) IDENTIFICATION AND PERFORMANCE OF TEST COATING SYSTEMS Series 2 CoatiJJgs (Received 1956-1958) .... -I n-;.- i IDeymg ~m nlm!'_ I"" ~It: :;;,- PR.--11.~ ~>·- m---21r ~.c T•lpi'on~.· ,. ~ C0~.11:1 5l:!- Jhmnl:~ """' I?Bl--9~ CP-Il &t!0\ml fuadl ~ ne0~~ <CN-Il:s. g,weeDl wi!mhi nea~ ~elti'c.!Je. l:";dJ-Cfumll r- z~ :!:..t• ~ 66UJbtru~wm~ ~ "~::el'lilc'le· :::;,- !?Bi.-'"111~· l<;cll-<C'fu::mt 5&.. Gli2: g,r.L}' wl!tlii umet:fume. ~le(ltww-<tOmpviiE'DI:!:tl E''rimer :..- Il"R:-3<- 119' \.-a:Il-(L-nem ~J·.. 6~1), 1~"'-rn wi.tll1 mretfume· ~ :11- l?B1-nK1o> ~aJJ-<lbmll :~W.._ flfi~ jO)'t!'ere wiltb u::It'etllane- 'il:eb:idl~· --· - IJltNimg; """' I!"""'""'; I , Rm.stittg .2:.11 3:.~ •-• •-• 4.5 21 BoCb. eoats Cba:reote from Charleston Rubber Co•• Charlesl:oD~ S... C. ~QI .;_@1 tj;_(]IJ a._ a. :nfU:Jl n Both. eoats from Valdara Divisioa of Americ:m-Marietta Co... Chicago :!'.. 7 .;;,01 8-.. 0: ~UJ: 2£1,_0: t:.6i ·lL$ • .. e: !!:!' I!:!' ......... T.W ·~ ~~)-{t<·,mplliatrllt}• 1J·•~~.~>(dl: arme ][;!: !,rt'W:<,.-t!Gmpanrtn:!tjJ 1[~-...!lllt -- I • Both coats from. Valdura Division of Amerie:an-llrfarietta Co•• Chicago lbno-<t~atrnttl' WID.inm tt- ~ Pnl.-iJ-JS, TGp<:mttt.: :il'- J?m-Illl':!...~ :!1:•• ~-::d!--€1'1Jtml :-;.~'- 6901 bnowrn wLtllt eplil~-eSI!etr \:~fe. ]j;!' lr;Mi-(!.'futmJ ~.,,_ n~ f>s,; ~ wi:tllt L~rilmie<Jl-whlle•Ir .. ll'ltfuillk:· ....• 0 • "' .,.. !Ptrum:IT: ;);;: I?BHHl.-;, 'l\"a!ll-<l~Ill\ 50c 691.·1' tl:~ru~wrn w~llfu 1."1~"'-'!¥-t..""Stlt.""l!" lfnR«roa.fL:· :;,..., ~3Jl-€ll;t~ml ~'-· 6;'>(), g.Ir~:er.l IPUl~ll•lr!W, w:iltlfu v:&.ru!:lle ~tfr!lmriml:!!4>tdJ-rull!i~L'll" ·-· 13.& •• l?'rt:m:t!:w:: :),-l!'m-IJ.IJt>> Sllclllll!fuJ.. 1.-1.-:mm wdl IM-.tdl wEt:liJ tel!l"'~ -~· v:tdlW.llic (\tW0M::GmpOn"entL)i 1£~:>peua£.:· ~ i!'BHI~ :,!3, F'l:ri:mL"lt": ~ Pm-llfill:" JJEilliiill ~'-- 5:B1 -..fumigmm wiJt!l!; ~W-;j: '"elti:dJr· Sleilll !S0c. .u-:-.mn Iredl Ieacli witt!ll: epe~-'~'ersamhll \t'eiW:dk(~: 1i"opc:oott;: 5ii:' Pfit~·Il :!.'~; P'lli'me2r::: aN- Fm-llilZ Vopeoatt:· 5~ ~lliJ~ eBiii}l NG\.. 5B\ afnmiW•m Il"RRi:" SOJ__ wiil!fu .<\.~-31 ~ .ro:x tt:l.lll wfdtl t!lli:olmll '011."-llmie· V~m1!'!io!.- ii5~p:t.ywiit1hl <!:!'dO~lev .;_@I !7.• £ Z-5 l!UJl ]5 Both coats from. Valdllra DirisioD of American-Marietta Co•• Chicago 3'-• .,1\ "Ld\1 rl'·.S 3_.01 :ns-.5i •• Primer from Shell Chemical Corp. of N.J. ~!'<- 'L@' ~-s; 2'-0 l'LS u ]_!i;<"' £.:); .._. 2:,.01 .._, U.Ol 19 PJimer from PJmd._ Res. Corp•• Det. ; Topcoat from Valdura Div. of Amer.- Jl'arietta Co. • Chicago .._., 3...0'• I!!>.QI ]'l.5 l2 Bolh .eosts from Saboi. me•• Toledo Si.Oi 3.0~ &.Ol !i'.(}l 20Ul • J,.8> 6·.5' ~0, ~.5 ZLO • l~ nz: ,. . u ~.5J!!I':PBH!ll3~ "Iropconlll:· 21> ~ ~ l?m-!l113Bl 11:!'" 58"E'Rl.-EE.4l ~Nil>•. Sfl~~glm-Y ;lijl SilO&..' SoL. 5i l1igJtt. ~ 3ll' G'ai"::mooo.: ziile:--pfg;menti. ~- ~ clill::lriJ:I;ate(t- '" ~v:eiiiclle ~ 5ti»~ No;. ;), ~ NIU1..~61~ 3& N1IJL 3£~5'(Jl peero "'' ss;~..;.; "Iro~$~-n;i ~ 291 ~: ~JI?RH_4-!I.!\. 30! I!igfttt gll'ay u P'HI!: l'llb>... -10& fmm;m ~ ~-MBJ li"BB[:' P'l!Iirmer.:: ;rr; ~ MSfiEI .... u, ted! Ieadl Silllafu.."{; N"o.'. 50'8"· gun:metat pay P'.rimetr: 110pcoa~: ~ Pll-'£491 f3 I?R-115UI n ahon2ml'}-, funnufufedi .. "-• "-' 't.$ "'-Z 'LG.• 9!.01 :l\1' :u 5-_@i u 1Si01.. -109' g.n:y; 1!0peoaitt:· 11opeoam.:. 5Bi m~ ~ zfue chromate o'llLve li.aJJo~ey- ~NO'~ -fA- green- Jo: 30't .. POO!rtWo:shbiill!¥ ,..,.. ~on! S¢ai1e Gil" ·-· 30, "IrQplto!lll!t: ~ !?R--lt!l3S\ :001 ~Oil" wd lto• dene~ tmJ detem:0.ra:ti:on rondl 0-' co.mpl'ete !a!iill.nre·~ from Shell Cflemical Corp. of N.J. _Primer ueiliidC: s, Chicago Z.QI ]:!: ...:eltudJr· , Both coats from vaidw:a Division of AmerieaD-M.arietta Co•• ·-· 6i.$ ·-· 7.() ll'LS· l2 2-£..5' , lS.S 1. Bot& coats from Sabox Inc•• Toledo lklth eoats from. NatioDal lead Labor.dDries. - BoE& coats from PrDdacts Research Corp. • DetJ:oit Tq:coat:. from Silbox Jac., Toledo TABLE2 IIJilDli'Il!F'lATIDJ!tlf AI!ID P~CE OF TEST COATING StSfE.MS(l) S'eries :I: ~ (Reeeiived 1958-1960) - II-"" . 11--.-r=·- ~.::.:..11;;:,;; I ,_ ! I lhtimm:: 'lrOpz:u:att: em J!JB...62 "' l!'r:iiDelr:: 6[1) ~ ~: SiBeJH...&IJ$ "liiSIIIIll'lin. 11& J!8dl teadi M&lllllllih. 4!A\peem 3l ID!iimm:: ti[I)JNB-62! 1lbpmatl::: m:€1H-8JJS3 JiiSBD1 NW.. 1lA\ md!.lliadl JIISIID)J'Rn_ a.w.~- (II)) . $ ..." II 611) Rm-llllZ! li5IBJ) IRn. li& ll8dl Jeadl MSIID.ll'Rll.. 5maD•mjnnnn 'Wfiftt&.W-3l ~ ~:61D~ MSIUJ) l'lih. 1TOII!£D&II::: 56)~ IRJ.JJ.lll!-5lll- llbi:lne:lr.: 6[() ~ MSiml IRn. 11&. mdl Ieadl '17•• 0! &.. $ 2!..® 8i..5i &..$ 71 :IDmmm:: S!llllm-4!n II'5Jm) Ni:n. 00: mdllkadl. llapwatt:: 6D) Pm-69.1 IRJ.JJ.<mmm> Pm!nelr:: 59:1 Rm-ln l!il)JmaU:: 6ID RllHm MSHID) N01. 1Kt Jrudllliadi '"•• .,. :9rul~5DJpw_m ])2: NISHD) Nb:l. :OO:"l!Udlleadi "'•• .., (goomi«ud)J ---- . Z:..Ol 30> ~~:illmriil.unn witthsi~none> a t ¥ v.wtil!fuo Htiil'mlr::: 59J RR.Hn IXD 'EOg£.oa:tt::: 5&; HRHSn NIBHDlh.'Ul. m·nud!leadl Nh1. 30ll.o?&umumtfurn..Wifulli.tumiimus;wiliitd.k n• -!OJ• .... lh!imrur:-: 59J RR~ 1!0J!W1att;: Sl:J,RRl--UJSi lllmfiD)h."fu. m: oodilimdf R:ilio.m.t:blllY modifii:ld! :'ful. 3~1f.llll¥- Rilirnetr."· 5"6; :em-ntlll. 1lbgeDatt:: 6Q)HRHBJ2:< NUll., !\U·iiiJI Ollaii(p!.' 3lii l\1BffDl ~~l. 5BI albmimum w-i.tfh A\W-31 v.eiiicle- ]]Jlj "'' lfi:iinen::: 5ibi!IR--Jj95"A\ 110ncoatt: 5:& JHn-D;ti~ BhsiC: llmdisiliila:>aliml~Ulte! Ol!aiiP' llll Rbiinf.ur.: Shl~A\ BasiC: Umdl siliilO)«limm"ate Ol:llDPl 'DORcnatt: a&~ Bru;;iC:lliadl&iliilo;l~~- lnl (m)) 3{JI Bhsiu_·Jhadlsillilo;lclb:toma~~ ... '"' "" 2l!l ~-6> .... .. RburriJmsltaUilil~~ ~omscalb:ofi ll11U.Il0l. w-i.tfil WltllinnUng:: RUJlfut.Wti.umtiUm :u11ll 01 <WmpfutU: f(alillme:.. (Ill)) ¢!lclh.•(!OIIsiidtldloff LIIDOJ lttru.),'•cliu:tll c.."DDIWJIU" ii'l1 Wi.<:atfu~::'-t:Oinunur (IJJ min1 \\l:tfun" ~l1:1!1,> gen-.mll IQ.imligtitn. anall:t..-ollttr~otxpmruru· inJ.mlltsnr.::alr ami IHumiili~1 lmmil~.ttt.att m;; 1!·:. .... .... .... 119l.O "'-·· 25.. 01 & .. Si ffi•. Si nstSi 71•. ® ~4LGl 2!.-41- ~.01 9J •. Gl ~-~ &.55 9Ul'l 2?..!:'!! Gi..5i :l!..Si :!CT. iji..(J) Si.Si 2'..m &...5i 8l..5i 2'..71 7i•. 5i 2'.. To au• ··muxmttinsiioodl lll!d.t~'81WftliiWDiiun.'-l' indiU:ltlt· [iuJUJ ~t\<.:alilatiiom nn1:W 77.,.1inidjat..-.< im Sliiaw.a~.: ~: . - ..... ...... ••• Nl5fiD) !IOJ.. Hnitntm~: 51ll Hm-4!11 lf0(!il03tl:: 5Bl RRHDS> .... $ .. 51 m:ti.Ine!t:· 5HllmHlll ,. nat.GJ :o ... net: zmdllkadl $.@ "" 3m MliiHDl l'§W.. 5BI alluniinum ~itlfu &.~-3l ~ 25.@ <c$ " 60)~ ... ••• 9Ull 2:..5:. ....,. IRI..II..lli-5m~- 'Jibpnmlt:: .... 8L$ 3Jj; 11&. nedi 1Badl 2U)l :!C.$ ~: 5B\l!!lt-ll4m 9l ~ "" ..,·~ .... ~-· .... .... --. -3 "' 131 • • nz • 2fii..Ol n li.&•. Si ·~ 5i.. Ol m .. 5i nz 6i,.5i 2:3..• ~ !ii..GJ 2!<!..@ 8l..5i Z$..$ • • 'IDIIp:wdt mmt 5'atioaal y~ ~.eMil f , atuzies. m.. ~ ~_Eal!londories. 1!"~-- ~ Eeadi Libi;aato:ties. -.. 'lropmatt: ffmltm ~ J.ea;d. Labontories. .,.,._.....,,_...,_.,__.'Ir~ffmml~ ~ llfetais I!m:~.-~ - Jllmirr:om- bm.l!fa:lmmaffi JLe:adl. ~- .,.,.,._, BOtlil aaab lii!omllEagt!e-Pi:ider Co~ • Ebtlil. CQ'IItls; ffm:nm ~ C'G>~ ~ Ciimrutm:dtli TABLE 2 (Gon't) IDENTIFICATION AND PERFORMANCE OF TEST COATING SYSTEMS Series 3 Coatings (Received 1958-1960) Test System Identification Compos1tion Drying Syt>t.cm Time. ThH'knt'SS, nul.s he Ratings•• Appcar-1. Face I Scratch Rusting I Remarks Rank ,tnt·o: Ru8ting Total 1.5 0.0 0.0 0.0 ., ., 6.5 8.0 6. 5 21. :l. 5 8. 5 8.5 3. 2 6. 5 2.0 -- 15 16 Primer: Topcoat: 5t~ 5~ PR-1S7A PR-1S7B Zm.:o mt•tal black with bituminous vehicle Zonl• :tluminum Pnmt•r· 5:-. PR-190 Gah·Jnoh•um :So. 122ti aluminum-gray with zinc dust (twu-t·omponent) Tu}.X-·oat· 5t~ PR-190 Gah·inolvum ;\o. 12:!6 aluminum-gray with zinc dust ttw(J-component) 19 6 11 6 5 23.5 6 Both coats from J. Dixon Co., Jersey City, N.J. 8.5 6.0 21. 0 11 Both coats from J. Dixon Co., Jersey City, N.J. 6.0 6. 0 5.5 17. 5 16 Both coats from J. Dixon Co. , Jersey City, N.J. 2.3 6.0 5.0 7 ..'5 IS 5 14 Both coats from A. C. Born Co., Long Island City, N .. Y. 2 4 '-0 1.0 2.0 11.0 18 Primer frbm Jennite Products Detroit 3. 5 6.5 Hl.O 15 Primer from Jennite Products Inc., Detroit Primer from Eagle-Picher Co. , Cincinnati· " Texas Both coats from"RliSt-0-Leum Corp. Evanston, ill. Dixon:-;(), llll red lead-graphite brown Topcoat: 5S PR-1%8 D1wn :->tJ. 1119 bright aluminum with g:raphite 11'1 Prim(•r: ::;~ PH-l~:i.A Topcoat· .J1:i PR-1%C Dixon D1xun Prim~r: Topcoat: 5 .. PR-l9SD Dixon So. 101 red lcad-graphtte broi'."TJ Dixon :\o. 119 sage green " " Primer: 39 PR-5 Topcoat: 51-1 PR-:.!01 Born Burn 1< :.!1 Primer· 59 PR-7 Topcoat: 60 PR-112 J.ennltl' 1\o. J-IG tar-emulsion black !o.ISHD ~u. SB aluminum with AV-3 vehicle 22 Primer: .J9 PR-" Topcoat: 60 PR-112 Everwear 1\o. J-43-B pitch'-base black :\ISHD No. SB aluminum with AV-:l vehicle "" "18 Primer: 60 PR-2 Topcoat: HO PR-112 No. E-:{-776 maintenance brown MSHD !'\o. 58 aluminum with A\'-;{ \"Chicle 24 18 1.9 8. 5 8. 0 4.5 21. 0 11 24 Primer: 60 PR-64 Topcoat: 60 PR-111 NLL maintenance orange MSHD No. 58 aluminum with AV-3 vehicle 24 18 2. 0 8.5 9.0 4.5 22.0 9 Primer from National Lead Laboratories, Brooklyn (25} Primer: 60 PH-59 Topcoat: 60 PR-ll2 PPG XLO-FLO brown lead .1\.tsHD No. 58 aluminum with AV-3 vehicle "18 2.4 8.5 9.0 6. 0 23.5 6 Primer from Pittsburgh Plate Glass Co. Pittsburgh {26) Primer: f;Q PR-ti5 Topcoat: 60 PR-112 Glidden No. 26H special-wetting n:d lead MSHD No. 58 aluminum with-AV-3 " 2.0 8. 5 8. 5 7.0 24.0 5 Primer from Glidden Co. , Cleveland {27) Primer: 60 PR-67 Topcoat: 60 PR-112 SSPC paint 3-5·5T No. a brown M.SHD No. GB aluminum with AV-3 vehicle "" 2.0 8. 5 8. 5 6.0 23.0 7 Primer from Steel Structures Painting Council, Pittsburgh (U) Primer: 60 PR-68 Topcoat: 60 PR-112 Calif. No. 52G51 zinc chromate yellow-green MSHD No. 58 aluminum with AV-3 vehicle 18 18 2.0 8.5 8.5 5.5 22.5 8 Primer based on Calif.·. specifications l':i " "' " " Both coats from Zone Co., Ft. Worth, 0.0 ,, 17 ....I "" ::o I 23 ..) Pnmcr ;:;~ PH-l~JA ,;~ PR-1~SA Poor brushability Ratings on scalt• of 10 to ~o. ~u. 101 red lead-graphite brown Hl:.!.cxtro light gray G:~.h·inide Hu~th:lar 0. With lO mt•tal gray rust-inhibitive gray <il-nvtin~ ,, :JO 30 " nu dt'tl•tiur:ltion and U ~·umpl{·t~· failun·. 1.5 '· 0 Inc., TABLE 2 (Con't) IDENTIFICATION AND PERFORMANCE OF TEST COATING SYSTEMS Series 3 Coatings (Received 1958-1960) Test System (:!!.l) :w :n Identification Compu:;itiun Sp;t.•.:m Tim<.', Thu:·kness, he mds 12 1. Ei '· ., :l Priml'r: j)Q PH-tili Topl·oat: liO PR-112 Calif. ;o.;o. T3:!G-l:! Epon red k:td (two-component) l\tsllD :\o ..-JR aluminum w1th AV -:l \·ehJch.· 1' Prinwr· 1;(1 PH-77 Topcoat· E;() PR-7'"' Bak!.'r :-;u, 1:!-B--I"i n·d lead BakL•r :\o. 11-A-G alummum (premixed) 12. 12 Primt•r· !\u Pon Cok Typt: :t 1:!' S~ PH-1-'i~ L'f)O.\}' l'"<·d ehrom:tte (two- (:!2) :;:; ..... ,-)~ PnnK•r: liO :J PR-1 »~1 :\u Pun Cutt; TypL' PH-~ Sp<.:vdn.•x Su. !{P, 1107 cpux;.· gTa.\· (twn-{·umponL'ntl L'pox~·-c·.-ter 12 Topcoat: \iO PH-112 :..tS!lD ;-;u. :111 alummum with AY-:l n·hiL'k ,, !'rimer: tiO PH-f!l Chem-Zim: No. RB 1119 zinL' "ray !\.ISHD So. :iB :tluminum with A\'-:! \'t.'hitk Primer: ;i9 PH-192 Topcoat: 60 PH-11A Carbo-Zinc ~o. 11 zinc-gray (two-eompont."ntl Carbo :\u. l~:JO vinyl gray Primer: GO PR-H Topco:tt: =-,~ PR-u:.m G:1lnmux !..inc--pigment Suhox :\u. -'">light gn1y Primer: 130 PR-7ti Topcoat: GO PR-112 Zim:utl" zin(·-pigmcnt aquco~;; himk•r gr:1y (two-component) ~1SHD :\o . .'">B aluminum with AV-:J vehick Primer: GO PR-a Topcoat: 60 PR-H Permaspray BB brown Permaspray furan bi:J.ck (two-component) " Primer: 57 PR-77A Topcoat: 57 PR-77C NLL M-50 baking orang<· NLL ~1-~0 baking grt·cn 39 Primer: GO PR-72 Topcoat: 60 PR-112 40 \;HI "' 1:!.-)) 36 :J7 41 42 ancc Face Rusting I Sci-atch 1 Rank Remarks Rusting Total ~." 5.0 22.0 9 Primer based on Calif. specifications ..... u 9.0 7.0 24.0 5 Both coats from H. E. Baker Painting Co. , Northville, Mich. ,-, 9.0 8. 0 24.5 4 Both coats from Glidden Co. , Cleveland 9.0 ti.5 .'). 23.0 5 9.0 25. 0 3 Primer from Truscon Laboratories, Detroit 1:!' orang"L' Topcoat: t.iO PR-11~ I Appear-~ 4. l'Uill!J'lnl'!lt) Topcoat: Raticgsu Drying ,, ,, ;) ti. Primer from Truscon Laboratories, Detroit ;). li.5 9.0 9.0 24.5 4 Both coats from Carboline Co. , St. Louis, Mo. '· H. 9. 0 9.0 24 5 4 Both coats from Subox, Inc., HlJ.ekensack, N.J. . 5. 7. 0 9. 0 10.0 26.0 -.2 0.0 0.0 0.0 0.0 19 D'>"en,-dry• 0\"en-dry• ' 7 8.0 8.0 7.0 23.0 7 Both coats from National Lead Laboratories, Brooklyn Fed. Spec. TT-P-1:16a, Type 2 brown MSHD No. 5B aluminum with AV-J \·ehicle 30 18 2. 5 8. ii 9.0 6.5 24.0 5 Primer from Acme Q.lality Paints, Detroit Primer: 60 PR-73 Topcoat: 60 PR-112 Fast Dry zinc·chromate red lead-brOwn MSHD No. 5B aluminum with.AV-J vehicle 18 1.6 ':l. 5 7. 0 6.0 21. 5 10 Primer from Acme QJ.ality Paints, Detroit Primer: 57 PR-76 Topcoat: 59 PR-185 SUbox L-47 epoxy brown (two-component) Kil-Rust epoxy gray {two-component) 12 3.3 7.5 8. 0 7.0 22.5 8 Primer: 60 PR-77 Topcoat: 57 PR-150 Baker No. 13-R-48 red lead Laboratory modified No. 4A green 12 2.3 7. 0 8.5 7.0 22.5 8 Poor brushahility Ratinf);s on scale o! 10 to fl. ~ra~· 12' 1> :HJ " ,, ,. 1' 1H 18 30 with 10 oknnting: nu dl'll·rioration and ll (."ompkll- lailut·t·. Primer from Amercoat Co. , Evanston, Ill. Both coats from Leonetti Enterprises, H01.~ston, Texas Primer from Subox Inc. , Hackensack, N.J. Topcoat from Kish Industries, Lansing, Mich. Primer from H. E. Baker Painting Co., Northville, Mich.