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I actually wasn i t the one who put the... 4 Mine si te when you were there i let...
VICTOR IZZO f R. G. 09/28/09 Page 23 1 quaLi ty. 2 Q. And did you determine whether there was any 3 significant threat to water quality from the Wide Awake 4 Mine si te when you were there i let i s say i in the early 5 i 90s? 6 7 A. I actually wasn i t the one who put the report together. I was out there just lping because I was a 8 geologist. So I didn i t make any determination. 9 Q. Who put the report together? 10 A. I have the report on my desk. Oh i yeah. 11 Montoya and 11m forgetting his first name. 12 Q. Is he a regional board person? 13 A. He was at the time. 14 Q. Do you remember the name of the report? 15 A. Not exactly. It was something about the 16 central valley mine sites. That is about all I remember 17 exactly. 18 Q. Do you know whether this report is available on 19 the internet? 20 A. I'm not sure. 21 Q. Would it be possible to get a copy from you? 22 A. Yeah. 23 Q. What do you remember about the Wide Awake Mine 24 site when you visited it in the early f 90s? 25 A. I remember a lot of leased mining SAROFF COURT REPORTERS AN LEGAL TECHNOLOGIES 877.955.3855 09/28/09 VICTOR IZZ01 R.G. Page 24 1 foundations - mine foundations i what appeared to be 2 furnace-type equipment. I remember some -- what we call 3 Jlmining waste piles II and some water flow through i 4 there -- relatively small. We were therei you know 5 late spring or early summer, I think. 6 '7 , 8 Q. When you say, Jlmining foundations i II or I limine foundations, II A. do you mean? Well, when you go there, you know, you have 9 these brick (sic) that are typically used for furnaces. 10 They were there. You have heavy piping and clay-type 11 piping that can take heat. You have the stacks that 12 are - and i believe at this site the stacks were down 13 on the ground from, you know - - from the furnace. 14 Q. Would it be fair to call these processing 15 facilities? 16 A. Yes. 17 Q. Did you see any sign of a mine shaft? 18 A. I don i t remember a mine shaft. 19 Q. And when you say, IImining waste pilesi 11 in 20 general what are you referring to? 21 A. Two types on that site. There was basically 22 rocks, you know, in the sense of 6 inches to a foot wide 23 that is kind of like waste rock that is not processed 24 rock piles. Also on that site you saw some fine-graini 25 reddish material which is probably processed ore. That -- SAROFF COURT REPORTERS AND LEGAL TECHNOLOGIES 877.955.3855 09/28/09 VICTOR IZZO, R.G. Page 25 1 is basically what I saw on that site. 2 Q. And do you remember that from your site visi t? 3 A. Yes. 4 Q. Anything else you remember from your site visit 5 in the early i 90s? 6 A. 7 Q. 8 A. No, not much. took you ? I was there -- his first name is Barry. Now I 9 remember - - Barry Montoya. He is the one who took me 10 there. Again, he was the -- you know, he controlled the 11 whole project. 12 Q. When you were at the Wide Awake Mine site in 13 the early 1990s did you meet or talk with anyone 14 associated with that property in any way? 15 A. I didn! t. 16 Q. When you were there was there any - - anyone 17 accompanying you who wasn! t a regional board person? 18 A. No. 19 Q. Was it just you and Barry Montoya? 20 A. Yes. 21 Q. Who told you that you couldn i t go on the 22 property more recently? 23 A. Jeff would be a better one to answer that. 24 Q. It is your understanding that someone from the 25 regional board contacted the current owner of the Wide SARNOFF COURT REPORTERS AN LEGAL TECHNOLOGIES 877.955.3855 INACTIVE THE SACRAMENTO V ALLEY, STAF RiiPORT OF TH CALIfORNIA REGIONAL. WATER QUALJ CONTL BOARD, CÊAL. VALLEV REGION STANPAROS. POUCIES1 ~SPECI StUDIES UNIT 343 ROU1lER ROA. SUIT A SA.CflAMENT01 CAUFORHlA 95827 , i' l../ t E~ /ip.. ~~"' \.l L r Staté of California REGIONAL WATER QUALTY CONTOL BOARD CE~"T VALLEY REGION John S. Corkins, C/wir 1&rl E. Longley, Vice Chair Hank AbralumL Member A. Vernon Ccmrad, Member Hugh V. Johns, Member w. Steve Tompkins, Mem.ber Clifford C.WisdlJ, Member Wiliam H. Crooks, Executive Offcer 3443 Routier Road, Suite A - Sacramento, Canûa 95827..3098 COVEf: PicFlE OF CoElAllO TUN/4EL, Ei DORADO COO1m (CSMB. 1908) ANO TIe UNDERGROUND WORKINGS OI'SOCMTES MINE (CJMG, 1946). ~ABLE OF CO~~TS l . ~ . . . . " , , " " , .. . , , . . . , . .. ~ " . . . " . " ... """"."."... Table of Contents........... ............................... i ii i 1. Sumary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , 11. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 111. Mine Drainage Formation.... . . . . . . . . . . . . . . . . . . . . . . . . 3 iv. . t . ~ .. " w " . " . " " . . , " .. " , , . .. , . , . , . " 3 , . ." . ~ II i ~ " e ,. ~ ~" """ I _" .. i 4 Waste rock drainage. . . . . . . . . . . . . . . . . . . . . . . . . . 4 A. Acidic B. Ar s enic c. Characteristics of Sacramento Valley Inactive Mines 5 5 A. Drainage characteristics... . . . . . . . . . . . , . . . . . . B. Waste rock characteristics................... 19 v. Mass Loads......... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 VI. Receiving Waters. . . .. . . .. . . . ... ................... References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Appendices. . . . . . . . . . . . . . . . . . . . . . . . . . . , . . . . . . . . . . . . . . . . . . . . . . A Methods 33 34 34 34 4. Mass .load estimates. . . . . . . . . . . . . . . ; . . . . . . . . . . . . 35 . B Rainfall Runoff from Spenceville Mine. . . . . . . . . . . . . . . . c Water Quality Characteristics of Mine Drainage and Receiving Waters in Several Sacramento Valley 'Watersheds. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Watershed. . . . . . . . . . . . D Individual Mine Descriptions by E Trace Elei:ent survey of Several Sacramento Valley Wacerbodies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Common Minerals in California Containing Metals and Meta.lloids of Concern. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . G 30 1. Mine selection................................. 2. Field sampling and quality control. ... .., .. .... 3. Laboratory quality control results. . . . . . . . . . . . . F 27 Input~Oi,tput Calculations of Metals Moving Through Shasta Reservoir.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ii 42 44 65 74 75 76 JI. SUllMY A water quaty surey was conducted between 1989 and 191 to asses the pollutat contributions made by inactve ~es in the Sacrento Valey. The goal included estiatg pollutat loads and assesin impacts vvthout ass~ al nues in the watershed had been pri;,viousy identied. The number of mies chosen for ths study (94) were limited to those that were known suspected water quaty theats. amt drinage, wate rock, and upstrea/downtream receivig waters were sapled andany.led for several heavy metal, arsenic, and conventionlÙ parameters (flow, EC). Dry weather loads were caculted ""ith perenn awt draie data collecd largely durg drought (1987-1991). Inactve :ms were pervasive thoughout the Valey outsde the central basin and ino the sunoimd. his and mounta. i\lthoug not al mmes had perennial adit drge, waste roc materi was observed at every site vîited. Further, hitorica accounts and site observtion indicate that ore processi o:perations were conducted at most of the mies, increasin the potenti for water quaty degradation. Mieral contai copper, lead, cadmum and me were mined or indirecty mied il the Valey included arsenic. gold, silver, mercur, and sulfu compounds. Amt draiage qualty vared from unpolluted sprig water to highy acidic outfow begig around the mid-1800s. Other products directy contaiing metal in the ppm range. Amt in the Shata Distrct exhbit characteristics tyica of mie draiage - low and metals conte!lt. Iron M.t. Wile (IMM) was single loa~erl ronmbuLi l:ctween 57-85 ~ercent of . coJ!per, cadmum and zmc loads. hon Mt. roads were estiated&om Sprg Creek Debr Dam (SeDD) which collecl5 water from the entire Sprig Creek watershed hiclud.g .amt releases, waste rock erosionand~age,-ad-bad:grolJricì stream flow. Unle loads from the othr mi, which were cacuted us data on perenn adit.(aiage alone, loads year-round dicharges comi from the IM complex The combed loads from al West from SCDD reflect the sum of Shasta Distrct mies (Ion Mt., Mamoth Balakala, etc.) accounted for over 95 percent of the total copper, cadmium, and zichiactie mine contrbnlii: to the Sacramento Valey. Perenn mine drage in the Sierr-Nevada mounta range was highy varble in qualty. Drainage from gold mines in the Aleghel1y-Downevie area (Yuba Rier watershed) was c1:ctri by nea-neutral outow andelevaled arsenic., Posive El measurements indicate th the arsenic.is dicharged largely in the less toxic +5 state accordig to pH-Eh graphs. Mies in the Footh Coppr Belt (Spencevie. Valey View) exhibited typica acidic draiage but were not major loaders due. to relatívely smal outfows. Mercur mies are located in the Cache and Puta Creek watershed. A.oug most sites were dr, a sm. number of western. footh mies diharged slghtly acidic watr chacteri by high levels .of Jr~.ca carbonate contaed relatvely hi levels or mercur. compounds. Most waste roc saples peods were impactd by one or more metal exceedig Inand Twenty-one of31 receivg streas monitored diig dr ~~~a~~~:g~~l~~=di:~eí~~thnÎ:tc~S~~~6becli~~ãu:~l%.=~e:e:a!:i:;fot~r:;i= and silver. . Strea impa.ct leng app~ared to depend 0)1 avlloffactors includi.e compound-spec behavior, diution :~a~~e~ed~~:;6:~a:r:¿:nin=d~dl:J::~~C:f&k~o1.e:d .~~:gr~:J:;l~~ò~~;~~ measured in Dry Creek below Spencevie Mie d~ a 3 inch storme~ntexeed.tbe 1-hour EPA har.dness factored 6~J:~~~~~:pleI~:o:~~~6::o~R~e(?=re~.;i~e:t:~l=~:~eW.:fu..~~cf~~~ of t:...je totalan. ua.copp.l, cadm.. ium. ,and ziC..lo..ads dur. gtheraiy sea.ß.nwa. .estated.to&. cçuntfor 5-18 percent ~:~:igi::g:in:'J:tf~J~i:i~ci~r~:i~;ttQt~l;'=f~i.:;.~~t~t~O¡¡lk~~rt:i~:i~t~ acidity, ruoff inuetloads.becuse of slope, Alost the vaty of inuenci factors includig pereabilty, vag metal content and porosity, raiiiclaracteritíci, ctc. al strea inuenced. by nie draiage eventualy pas tbQugh one oimore. major resenrojr The fracton of metal tranporteà t:oiigha reservir appea to depen!11agey on dacbderCS and the qu¡Ùty of upstream inputs. summer input-output:flowsØt aSiera-Nevada reaied concentration ofseveT:a1 meta esntàlly unchanged between The reservoir. TI majority of the anual copper loads mto Shasta R~elVoir cae &oø:inacte mies whi~ liely ~uenced was Dam release levels - copper was ap~ioxateiyan order of magtude grcaterthan what streas not inuenced by mie draige. 1 pr.et m the major feeder D. ß1lODUCTON Mies once actve in the excton of heavy metal (e.g., mercu, gold, copper, zic) have exposed suirace mie.ral deposits to the weatlerig attrbutes of water and Oreboes were mied b aroWld the tur of the cent usmg w:dergroWld and open pit tecques that increaed &lJrface area of mier' one to breakdown in tle presnce ùf water, oxygen and acido c bacteri. Metal are leached from the mieral an tranrted dov.'leam vi raial runoff or adit di i ca cause fi ki tht have been docuented as far hack as 1940 (Nordstrom et aL, 1977. Run dicaded soi has resulted in the isuance of health wargs agait eatig mercu taited fih in Clear Lae and Mar Creek Reservoir. Prior to 1972, iegutory actioli by the regiona board to abate inactve mine dicharges wa hidered by ineffecve leglation (Mier et al 1979). The board had lied legal mean to force a mie propert owner to comply. Because operations ceased alogeter, the present mie/land owner was usy unwig or economicay unable to remedate the site. Furer coplicaons arose when th mie sie had been sold by the orial m. companY. Tyicay, wilved compliance was referred to !:e Câlomi court system beuse of the hi costs inevíbly invoíved. Many referal to the Distrct Attorney or General were Dot pursued, referred elsewhere, or decided in favor of the mie Q'ler (e.g., Penn Mie in 1963; 1988). Several major mies in the Central Valey have extensve hitories of regional that, in some ca, exceed years. Conversely, actve mies pemiitted by board to comply the conditions of as at for contiued operations. Reguatory have since the pasage of the federal Clea Waler state Porter-Cologe ads, although some the impedents stil :remai In many intances, governent fidß have been used to 1"lstal control measures. projec have resuted in reduced mie loa.ds (e.g., Waler, Balala mies) but most attempts have nor always been so successfu priany due to ineffective technology. . A water qualty surey of mactive mies was conducted as part of the regiona board's Basin Plang procs to obtai inormation on pollutant loads contrbuted by Valey-wide sources (which alo include permtted agrcrtual, and urban alow us to pnorti sources of downea ruoofdischarges). A water quality asessment usmg load estiates wi impaients and help to focus coOOol eforts on the. major contrutors. The amulatie input of pollutan from poin and non-point som-ces has rested in periodic objecve excedance for copper, zic, cadmium, and lead in the Sacramento-San Joaqui Delta/Estuar (CVWQqJ. 1991). The regional boæ-d is ,rpo~ble for developing pr,;grams to reduce overal metal loads to th Sacramento River and Delta. AJoug inctve mmes contnbute sutantiy to downstrea ooinceDtratons, several questions remai regadig previously unsuyed mies, waste rock nmoff¡ and reservoir mass balance inormatiol1 Thi study attempted to assess the regional water quaty impacts caused by inactve mies in the Sacramento Valley. In general the objectves were: loadi from known and previously mimveyed major inctve mies. 1. Estiate and c the meta 2. Detere the oontn1nitions from wate roc ruoff. 3. Assess the mass balance of metål comig ino and leavig major reservoirs. The rests of th study show that most of the major ines with perenndrile had been previously sureyed; . The copper, zic, and cadm .ca from mi10c in theSha MWg Distrct The lsrgest smgle ~~a~:~tr=S:e~~::s~~:~~~~;~J~:~.31i=~e =~s~xii~~ ::is~tb&~:;~ largest loads of drai.'. age. due to runofaid seep...aagefiom Was. e roC stormeventsigncay increas the receivi pies dun th. e. wetse.. Ol1.Wast6 roc ruoff ca1;ed.bY a3 mch steam COn.eetr~ of ~ndedsolids Ctpper, and ZIC. Waste rock materi was prevalt at al mies sueyed. Dam releas water qualty is probably iDueìiced to some ement by uptream mine inputs 2 FORMTION m. l\U:Ñ"E Mie drage as a result of pas mi actvies tht exposd geologca deposi.ts to the natual weath~ attrbutes of water ai. Air Cl enter an underground complex as advectve drafs and barometrc "breath" thoug and manade openi (e.g., shafs, vents, fractes; Shwnate et al,191). Water enterg the i:l system origies as raial seepa.ge and ground waer (CH H'il 1984). Ground water flows intercept tunnel pasgeways followi the path of leat resitace and eventù become surac dichges when the interior floods to the level of the lowermost awL. Water rarticipaies in the wethrig procss as a reant, reacton medium, and a vehicle tra.portg solubild mieral out 0 the complex. Th humdi wi a mie and large surface area of roeri exposed to oxidants are ideal conditions for reactve ore to degrade (Shumate et 1971). The volume of water dicharged vares between seaons and yeas an outfow loads ar stroogy eorrelated wil: anua precpitation (Heiran unpub. data). Dramage alo orites at the siice of a nie complex whre waste roc ples, cOmposed of e:acted mieral deposits, have been duped and e~osed to same weatheri force. The off-site movement of pollutats material is largely lited by contact with water from source such as precipitaton, strea, and released from waste rock sprigs 1' product ?f. waste rock weatherig Cl degrade water qualty in th same maner as adit releaes - elevated meta, tubidity, or aciwty. A. Acidic Pyte (FeSi), the most common iron . in Acid mine draiage is generated from the of pyrte. Calorn (COMG, 196), is snsptile breakdo\V becuse of it hi oxidation (Doyle andrrf'.P Miza iron.The 1989). is clved topotential for sulliiTÍUc: ::nò When c.icosed to an oxidi envionment, the ferrousdisiide bond generaly accepted mecanm for acid formtion is represented by the followi pathways (from Singer and Stum, 1970): FeSi(s) + 7/202, + H20"';" Fel+ + 2 SO¡- + 2. H-I Fe2+ + 1/4 02 + H2+ "";: Fe3+ + 1/2 H20 FeS2(s) +' 14 Fe3'¡ + 8 H;iO ::;: 15 Fei+ + i so¡- + 16 Ht (1) (2) (3) The Reaction pa.W4i¥S land 3 have been p..ioposedto desc.'be th overa kietics inv. .olved in the br.eadovm of pyrte. diect pa,thway (.1) involves 0 act. dir. ectlyonthe pyrte cr. stal wh. .. te.as, aneindied. paanwaY(3. ) goes .forward only when the iron product of. 1 has. oxdid tosuQcient quanes vi iwhn (OnyeQ, 1985. Oxen serves as and the proced onl an abunt supply of both water and ca oxdan in :i prodnÇÎg a,çi .at rates typicaY observed 0X... .. en are avai.' ..ble (.T.aylor et åL. ~ 1984. ; SuIv. anofet ai., 19.88a~b)...O.XY ens.i~d elVto asthe~fornation the vltimar.ecton accptracid that hydrolytc reaclçDS .lthat ofsu1c a series se into. . cleaves i. iron-sulde bond (Noråsti0m, 1982). There are mayche .. physica and biolo~factorstht caafec the ra.te ofpath""ayl. includi temperatue, resdence tie of die water, plio! themeaiwiand the.pr~i. 'of miáobe5. However, the grai si of factor controDi it's. rate. Fiamboida pyrte crta les th 0.25 micron are much more a major pyrte is thought. to be. prone to breakdown than iarg~r, euic foris (Caccio, 1975). Equan 3is caedtht indiec pathway l:causefemcirontFe3+) act as the axdant wbichis prodd vi~ conversion from, the reduce form lagelybya.bacteraD caa-y;reacttln2). The reuce~esofiróD (Fe + - ferrous) 3. Th~æOferr;liisiotliirqp(;sedbypathway 2 issto~Y is ~tia1Y present ~apr~ucpf rectons.i and fac:tated .bY.a resident mii:Ob1alCQUD toltrant-oflowp!warS i(:rever, 1988;Sniger andStmUl; 190, Erlich, rates. and p~~~, 191¡ Noikeeta1.t~; .~va el.ai., l9a). RactonPllthway 2,caproce~diiorgaeaY 19p.;M.01I . disolved oxy~nprestip waerisllïi~~initse1ftoperptul.ethec()nver51n at obsered but tlai0un of In the pr. esençe 0. facidOPhic.. . bacterilhe rille. of ~ ..c;."b~.acc. . ra.. .. tedbyUP.. to6orde.r. 5..0.f ma. .~tu. di-overth.. eÍ1orgac oidiec patwayand isgovemebythe coocewatC;111òfreucd.irnald.i¡ofthe nucrob1å1poPultion. Th in ferrc water thStig1y favprtheforwardleêôon of.reacln.pathway 3.. Thert;fore, an generated. tò le\.è1s. in ion ca. be aqu~us exianmen! pathway 2 is consdered to be the rae determg stepi. the productanof acid. .,Cdrr"'."'l!rt. .di""..¡,¡aJ."".,;.a¡~1i Mt'1~," J..~c~) an autotropbi~ usin (Wic.h1ll.czand Øi.r.ß3. nic. caOO. .. ...Jstr. aiii. $ U,.... oz...19.8.11' Glemoaiitat.o hi. 'cb..act. erahå.. ve.~eiiis...o.1aed.as. th we .'. .f~rrçusoiiu?nanghenctbe Ja~ûonofAfimidram~ rmatiø~ .~dîoxideis usd 11.a\1 ~n idenedastleiiriPâ1slr1Iolvedand w~respeatedPasd. . asa rooô source .V. hichis DletbcÎlici...y.mcorp.... ra.. '. ed. wi. . tn.er. deriedfrQI ..tbeo* . ..... . .01 di.... ale. n..t 11. Q.. iL.. '. us ferr .. d 1". thooxidan. th.. e... ..rateatw.. hièh. tléco.. .m.~uiwer. 0.(0. ... ..t1. .~OUId.S.'. and .ßQlmeril97.. )'. .. .'p...ar~~rø~ce..... .00..... mpoimds and Optum metabo1iceffClnc.1Sg~eral.attaiedwit1apR rar of2.o.3S (Nalaufand:Frater, 191)-utca var wi ~mperatueeies (Maonad and Øar~1970). .Aou.llutrelltsCC)lJl besubstìtutef ôl .anenergy SQurce (Noik etal1.83), therr su.m watersabovepH6ar lied byinter-staioompetion. ' '. hicmicrobesare 'Wth "Wide ~angeofabilesenabllgllem tosur~ine7e~een.vùonentsbuareQi ... . . byspeciii neutral stieams;MiandMaloI)11987. generalts better equipe tOcoOlpete under condions that areniore faveral)le (i.e., in The aquc mî~obeb¥Cmeatch~ tosta.tioiiar obje?:~ the ~trea.bed~dprolla.gate in layers Q.acdOla1d and Oark, 1970) w1ichwere found t(. be more. metllbolicåy acüeQi thei pla0nu: counerar ~anà Malory, 19&1). The oxdation of ferronssulateis though to oc at the cell wal or membrae (McDoidand ßlak, 190). suldes (cog.. CdS, Cu, znS) oxidid m product of oter The products of pyrte oxidatioi. as well as the disolution acidic solutin and are tranrted sim fasn, concentrte to high levels in the 3 out of the .me.cplex ma singly 1988a). Mior amounts of disolved compounds (metal, sulate, other of basic iron sultes (e.g., copiapite, jarosite) and ca be seen as red complexed or imric state ("diolved"; Sulvan ions) crstal as secondar miral in th to yellow staig in the impacted steam waers, the disolved compounds become les solule and precipitate As pH increass of iron hydroxdes. Between a pH of 2.5 and 4, iron intaously to standard (pathway 4; Jenke et aL, 1983). out at a rate that is fonns mase Fe2-:H + 2-3 197; Filpek et 1987). =:; Fe(OH):;(p) + 2.3 Iron hydrmcides are amorphous in natue (as opposed to crtale) and are vile as orange, streambed deposits. Other metal alo precpitate as hydroxides when their individua supesatwation points are reached. Howe,elements such as coppr, arsenic; and zic are thouut to be removed from solutionpriår by coprecpitaon and adsorption proceses tht accmpany the format of feir aid ferrous hydroxdes Meta ca adsorb to the surce of form colloids via tlecto-static attaction (Johnn, 1986). Co-precpitation ca alo scvenge meta whc:i they are occuded with the f~mug colloids or are mcorprated as part of the matr (Har 1982). Arenic, present ás an oxyanon, diectl inte¡nates wi iron out-competi and replaci two hydroxdes, resul in a coordiated complex (Haron and BerkhelSer, 1982). Th resultan removal rate of arsenic from solution by ooprecipitation is in diec prportion to the amoUDt of solid rormed (Chapma et 1983), therefore, very lie arsenic remai in solution after acid mile draiage undergoes 11 sh.. Alerntely, copper zic are solution maiy aUiaction ow!. Copper zicelectostatic are ly present as a~uo tht are weaker the forces involved in rem or anon (e.g., sulte) pais Thornton, 1987) and are aUiacled to, not mcorpor inoo, the fonnmg hydroxide material. The degree sorpion increas wi pH (John, 1986; Moore ancrSuther1ãñd, 1981). A: impacted waterapproaches neutralty, most of the metal have becme components of the flocculated hydroxides. The as well as other stream featues meta remaig in solution contiime to exchage with hydroxides (Vindom et al, 1991) such as the bed substrate, organc material and suspended particultes (Chapman et aI., 1983). B. Arnic Dranage Mie draie with high arsenic levels is assoated wi Sierra-Nevada mies locted in the Altgbeny.Downvie(mai area. Miers were afer un d gold ikpo th formed wi arenopyrte (As~) and cacaeous mieral . acid tyici Caco~; Ca1.()n and 1956). Draie from th area is disi to mine drage in that it is clear, ~f:s~~~~alle:c!~:d :~::~~ . ;:g~b~~~cl:~~~~1~n~Ji~~ll~:~e¡):I!::na:~=~ :J:~~i¡Bth~ ~s:~~: :;:r:! i:a:e~~:~ ~:i~:p:iilrta;~!¿S'i~:awi~ :tt:2 of::ls~~~~~d: less than...4 m V waers less toñc than thereduced valence species - arseIlte (+ 3) - which is present oDl in reducig mie draiage (low iron content), 50-90 (Moore and Raoorthy, 1984; Hem, 1975). In watrs notafeced by acid percent of th arsenic is elleced to be diolved (Johnon and Thornton 1987. C. Waste Rock Dr¡ii WAste roc ~ateridep()š.tçd ~bov~ ~d aJ undergoe oxidave weaerg when in cotact with watcr. Westcrock was presciit at iieatly al mmcsit. .. iitb 5tand ca.be ~~ .ofiivetblUdeo, gaguuiateñ (less valuable sunoundim.eral), andl~ftover ~ from:processore(U.s.EA.1986).~erâfoxidation and.oí-sîtetrrt roc. In pytisoìltbe.(tentto.geiuratellcidi.la~lYeot.onedby . .. ... ... r waíer, tbeprence.of cacaous mater is adequately is liedtoperöd ofprecitanvienno other mineral (mal qaC()3; U.S.E:A, ~)I and~ci si water soUTc.s(e.g.,.. . Ø"eeks) are in cantactwitl waSe (Orcco, 1975). 'retop6-14û:cÌies of aerfîedi()provi~e oxy~en at levelssûcientfoir diecox~ti (Gpo .l,0). D.ursdK pel'9%soluDle :products of :~:tia1;:~:l9l6~~ci1sa:~Jl:itai~~=t8~~ht~t.SurCtil.:~iiag~ií='~r~i::Ke~~:;~l:~~r: 1Q83;see~l:xi(l B). Thewtal pcilltøC(tentdQesnot . .siuarfisttlusheffects because òt er05ionat.~port material niorphology (.es and with M~uredl'åìalnmoffçoèffcintsnDe betwen 11 aid ?8percéiit . aad va Riche,1983)andraalclacteri.C5 such as inc:nstymiiidurtion (seeA1:pendi B). Intrted waterpasPie,tbougl wa rocnierial usuaY emanates with a ~er ~nutileveicompå. to $Úcenmoff due to theuicre~ed resdence tie .of water alowed toåpprQacb eqti1iralon 'Wth leachble aci and maa (Haries iandRicle, 19~). Simple erosonal force ca trport particuates andt1ir asated méalof-site regdles of the pH of th materi 4 MIN lV, CHARACTRISTCS OF SACRAMEl\IT VALEY ~ water qualty suriey was conducted between 1989, and .199~ to ases Ule polluta cpntnbuti0:i made by inaclÍv7 ines whch are dam or prospect with little m the Sacramento \r aley. There ar hundreds of mme sites m the Valey, some of potential for sicat water qualty degadation. For intace, there are 55 known mie clais in El Dorado County alone (SWRæ, 1972) and 161 hitorica mie sites in Sierra County (CVWQCB unpub. data). The number of mies included in th study (94) were lited to those lht were knO'Wor suspected water qUaty theats (see Api¡endi A for selection crteri). The goal included estiati utan loads and .asesg the impacts of inactie mmes without assumi¡ al indidua contnbutors had been and cbaracterld. To acheve th, the mies selected were those 'lth a hiory of heavy actvity and/or hi ore saples were collected and later analyz for severalheavý .ieta1 j1d arenic. AI mies with perei:al draige, water Conventonal parameters were meaured on-site at the tie of sampli (flow, Eei Eh pH). Sedent samples were collected at al mIne sites viited and a lited number were an for simar i;arameters (see Avpendi A for a complete descrption of th methods). Mies not well characteri du previous mspectons were monitored several ties over a 2 year period to accunt for any seasona fluctuation in flow-volumes or pollutant levels Those mies v,ith characterition data were not sampled becaus load cacuations and impact asessment could be made usg mies in the Shata Mig Disct). Several mies included in the sury were inccessible and the results of th are reported in Appendi C. virater is presented in Appendi A. Drainage Charcteristics Ûle Sacramento Valey. Mie locations iiealygrapbed in Figeiv-i show that m'Îllingwas not lited to;my one area of Table IV-I summares the physicacharactnstics and hitorica backgowid oImwes th suey. Inac.tie minesare were suroundi bi in. andmo1.ta. There si pervasive thughout the Valey outside th .ce basInAld into the map identification numbers r map ID. broadly defied m,ing zones in. the Valey (refer to Fige IV.;1 and Table IV-l for t.~~:¡J i6~t~~2f~: \j~~kI~~J),i~itl~~~o:~i~~te(~ttiIT f;~2!l~~~~;~M~~~is~~ ~::~ 6) western foo.th mercu mies (plates lQ.12). ,Atho~ not.i miesh~dv~renn aditdihag,s il. #s *57), and (Table IV-l), waste roc matenal Was observed atabost al mmes vited, Furer, hionca accunts and site l:~b~aI~êr~bi~e~_1\~rT~~J~=(~:!=Æ:::Ji~:;~::~oo;:~~n6~i~~~~:d~~r~I:C:~~~ in a greate l)-nti,for water quatylmpacts. Ths potential is and the sUtfacearça exsed to. weatberi results intersectg flows. . :~ma.ested when waste roc pollut are tranporte off-site into reivi waters d~ storm events or from attribute (e.~, product, mieraltt) of Sacrent! Valey mis and theidraiic qualty were hiy van¡Ûle. Valuale orebodi~ contai r,caÔDum, zic, an clomi inineralwerçmosmtenve1y mied gold, from the Val'y.~c1u~inerCl,arsenic, (e.g. Silverlal The genra the mid-180's to mid-:i?D. OtherI!r. diec:y' or.indiecY mied in siyer,sull;conw0)lds,and pai.p'x¡wents l)aie quaty r2lgedfrl.tl unpQn~~ spr water Mi~) tohiY 8.adicoutfowCOntai xr1..th pl)m r~ ,Wçst ShataPl$mctnw~Table IV~2), Previous stndiessenera1Y agr .tbatdiaiatc.dierence inwaterqui . Glltf0W .are.inY reÙ\tedto .theKeologic: maeup depth togromiâ water. UDdel'g,owiamira1mâyhave tlep()t~ntitoeasydeside, but an of undeilyigmmeral suracerek;asswouldbe absentifthe'\ter tableisbèlowthe lower-mOs o~. yarabity indiclar'liniity from -t~l: ~:rdadi~ miÌ:wiym::;la~â:~:å~;i~=;~~t=~xi:!i:àe~,~:i:Yt~~.r:~=~~eiö no pereiål adireleas) draige is . 'tOO.to iaal and avpI"øacht:Ì! âi sat:ationpóin At mies wi snowmelt ruof from waste rotklIateri ~i:?#~~~~t:~~¿~~a~i.~~at:=~~~~~~~"~~. .. cl~~#~~t:aa~~~; contJhighievels.of. mostcompounds~êlas~pc.zic, cadm .ot ltag.(Tablf.lV-2)... TbeFoot1ûllCopper Belt idenesa.reriesofnies siateOD a gelogkforDati1Q~ înGias~pyrte~~locat~atthewesternedge ofthe Sier-Ne~fi foothJ'g~beeeiir~ eleyaoD,of$l .. .. .feetMSL.. FoW"m¡~es iI.th belt ;. vited ~~m~~~e=~.~:n:::;~dt:i:tll~~tl~~a:~lr~~~:atf~fu~~g;~.Jl~t:v~~~ COunty). the Yub River Water$eØ) wa charact~d Draie from gold mines. in ile Al~y.-:oownie:vi1l area (lcated in by near neutral oulowand elevatetarsenìc1ev1s(TablelV..2,l. Th mieralog ofth~.arealibe~n~nsivelystudied cieposited ûi closeasociatlon with 1:wer¿ bc;causeof'te Jode-gradegold d~posits. MigjQûr de.cñgo1d vein carbCl.nate mlera and arsenopyrte fAs.e; Ca1s~imd Cik.1956). 'which pa;ve.1a the d.age maeu!:. Notablear.senic sources in . the areamdude the PlWKb~o AId)3msh Cr~kJ,esand thnse situtedintheKaaK Creek couned over 14( mi in thwatersbiinclurJgYuba ~6 to 1, River watersed. United States.F(KSI ServceperslleJ hae Kenton, and Oriental .(Dane~ pers. comm.). ~e are a3anumber of smaUcrmÏtS di:Fg in the watershed tht were not included in th surey ~. pen. comm.). Arsenic from these mUes rem largely in or the low irn content and near neutal pH ofthedraia.ge - arseJJc becuse efecly removed .ttom solution by bydroxde pr=piWes. Posie Eh iieasm:mennftb draiage solution in the downtrea receÌVg waters is known to be 5 '1\.-: ~ #llirr ii!Æ ~q ,~-. '4(' \, ~ Fj.J!' PIS. ~~..~\( ~~,""ílLY '1 .. ii*l'L" ..u..tr _y alt; iJ;ir y )j, m~tl~rr'~'~ ~~ r/ ~.\.L'IHV(~-; : I Iolit.!.-,:t i;.ml-r:-c: ¡, ! l~O.. " / i ì i r.. /'. ) I1 7 -..: ';'~.~ ~H \ ~ - - ) "Q~ \, ) ~ ~ F"nge lV.i MAOR INAcr Ml IN TH SACRO V ALY. MA lD. NUERS (I CICLE) AR DEF:"l IN TABLE IV.1. DETAI WATERSHE LOCATIONS ,A .PREEN IN PLATE 1-12 er SQUAR). ¡: :' l LEGEND BLACK OAK X l,tM S1 .. UHE Ai.~Eui~~ Ol$:i PILUKAN X. ,'.. ~a.;;p¡ - . "" UMî""'I1EIl,~_ (¡ lAfVE SQiJl 0"'_~""_D""~ ....:;~ ~lRA$mt*~t1mCliO~ . . x El DORADO . , ''0 '.1, 'll ~\ ',\,~ AL¡'AMS~A I . !;¡G 6 UZZRO , ~ l i. "- FUNNY BUG X ~¡$: PLATE 1. InacUve mines of the Folsom Lakewalershed. .. VAlJE'l VIEW LEEND l .. iJ~~~~~ -( _,._.s-iG(1"" lo_ o _ ~_mo..~ømJ; ....~. ~~l""-i X ...m PUTE 2. Inactive MInes 01 th Sear River / Dry Creek watershed. 7 SlERAA lilb,onolll.O ¡uvæ Lo lDl"li! i-ii:i¡,sr AKE . A SIERRA a\J o :x o 51,rro Cl1y Cf"Q:td liivl l)t 0 I SFANlSH l, 1/ ,i-"o,hlnglo" 0 Sls ""vodo C ll~ r. ~¡1ij CHAPIOW Lake W~à"'Olti n.ry~U ii I. ,pi 0.ß FiBI 't. -r ßANliR c. ;'1, '3 PLA"Æ 3. Inactive mines oj the Middle Fork, Yuba Riiier Walershed l UõGëUD 'X illlm£ .. IiwS.lITIA..~J~~ .."IK~if~$~~ oi.l.~ o Ol/T _~_l"""..ci." ._.~, _uw:mAlI..~ II tl' .. l' PLATE 4. inactive mlnas 01 the feattir RIer watershed. 8 R"servoi o I R I.er GOLDEN lAGLE Chi.. 0 X o PQl"tJdì~t . , , . .- ,", . , , , Silva Flal Ros.rvoir l l.GeND 'X "K¡si -( "'HE.Nil'rs.c:IJO~ .. l.OiAlii.I_O_' . ......llOQ'..,¡O o lln_ R""m£__"' ,.....:-' ~=lUa'mJi~li;c1lG PLATE 6. Inactive mines 01 the Pil Riiier watershed. PLATE 5. Inaclh/B mInes of the aulle Creek watershed. If ~i d i:è it n i:II EUliU m .sIt ¡¡ ~ ~H~h~ :i GI ~ "VIIDoH ~'" 7i .rii W c; - -. " g¡ i: E ii :; ~.. .E i. w ~-i g. .0 9 A GLADSTNE r;:i'':: 0 .. ltll~££í,~~ ooi.!liJrrl'w.~~ c iUl.AG~t o em"" ~fi~lM~O~ ....~~E~EF:i~~~ ffO J ,ct C Ill! o 10gotO,,'7 'TOMPSON. XI (/ . AFFlrHOUGH I I $I .1 . 'T . """" ROI,IlD BOTTM ¡. PLATE 8. lniictlve mines of the Upper Sacramento River watershed. .. " -- - '" 1: "" "" ~ cn '0 .rClCI i . ,:;CD 0f.. 1- "0 . :l. . i i .. ~ i 0 ft . ~ , i ;; ,,l , , - ¡¡ .x ., l! (. :; i: :l i 0 tiCD ~ * '" i G, -iG , Q -f¡ t ci CI ~ :i :¡ ," , . '" i' - '" , ~ l! .~ /1 " ~.,.l 10 '" .. .l o~Xi. :::i II ~ "t-' Ë Iil ifii ~.. U !IIl Ht. i w l!11~ ~~l l .:1 Cl i: i.. I il ~ ¡.yyøot~¡ tI .5 G! ~ -i ii l i LEGENll X uNttm .. W'AOruSEI~i:ll OlSAAGf -( Y1""".U'.SW1HAO=E $ &.Ultaol..i cnYfTO'i f'fVfF prat Cj¡¡~eTON £~Pi1!Yf(,,I~t:T' OAiHll.l. ÉXSIOH :x rOVON OATHllL GRANIIDA A Á X " /j :'J x. AElA X AlfA EXTENSION o R,IM Spring' .; PLATE 10. Inacl!ve mines Qr ltil Lake aerryessa, Pope Creek walershed. 'X j - MAHA1' KNOXVlLJ -.. 'X o ç."" x i:e¡ CHEf l nlddIO\Oo.O 'X ila E ~ INUH GREAT l- ..-;.'" WEi,l1¡aH ...., .....co.. .' ....;ii + LEGEND ._- .( wll_l$.~oi "' -i"'.-'-o Cl X w..nm -fWTJlWll~ ........... ~int-A DÆCT PLATE 11. InactIve mine 011le uke Serie5$li, Putah creek waerSleà. 11 ELGIN ;",;/ Alison ..~ CENTRAL È. ! WIDE AWAKE 'X ì .. :J , u;c£Nn I x ~~ .0 w.lHADI1..CCi~D~ -( _Al.~C_£ tt!iB.~ o cifT/ftw ReED Davis Cie1k -i 1I1M~ DIf ~'"...~.. lftYllSlfliw:Æ¡UJ.TKlU Jf -.,.. ñ) - - " x HARRISON PLATE 12. llictive mines of the Cache Creek watershed. 12 R...rV~ CONT -' '.. R£C!lV1NG WillEtt SEQUENCE Folsom Lake (7.5) Canyon Cr - MF Amrican Riv - GeorgétOwn i sh 21 sixteêl1 to one 20 Kenton 19 San Juan 18 span 17 Malakoff Diggin's 16 Chllmp'ion Fer West Lake Wolf Cr - Wolf Cr - (7.5) R6E A9, AU See i6~35 spencevl llc CUi poormån Cr - SF yuba Rfv . Alleghany (15) Nevada R10E Iliv KBnaka Cr - MF Yuba Riv . Yuba Alleghany (15) R10Ë At t egl1any see 34 11911 Alleghany Kanoke cr . MF Yuba R; v Yuba A llegheny (15) Sierra Sierra Set: 4 1"18N See 12 THN North Slln Juim R71! Sec 31 ¡18N Ya~hingtDn Ri1E See: 4 118M R10E lliV sweetlal' Cr - Yuba Iliv french (7.5) Corral Nevaa Yuba Rlv H\.f: Cr - south Yubå River Alleghany (15) Nevaa NINllda yes yes no yes yes unk unk all mill, no Au Arsenopyri te All ClU¡rti. chaicopyri te AU, cu Auriferous sulfides, yes yes nO yes yes cyanide flant, Stamp ml \ I Blarit nknown flotation 1SB9 1861 10 Stamp mill, 1883 plllnt Hotiition tube mil, 40 stamp mi \ L , Pyrite, chalcopyrite, galenii yes Ilone cyanid.. pliint Stamp mi It, sphiiler; te. gat ena pyrite, arsenopyrite1 unk sphaleri galena Pyrite, ar$epopyrite, yes 1862 1904 186- 1883 1860 1894 20 stamp mi II 1865 tei I ings pond mi ts, cUanide plant, 2 \ 60 stamp Sme L tlir Cyiin i de pi ant l,O stamp mi II pl atlt Mi tl and flotst ion Stamp mi t I plant flotation Ball mil l, flotation ~lant Mi II 5 stii~lp mi LI yes no no un!: DISCHRG? ONSITE PROCESS -UP PERENNIA( ~ pyrite, ch9leopyrite, galena no cu, Ba BarÎ te Au See 111.12 Nevada city Au yubá Riv . YUba Rlv Ti6N RvE R9f li ttl.e Deer Cr - Deer Cr . SF Col fiii( OS) See 16 T16N Nevada City AU R9E See 26 116N Grass Au RaE i:ree~ nSNRoE H2:ì04 See 35 T16" sulpnur HQ little tUppr tr - cUppr Cr Colfax OS) D~ér Cr . YUOIl Rlv Nevada (15) City te Gossan, chaicopyrite, pyrite, bornl te C i nniiba r See 21 T14N OBi ry Farm cu, Coppr sut fides Nevada . little Creenh~rn Cr · Greenhorn Crk - bear Riv Atsehopyrlte, ~6E Au, As pyrite, zinc sulphides Au pyrite pyrite CU, Au Chblcopyri te, pyrroti te, Au pyrite hemtite, sCheellte, pyrite See 13 T13N Dairy farm cu, Chaicoprite. cuprite, R1 IE See 6 T1 1N R10E Sec 34 T12N Foothill R10E Sec 3 T121l 1121l R~OE Valley Au Ag RaE Valley See 28 T16U Nevada City Au Grass Valley (15) a.5) Câmp I'lli' blest Hill Set .27 34 Garden 1l9E See 3 n11l T111l RBE pyroxeni te, garni eri te W. Foothill Cv,Au, Chl'lcopyri te bornl te, Sphalerite, pyrite, See 29 ¡1 IN W. Foot"i il Cu,Au, chmlcopyri te, selene 211 RaE chromite, dunitei Cr Sees 21, 28 Flagstaff eri, hemat i te te,arsenopyrite,st ibni te,esl Cu, Au pyrlte,chelcopyrite,spheleri DUCT ORE MINERALOGY Ublf Cr . Rear RiV Grass (15)Valley Bear RiV little RiV littlø Dry Cr - DrY Cr . Bear temp ~ Nevada 9levada Ilevada 1S B80Mr Ilevada ** WATERSHEO : Yuba River 14 Uva Cilp 131daho-Haryland 12 E~irE! 11 SpevH le Placer Camp Far West Lineoln (7.5) Folsom Lake (7.5) ELDorado Ròek CrGO~ - SF Amt i can R I v - Garden Valley It'" C'r - Dutch cr -Sf Amriean (1.5) 9 Valley VieY Placer coonCr - Feather Riv 10 DBi ry Farm (1.5) Carden Vall ey colom a.5) a.5) pilot 1m I (1.5) Pilot Hill (1.5) R10E Shingle Springs See 3 T12M foothill El I)rodo J.ittleSeHor Cr - B;g saHor Garden \falley ** WATERSHED i Sear niver/Dry creek B Alhaftre 7 EI Dorado E.l Dorado ELDorado Johntown Cr - Dutch Cr - SF !\rica" Rlv . Folsom take 5 'Black Oiik 6 GeorGiB Sl ¡de El Dorado ~astlngs Cr - SF American Rlv . fol£îOl lake El Dorado l1F Amèrh:an Illv . FOlsom Lake E I Dorado Folsom Lake 4 L ilyama 3 PilI ikan(areàS t.I 1) Z Big Buzzard 1 FUnnyl:g Ël Dorado \lèberFolsom tr . SF American Rlv . Lake ** ~ATERSHEO : Folsom LaKe I D MIllE NIIME ia TITLE (MINUTES) RANGE DISTRICT U~GS GOADRANGLE ~p- CHAIlCTEIHsilcs. 1/ Table IV-1. SACRAMENTO VAllEY l~Ai:TIVE MINE ll Yuba Riii - Yuba Rìý NF Yuba Riv - Yuba Riii sierra Sierra ,i i- i'lums ~e& - Lake Almmnr Rl0E shsstii Dunsmuir OS) Dunsmui t (15) NF shotgun Cr - Saeté~nto Riv Dunsmuir (15) - shasta lake Sacramnto Riv . Shasta lake R iv - Shasta lake Indian Cr - Castle Cr - 41 Coggins Shasta Shasta LIttle Castle Cr - Sacramento ,,5) 1l1lycl!lun See 22i27 Dunsmuir 137N R:i\. See 16 T38N Dunsmuir MW R4W See: i (, T3811 no un!, unk no unk yes unk 110 unk yes yes yes aler~te,gBlena eii Cu,Ag Cr Ch;-omi te None No.'1e Cr Chal copyr i te, borni te chalcopyrite. galena Cu, Au Pyri te, sphBleri te, cu, Au Chalcopyri te, Borni te chslcopyri te, bornite no no no no no yes no CU Epidote, ~arnet, pyrIte, no ri te,pyrroti te, en leoc i te, sph 18B1 1£175 1913 None chrOOite mi li t"i IL and cyanide plant pllll't oil flotation 1942 Stamp mi I i and 189-4 5 stamp mill unknown mill, crusher Flot~t ion 1915 plant, ball 1860 60 stamp mi i I 1851 None ball mitt 10 stamp mil l, cyanide mil I, cyanide mi It Rod mi i L , Unknown Uone DISCIIRG1 ONSITE PROCESS 'UP ~ ~ cu, Au Chalcopyrite,tetrahedrite,py yes See 137 T36W Haydl! Hill Au R9E Mtn Meadows Cr - Mtn Meadows ~estwood (7.5) See 29 T2eN OroýH i e lake Lll!:en ** WAtERSHED : Shasta Lake 43 forest Queen Gènessee Feather Riv . NF Feather Rlv . R11E Creek 40 Golden Eagle lassén 42 Castella See 28133 T2711 R f1E See 14 T26~ Genessee R11E Lights Cr - Indian Cr - EBNF Greenville (15) See 17 T27N lights Rlv Silva Flat Reservoir - EF Juniper Creek - Pit River ** WATERSHED : Pit River 39 Mountain Meadows 38 superior-Ehgel Cr - EBNF feather - NF Feather (15) Peters Cr - L.ights 1:1' -Iriilin Kettle Roclc EÐllF Feather - NP Feather Rlv ~eather . NF Feather Kiv (7.5) Kosselkers Cr - i.ndian Cr (7.5) T251lRilE See 14123 Genessee Sec 7 T24N Genessee R12E P luras P\ums WF Davis. Cr - Davis Cr- Geneseé Valley Plums Fliiittie\" Iti v - OroviH e lake - E.BlI~ Feat"l!r Rlv - NF a.5) Lfttle Grllzly Cr - Indten Cr Mt. Ingalls LalcéOl"ovH Le 35 Rewiird fl7 37 lueky S Malachite, azurite, Pyri te, chaleopyri te, arsenopyr ¡ te, 98 leon Andes i te Malae" ite, chalcopyri te tll1lrti galena, pyrite, chlorl ite, serpntine TtlytorirCr - Indian Cr . EBIlF Greimvn le (15) See 34 T25M lByLorsvlll cu,Ag, pyrrhotite, chalcopyrite Werder' Indian Cr - .EBNF Genesee VaHey 36 Beardsley Cu Feather Riv - Nf feather Rlv - R10E e Au lake llîh orovH te R7E QrovHle Mountsin (15) R5E UUlow Cr . MF Feather Illv - Buch.iiike' (15) See 34 T23N FrB~ier Cr - NF Feather Riv - BIS, Bend See 8 T21M Oroiiille Ll'ke (15) t2211Ri1E Ao Jømison Cr - Mf Feather Rlv ~ Downieville See 23126 Johnsville Au little Botte Cr - Gutte Cr' Paradise (1.5) See:3 T2211 pllimas Plums PI UlS Butte R12E R1ZE See 19 T2011 Sierra city Au See 29 T2011 Allegheny Au, As Sec 12 120M Allegheny Cu R12E R12E See 1 T20M At teghany Au 1110E See 1 T18N Alleghany Au See 23 T21N R9E T19N RiOt: Audferous Ilrscntlpyrfte, DUCT onE M1NERAlOGY ~ see 171 Downieville Au sacramento Riv R3E Sièrra City C1S) (15) Sierra City (15) Sierra City (15) Sierra City 34 Walker 33 I ron Dyke 32 Cliini Guleh 31 Big Bend 30 Plums-EureKa Plums ** WATERSHED : reather RiVer 29 MineraL 51 ide Butte II Yub'Rili - YUba Riii IIF Yuba Riv - Y~ba Riii Yubi Ri" Yub Riv YI. Rív - Yuba Rlv Buekeye Raviné - WoLf Cr - MF AUeghari (15) Sierra Sierra ** WATERSHED : Butte Creek 28 Coluio 27 Sierra Buttes 26 Zuver 2S Sierra Hómestake sierra Päts nulch - Slate Cr - MF La Porte (1.5) Yuba 23 pick & shoveL 24 pIUlago Yaoruff Cr - NF Yuba Riii - Goodears Bar Sierra 22 Brush creek Yubs R iv (7.5) RE:CEIVING \.inER SEQUEWCE TITLE (MINUTES) RANGE DISTRICT USGS QUADRAN ~p- CllARACTER I 5T I CS. Table IV.1. SACRAMENTO VALLEY INACTIVE MlijE CONTY ro i 0 MINE NAME 2 n ,. Wast saua~ cr - Shasta lake West Squaw Cr . shasta Lake West Squaw Cr . shasta lake Little Backbone Cr - shasta Shasta shasta Shasta shasta 46 Keystone 47 Early Bird (15) Olney Cr . Sacramènto Riv Redding (7.5) Seei(SW 17 131N Andrews Cr . Ctear Cr - French Gulch See 18i19 Sbcrllmênto Rlv (15) T31M RoY Andrêws Cr -clear Ct . french Gulch See 18,19 Shastll lake c R5W Harrison nùlcn . Ml Cottonwood Chenchenulla Pic see 3i4 cr . cottonwood Cr - (15) ¡29M R10W HFBeé!lùiCr - 13é!l!lUl tr - ÐubakêllB Mtn See 5 T281l Shasta Shasta Shastli Sliiistä 60 Yankee John 66 Nol:lé ELettric Tehama er.S) !iF Elder Crlr . Sllcramimto Riv Riigl in Ridge (7.51 Raglhi Ridge R7W See 17 125N R7W See 17 125N cottonwood Cr . Sacramto Riv (15) R10W Sacramento Riv Sacramento R1v, (15) T31N R6Y 65 Grall Tehama !iF Etder cr - Sacramento Ìliv ** ~ATERSHED : Stony Cr f elder Cr 64 Roun Bot tom 63 MidìlS 62 sHVèr fallii 61 White Star Shasta Olney Cr - Sacramento Riv . Reding (7.5) See 8 T~1N Shasta 59 JeL (15) Platina Gulch llarri son 19o Cr - WhiSkeytown lake (15) R7\ Gulch S1gel'amento Riv 58 Greenhorn 57 i ron Moiintllin i33N R6\ Vi llow Cr . crystal tr . Clear French cGulch See: 31 133M French SèC 34,35 Y. Shasta R4W T33M 1!i:1J See 34 133M E. Shasta See 10L'1 E. Shaßta R6~ Gulch spliileri te Pyrite, chalcopyrite, bOrn i te, quartz Pyrite, chalcopyrite, Spla Lori te, chalcopyri te sphalerl to, arsenopyrl to Quertz, pyrite, galena! Chalcopyrite cr Cr Cr Au I i:e ChrOli te. serpent Ino ChrOli te. serpent i ne ch rOl Quartz pt,rite. c ,a lcopyrite spha erite, M,AU ietrahedritet galena, I\g,Cd eliali:oci te CU,AU, pyrite, chaicopyrite, /\u,Ag cu.ln, l\u,Cd cu CU,ln, Au Cu See 18 133M ~rench sphalerite CU,zn, Coppr sulfides cu Au,M Sec \3 133N Il. Shasta 'R6W Pyrite, chalcopyrite, sphalertite, galena, covell ite Ag, CU,Zn, Cd,Au CU,Zn, pyri te, chalcopyri te, ln, CU, Cu, Zn Chalcopyri te Ag,Zn Cu,Au, copPr sulfides tetrahedrite, born; to pb,Ca chalcopyrite, galena, totrahedrite borni te cu,ZnJ Pyrite, ßphalerite, Pb,Cd chalcopyrite, galena, CU,in, Pyrite, sphalerite, Au Y. shasta -- DUCT ORE MINERALOGY ~ sec i8 T34M W. shasta RSIl 134'1 RSW Sac 29 30 R6\. Shasta Freneh Gulch (1.;) Project City MiUvUle (15) (15) Frene:h Gutch (7,5) Shasta Dml Líimoi ne (15) Lamoine (15) LamoHie (15) II. Shasta See 32 T33M IJ. Shasta See 1 T33N R6i. Shasta Dall a,5~ R61J See 12 133" Y. Shasta MY (7.5) shasti Dam (15) frencli Gulch Spring Cr -' keswick Res - EF StHHlllter Cr - Stillwater Cr- Sllctamento I'iv Saeremto IIi" Riv L itHêÇow C.r .. eow Cr - R6W See 10 T33" W. Shasta See 14 T33N W. Shasta freneh Gulch (15) See '5~21 T34l1 R i. 90LHbokka Mtn E. shasta E. Shiista 13411 R See 16~2 (15) BolUbokkli Mtn TITLE (MINUTES) RANGE DiST~ICT USGS QUADRANGLE ~Hip- CHÄRACTERr Sf i CS. Table IV-'. SACRAMENTO VAllEY INACTIVE MINE Shasta Shasta Shiita lJiskeytow lake - SII1'8mento Shasta 1:1 ine Golch . C1êar Cr - Shasta Spring Cr - Sacramento RI~ Lake Lake Sacramento in,,_ Upl" 55 Afterthouht 56 Thorson 54 Gladstone 53 stOWlL "... WA TEl(SHED : 52 Golinsky 51 Sutro 50 MèIth 49 Shastll King 48 llalBldiita litUe Backbo Cr - shasta West Squw Cr - Shasta lake Shasta Shasta Horse Cr - Shasta Lake Shasta 45 Rising star Shasta Town Cr - Shiista lake Shasta 44 BUlly Hill lake Li ttle Backbone Cr - Shasta REtelvtNGYAfER SEQUENCE 1 Ð MUlE IIAME cooim ro 3 PEREIIIW\L - 'S no no yes no yes no no unk yes yes no yes no yes yes yes yes yes yes yes yes yes yes Unknown cyanide pLant 20 stamp mill, Unknown pliint sedimenteti on plant Coppr mil I, cyen; de FLotation Unkiiwn plant, smelter Flotllti on 30 stamp mi \ L Unknown near Kennett 19'5 1900 1879 19D3 Smel ter 4 1900 mi i es away Coram SmeL ter near '890 IJnkno~r!1 plant flotation Smel ter, 1860 5m1 ter, 1860 flotat ion plant DISCHRG? eNSITE PROCESS -UP Gtenn Glenn COOY sui fur Cr . Bear Cr - Cache cr Wilbur spri ng Grizzly canyon - Hiirhiy Gulch Wi lbu Springs wHbcr Spri ngs (15) Knoxville (.15) Col usa Lake Loke sulphur cr - Bear Cr . Cathe Wi lbur Spring Colusa Davis Cr . Cache cr Oiivis tr - Clchê Cr Yolo Yoto - ci!e creek Grizzly Canyon - Harley Gulch 85 Andrson 84 Big injun 83 Ilh;¡ Chief 82 Coppr Prince 81 \led i: ephal't 80 Manhattan aear CBny~n Cr . putah Cr . Anderson Cr . putah Cr . Lake Lake lake Bèrryessa lake. Berryessii ll!!rt~s8a ~nderson Cr . putah Cr . Lake pi.tah Cr . lake BerryeSSa Putah Cr - Lake BerryesS8 Jer.tcho Cr - lIi.tiig .Cr . Beri-yeasii IIl1ting Cr . Putah tr - lake LIIKe Lllke Napa Napa 79 KnoxviHCl Wapl Knoxville tr - Eticuera Cr Lake Betryessii Pines (7.5) Uh i Sl'èri og P ¡nes (7.51 \I i sperhi9 Pines (7.5) Yhisperiíi p'hies (1.5) Uhispertng 05) (1~D I.orgiin Valley Morgan Vlllley Horgan VaHey (15) Knoxvl He (15) . Càche Cr (15) (15) sulfur tr . Bear cr - Cache Cr Wi lbur Spring (15) suipiur tr - Bear Cr - Cache Wilbur spring Beer Cr . Cache tr (15) WF sulphur Cr . sulphur Cr. Wi lbur Spr ins Coluse coiusa colusa Ch~Ol¡ ChrOlÎ te no no RBW See 35 T1111 Mayacmiis RBW See 35 11111 Meyacms R8W See 35 T11N Miiyecmas 1l7W Sec 19 "1'111 ~5\. See 3 1111l Knoxvlll e RS\J See 1 n1ll R4W See 1 T1111 Knoxville R51J See 35 T12N Hg 1\9 119 Cu 119 119 119 , pyrite no Cinnabar, pyrite, calcite yes Cinnabar no Cinnabar no Azurite. malachite, sulphide unk c i nnl'bnr Cinnabar un\: no unk YeS no no no R5ti C; nnaba!" Cinnabar cinnabar i:innebar no no unk yes Hg 119 119 Hg su ph H!l(AU, Cinnabar 9 cinnabar ur ~,sui Cinnabar and 1875 1863 1873 '892 1863 furnace! furnace 0- retoti: !'Ipe retort Rotary ki ln 1916 !loury furnace furnace rotary p' pe 0- retort i Scott furnace. 1862 eycl on dus t coUector rotary kiln, pIp: furnace Scott furnace, 1862 furnace, smat L Large Scott furnoc;e mi lls, retort Hunt: mlton Sta~ and Retort lJ-Retort rotary severa L ;) Scott furnaces, Knox-Osborne, Mon!! DISCHRG? ONSI1E PROCESS -UP PHlENllU\L --~-- nm R5W Creek See 2S 11211 Knoxvi lle See 32 114M sulphur R5W creek Sec 32 T141l SUltiur R5W R5W Creek See 29 T1411 See 26 11411 SulP\ur R6W Creek See 29 T1411 sultiur R5W Creek see 29 T1411 sultiur R5W Creek See 13 T14tl Sulpnur HighlandS (7 .5) R~ su phu r Cr (15) Cr . (5) C i eliI' lake Oráin ~eservoit - Stony Cr . colusa Cr Cr DUCT ORE MINERALOGY ~ --",- -,",=-' clearlake See 6 T13N Clear lake H9t Cinnabar, marcasite, pyrite no R7W Watson Cr . Griiistone Cr . Clr~ (1.5) Ston.Gr - a tatk Butte Sec 25 T22N R7\ _ stony tr - ¡;oltlSl' Oral ri Creak - Black Butte Reservoir See 25 T22N TITLE (MINUTES) RANGE DistinCT USGS QUADRANGLE roP- CIIRACTERISTICS. Table IV-'. SACRAMENTO VALLEY INACT IVE MINE Heif.er Cii cr - WI' stony Chrom (7.5) RECEIVING ~TeR SEQUENCE .. WATERSHED : Lake BerryessB,putah 78 Harrison n Reed 76 Turkey Run 75 IItt 0' 74 Wi de Awake I- 73 central 72 "'amanita 7t Eimlre 70 Elgin 69 Sut fur Bank lake *~ WATERSHED ; Cache Creek 68 Slack Oi~mbnd 61 Grey Eagle i 0 MUlE NAME ii 4 St. ~ßrys Creek - St. Hel enii liike ~ 94 Toyon 93 Grenada 92 Aetna 91 Qat iiit l Extension 90 Aetna Extensl òn Jeme!!. Cr - Pope l:r . lake Napa Reservoir (7.5) R6W Detert See 34 T10M H8yacmas Reservoir (1.5) R6Y Datert See 34 T10M Mayaemas Reservoir (7.5) R6Y Oetert See 3 t9H Rêservoir (7.5) R6Y Detert See 27 T10N MaY6Cmas Reservoi r (7.5) R6W . Springs Detert See 34 T10H Aetna Reservoir (7.5) R6Y Detert See 33 T10M Mayeemas ~ CInnabar, pyrIte yes Hg IIg "g Hg IIg 119 IIg Cinliiib9r Cinnabar C i maber Citiabar Cinnabar, ml lleri te Cinnabar, calcite, pyrite sulphide chromlte) mil erlte (nickel Cinnabar, ser\entine, no no no no no no yes mines areally located on Figure IV.i. Mineral formulas, names, and abundances iii can be found in Table F-l. to 1937a~b, 1936a-b. 1942, 1946, 1947a-b; and CSM:a, 1918, 1915, 1916. Map Identification Numbers correspond , Scottl 1ß73 S!l n furnace 110m fUrfllces 2 ll-retort furMce:, mill, rotiiry scott furmicc, rotary fumace 1864 SCQtt Furnace, 1867 furnace Rotnry pipe 1902 furnaces Scott and pipe 1895 furnaces furnace, 4 1)- retort and Ilerreshot f Br ic1: DISCHRG7 OilS! TE PROCESS -up mt mt IIg, cu Cinnabar. serpentine, pyrite yes 119 DUCT ORE MINERALOGY 1/ ThemiiienlIogÎcal cbaracteristics of the mine.'iwcre taken from DOM, 1957; DMG, 1966, 1970a-b; GJMG, 1956, lIerryessa Jams Cr - Pop Cr - Liike Berryessa Napa Berrye!lse James Cr - Pope Cr - Lake Berryesiiii Ja1'esCr - Pope Cr - Lalce Berryessa James Cr - Pope Cr . take Berrye!îsa Jiimes Cr - Pope Cr . lake Napa lIapa Napl Hops Reservoir (7.5) R6~ 88 Twin PeaKs Nape BatemnCr, - Jbmes Cr - Pope Cr - Lake 6erryiissa Detert See 4 T9M M!lyacmas ReservoIr (7.5) R6W 89 Oat lIil L Miiyaèma Detert See 32 T10N Mayacmas (1S) T1DN RIW Mount SL Melena See 16~~7 USGš QUADRANGLE TUIPTITLE (HI~TES) RANGE DISTRICT Table IV-1. SACRAMEnTO VAllEV INACTIVE MINE CtlAlll\CTEIH STl CS. 87 Corona' Napa James Cr - Pope Cr - lake Berrye1l9B Berryes&1l Creek - Putah Creek . Lake RECEIVING YATER SEQUENCE COUNTY ** WATERSHED : Lake Berrye9911,Pope lIesterntold/neli 86 Great i 0 MUlE NAME I\ 5 Table IV.2. CHARACTERISTICS OF SACRAMENTO VALLEY MINE DRAINAGE OR DRAINAGE INfLUENCED STREAMS SAMPLED (AVERAGES FROM TABLE t-l AND C'2). 9 Valley View 427 0.11 1.70 75 5,500 170 123,500 39 650 245,000 ..iO 660 15.5 7.08 3.1 0.18 "'1 375 "';; .:4 299 "', .09 229 8.13 6.66 1,9 .:0.1 ~1 4:1 ..1 2 .. 4:4 11 .:1 4.7 ..5 .. 19 ..1 0.16 "5 ..4 11 "'1 1.5 "'5 44 41 .:1 19 21 .:1 37 1 Î Spencevi lle 2/ 12 (Nevada Co.) 275 5.86 ì .60 14 Lava Cap 2.26 16 Champian 176 21.9 6.'52 17 Malakoff Oi99n'5 18 Spani sn Upper 16 to 1 68 2.30 5.67 240 2.92 3.50 0.2 57 0:1 0.7 4.5 .:0.1 .:i 193 3.8 5.3 16 6.2 1 267 2. ",o. ¡ 83 22 lJ rush Creek ..1 1 34 21 i 1 10 .:, 2.05 29 2,050 "'5 ..10 .:1 .:0.030 "', 87 .:1 .:5 137 14 ;:1 O. O~ 2.2 2 .:5 15 .:10 .:1 0.0&5 'C0.1 2.5 "1 .:4 0(10 "'i "0.03 0(1 n.1 -:1 250 "'5 ,,4 10 130 3.64 6.04 0(2 2.7 -:1 T. 44 Sully Hi II 0.85 4.30 .:2 248 ..1 5,053 45 Rising Star 2.66 3.30 865 130 :3 3,100 46 Keystone Z.15 3.18 78 9,658 47 Early Bird 11 0.17 2.50 487 99,365 116,400 48 Balaklala Main 3.SS Vii 320 42 '09,463 18.,800 27,692 172,308 49 Shasta King 11 Upper 37 0.3 2.25 0.15 2.20 300 level 0.04 1.79 2.09 2.16 23 Pick & Shovel 126 2.21 6.28 1.5 .:0.1 24 PI uiiibigo 235 3.27 7.90 264 .:0.1 28 Columb 166 31 7.01 0.8 0.55 7.34 34 We lker 37 lucky'S 0.28 2.71 \.ei I Lo¡.er :;0 Maimoth Gossen #2 51 sutro 31 F ri da.y'-towden 9.63 vn Uppr i.7 3.80 8.13 6~80 Middle lower Stowell 58 Greenhom Ilorth Middle South 183 70 II 1.5 17.3 i 00 31 166,675 104,920 6,547 ~50 31 1.26 ~.48 31 4,625 17.9 147 3/ 8,72U 3/ 213 1,008 883 257,475 11:9iO 410 387 188 1.06 0.23 0.45 24 27,035 29.6 6,615 26.8 3/ 93,000 "C1 104 3/ 19¡46tl. ..1 125 '3/ 2 14,000 518 807 2.80 44 94 11 3,077 91 32 20 12 0.04 i.3.4 0.49 5.16 0.05 5.74 10S 10 :69,333 30 137 160,000 424 171 135 8 665. 2..75 ..1 2,450 19.2 24.2 25 1,3.8 1 ,210 12,413 16,705 61:200 960 107 309 i53 3/ 58 900 63,800 0.86 2.90 30,000 340 "' 890 ..1 29 .:5 .: .:$ ..4 4,600 .:5 ..4 6 ..1 ,,5 -:4 .01 ..1 .:1 i 1450 .:1 rzo 6.7 ;:1 ,,0.1 .;1 200 .:1 ..¡ 0.19 7.83 0.16 6.33 ..1 -;0.1 3 .c1 59 ..0.1 46 .;1 -:5 1.200 20 0.14 6.n 0.5 6.61 3~3 "0.1 4.3 9 .:1 1S -c 107 .:5 92 156 73 .:1 7.00 .:1 2.70 91 172 0.33 7.36 ,,1 ..0.1 4 1 .. 34 15 .:1 0.79 2.5 0:.1 .00.1 33 0.5 lil "1 .:5 2,950 ..5 9,350 43 197 \.ater tunne L 120 0.3 7.40 2.87 5.73 143 0.24 0.30 "1 0.13 5.7 ..1 .:5 1,800 29 .., S3 "1 250 .:1 15 o 76 Turkey :Run 94 77 Reed West East .85 86 Great Western 87 Corona 1,450 64 .000 20 31 21 31 .:1 0.223 3/ 13 , 315 25 62 Silver falls 85 Anderson 334 349 31 24 45 12 ..1 25 298 0.88 3/ 2.70 55 Afterthoo.gli , spri ng Creek Oebris Dam 5/ 20 3/ 19.2 6.5 52 Gol insky 31 53 320 31 .:5 .( '" 1 Main 88 Twin Peaks ,,1 9.3 12.5 ,,0.1 .. ,ientot. I ost'p 1.9 iiverai¡e. 21 Below mine in LIttle Dry Creek. 3/ 1981.86 data. 18 graphs. ~Gant sU~senite indi~te tht arsenic is present larl?ely in the less toxic +5 state based on (As +) is 1 to 2 orders of magmtnde more toxic to aquati organs the arsen8te (As .¡~) species (Moore and 19&4). R.amamooy, Other mies in IDe Sierra-Nevada n!iie exhibited diar characteritics. The commodties mied at indidua sites included tac (e.g., Span Mie) clo~~mies in the America River watershed), and copper (plumas Copper ) mieral. ., were . . acidic (pH "" 4-6) and contai low to moderate levels of most metal aiialyzed -2). An ai vent at the large iold mie, Empire, dichged slighy acidic water coai~ only nomi levels niclæi and arsenic. Chomite was mmed in the America River watershed (Figue rWl, Plate 1) usínß bO. th surace and widergrouid extacton tccques, aloug waer poDded in the opeD pits was relatiel.Y free of mi pollutants. Mis in the Feather Rier watershed (plu Copper Belt; Plate 4) eîit.JSI ailomalous drag makeup. Th.mai amt at WalerMhe had, .a.t onetie, diCb bigh volumes of low pHnear water to th N. neutral water F. Feather River watershed (Croyle, pers. coin.). The amt was pm in and preseny releas origitig from the raceay in t oflle . Other met were vîyabsent contaig moderate levels of copper in th draiage (Table IV-2). Adi outows from the Luck-S coper Mine test s1y acidic and contaed low to moderate levels of cadmum, copper, and zic. Alough the mieralogica suys sugest ot,rwe (Table IV-L), the high acid and iron tyica of acid mie draige w8ters was absent from Luck-S outfows Several reasoru maz the water, and thehigb elevation (6,80 feet MSL) expla these induilg miral morphology, residence of in which low may e:iensÎve mineral oxidation. In the northern Sacramento Valey, adii releaes from mies in the Shast~ Ming Distrct (map I.D. #s #'58; Plaes 7 and 8) exbited quaty conditioi:tyica of clasc acid mie dr~ - low pH and hig.-m~.tt~We-w"). degraded. High anàl Geoioæca sureys for the area descroo the presence of masive pymc deposits tht are easily precipitaon (40., inches/yea) alocon.trbutes to th formation and dige ofstrong1y !luted water. The orebodies as .refld:ed in m tbe area were very mieralogica dierse includig the wide rage of comp directy or indiecty mied silver, arsenic, gold, copper, lead, and zic. Most of these metal Were alo found in. drage whiclgeneraly coni:;red copper, iron, and i.c m the ppm range and lead, arenic, the strong mådigconditions (Bh ca 500 mY; Table IV-2) keep . and nickel ii the tens of ppb. The low pH (2-4) and metal .În !Solution, The largest dichargig mies are include the hOD Mt., Balakala, Keysone, and locted around Shasta Reservoir in th West Shaa Mig Distrct and Mamoth mine complexes. with Elect Grey Eagle) or mercur mines largely eithr chomite (Gum, Nobe Mies loced in the western footh were shadow of Tehema little or noadit øutow (Table IV-i). Western footh aiomitemies were locted in the rai andG1ennrouies (plate9)ani:ílthoug, .thetopographyofthearea is stecl and mounai01i,tb absence of perennal draiage is liely due to llited .raiå1. Fmther, pondd water in an open pit at Grey Eae ;Mme.t&t neutral andrelatively free. of metal indic.ti uneactve miner~ogy, Inacte weste¡r ciabar (H) extactanmis are locted în th Cache and Put.an Creek waershed (Table iv -1). LD.#s Most ohhe few ml~(niap 77, footb mercu mies weedi wi:nolerenal~ge .Adit drag~ Hom a 85,86,87,88) was cl¡¡cterti 'ii upn, mçk and caates (Table iv-2). coron~:Mediargedthehiest volumes (2-31ls rea 1/10 Cf) . el-ironponute waer wi th pIt .g;a:i.5.7. The hi iickc.1 levels (me!:lleiup to12ppm) are~edbygep1()gicas1.ey ~ppi ii~el. ..e(p~ntldire or. mii:te) comp( :EJPJfcó1\~~r~ s~gfuti~g~tb~~~~~~:i~f'~~:a~å~!3:nJ~~¿:gl~.?h~ cabQnates~ ~ iron levels Ilea5od in the w.te, stram coii the acidity(as pynte oidtlation) and were ~~~l:~~~1.~:~~ri:~~~d~:~Js°~e~~\!~e~:~~mïris;~£~~~~:iì.~l iickel, suggestig that if the W,iiterreaied UJtered,. solllepolfanswolldbeei:lubleprecpitates provide enoiigh suracearu wa avaiable fornuleation.hon~d~fonnat0ns wer~ .fl9OOSl.rved at t\oiieslocatèQii the Sie~.Ne~daraie (pic and Shovela.dSp~uPPeradit). Other mercu miespitb.earea (e.g, Twi Pe~ Re~) exhöited . simdramage diaractn'locs. bul witlsmaler. oUtows. and lower. constituent li:weIS. A:cion Mie. was aiom.~in tht fbe drage wa tesed în areducistate (Eh "" -8 mV),althoug arenicwasundèteetble or preseí1 at ver '19W iev~. Siler was. not found in any perennial draiage sampled (detecon lit:: "1 ppi:). . Othr work shows. min water ca contaisier. in the pptr range h\lt tht 99 percent of :it is sorbed ta particuates and wiùtrable e.ven in low pH waers (JQnes, 19. B. Wastellôe Chractestics Waste rock material ~vated as a result .of actve mi~.operatio;m is defied as either developmen wate or tailigs development waste caninclnde soilJ overburden, or sub-grade ore re~oved to ga acc to th more valable ore. Taigs .includethe.alteredremaiof (lre afedt i.dergt.es pllsicaandjor clmica treatent to caes, wate rock (U.S.EA, 1986). Mine extact at alost eve mievitea In m9St the desed cnmpound(s). One or both I:es were observed was removed from the sie 'by dumpin it ino the neares water cour. It wa apparent at tbese nis tlhi flows durg the ray season had eroded muc of the mater away ino downtrea wate:r,and onl ;a frcton of the waste rock ori generaed remed on-site. 19 The soi pH of waste site to si, rangig between 1.4 and 8.8 (Table IV-3), wi ~o apparent large-scae g trends othr th providi a representaton of th dierse makeup of ore materi m the Sa~ento Valey. . intant~ooU5 measure of acid at one point in tie (Tu~r et al, 1987. Furer chge m pH OCC~ from dedal.e weathenng proeses tht generate more acid, mae mmeral bound cabonates av~l~ fOT buferu or ~!ll: Th tes needd t9 determe po~:i acdity sbi is caed net acd generatn pote and IS dicused below. Soü I:e irelatie ease with whch me c. miate thoug or of l: waste rock pil. Avaia~le. meta .are ~ore mobile. disolv~ ~ an ~d solution, and so, soil pH ~ be' fact~r in detem:g the reltie waer qwi theat of siarly siz waste rock piles. To determ sie replicae samples were collected from 10 mies and individuall ed. With the excptioo of two mies, the ina-mie si vaabilty (cocint of vaa.tion) of 'W low,' to 13 percent (Table IV4). A.oug 2-3 replicates ha:dly represent the tota vabilty expcted at :a od of COlitiOD atempted to obta th most. vialy materi based on color, compoon and procein equipment. The varbiísdne completely to si!e conditions since ~ooiroi: iep1ii:t~ p~rf~ct preci?D (Appendi A). W~te roc .materi eiit a diparte relatiely homogenous aC1d content may indicate that acid lS dc.iocfrom source matenal and ditributed thougout mean .tht tbwate roc coiiP.IDon itself is hom~~iUs wi li for the pile dur period of saaton. It ca alo simply respect to pH inuenci materi Sixeen of 52 saples tested at pH 4 or les which is considered the divi . defi £ waste as "acid-toxic' (Sobek et al, 1978). From a recevi waer.staidpomt. other factors such as slope, water contact, metal more important in caus impacts, and therefore, soil is one of many factors used to assess what may from wate :rock material Mercur levels were highest at foothl merClld-i It.wa dicwt the age of parcu. waste materi but the hiest levels between the mercur ins teted (0.2-140 glkg, dW; Table IV -3).y be reflve of older Cacìe, the leftover ore afer operations (mid.i80s) that were less effcient at extactig mercu from tleciar ore. beat extctIon, was collected at most of !:e mies as part of th study and bad some of the hiest levels of mercur. Pipe fuac and retort equipment used to extact merci were ~parently very inffcient. at one site, free mercur was with an oftleother metal which were high copper). The intra-site vabilty of waste rock metal found in the .cacie ta. There were no other str . pli trends ::t=~o~ti'~~~Klf:a~~i~;~~:~~n;e;dff.~~=.l~:,~-;a,=i~k vaable between mmesites (up to 4 orders of m. or materi indicates that site nwoff ca pose a substantial water qwity theat. from -48 to 11 tons of cacium cæbollàte seven representave saples raned The net acid generaton potental (NAGP) of needed to nental 100 tons of materi (the .aIount of mater in an 8l'proiåte acre-foot rSobek et al., 19Sl;Table be formed beyooâ wha inerent buferi compomidš could lV-S)o Positie values indicate il ~ndency for acid to neutr. The mÎ.eral. A ret meaures th fipaentiah)famaterial to . or neutrafacifrom tߥroduc ofl~chable conditions that exposed soil may good)ndicaors of not with pa.values above 6 are dieson step releases aieooPounds . . .the weat 6 is neraly thougtto inilcate an acid generati material (Soek et ~.. 1978). experien ovr time. Asoll pH below Tb.held tr for the sample tested. in TN-5, Ðowever, soil positive or negative NAGPmeasemenl:. Th wa aparentiiJ~/Snperior and OreyEageni with m.easyred ~eí~~e~Jt&~~.~;eil:;v(Ìsr:::b~:ri:nN:~t:~~.:u~(;~~et~.~~~~:ll~~:/~ was a complete lack ?f cOlTcl,ation between NAGPand pH due to th present liw.bilty ;Of. i.encicornpounds under nOrmal ~t:at conditions Fuer~the test nl Rot becompleielyaccurate mpred~ pH sli which al liely contn'butes to the lack Qfcorrclition. Soil posite.potnti wa not lited to low pH materi" (Sobèl et at 198), but materi "W a pH below 6 'Oay be goo Üic.tors of EOSltI NAGP, ,alough soil. :MatenaLwith a valiieof 5.0 or .greatis defied as "poteiiy to~c as with pH values NAGP is only one factor in the overal assessm~nl of waste rock 20 Tabl~ IV-4. VARIABiLITY Of WASTE ROCK METALS COHCENiRAriONS AT SEVERAL MINES. TOTAL tQNCi:JJl RATlOlI (MG/K.G. DRY IJEIGHT) _ _._4 _. * _ ~ _ ~ * _ _ ..a.. .__. ____ _ __...._ *. _ _ __ __ ... ___ __. ___~ -.-. -~ - 9G.. ~---_.. - _$¥.. pH ARSENIC CADMIUM CHROMIUM COPPER LEAD MERCURY NIC~L SILVER ZINC HINE AVERAGE . _.--- - ---- ~ -- - -~ - -- - -- -- ---- - - -----~ ~ -- - -- - -- - -- -- -- - -~-_.- ..--_. $ P. _._. - _.- _. - ._.. .....480 9.0 7.6 'l 24 189 390 14 246 "1 2.7 76 28 COV L8 llairy farm 42 2 1\ VERAGE 14 i 47 54 60 55 50 59 67 1.2 3.B 1300 1400 440 300 3.8 3.7 9 32 16 19 10 200 710 79 " 19 i 140 2.8 54 40 . . . . _ _ _ _ __ _ _ _ _ _ _ . _ _ . _ _ _ _ _ _ . h *. _ .. . . _ _ _ _ _ _ _ _ _ _ _ _ _ - _ - - - - . - - - - - - - - ~ - ~ - - - - - - - - - - - - - - - - - - - - - - - 455 15 370 3.8 17.9 1350 91 2.00 1.90 5 COli Spencevi L Le AVERAGE COY A ftert1iought 12.5 28 56 31 120 6.4 6.1 76 1.8 16 270 (, 0.8 43 51 1m 0.59 230 110 B8 0.7 2.7 280 13 6.2 1.4 450 150 2.2 27 26 __~ ___ __ ___ __ __ .__ _. _ __~______.Vb~___._ ___ ____~ _ ~ ~ ~_. _ ___ ~~ .*.. ~ _ _ __~_. __ - - ---- ~-~ _c ~~---148 23 4.10 152 1.26 277 15 40 1.23 2.97 67 84 71 40 4i 50 65 87 S6 9 4000 38 4.5 25 4900 7.3 1300 16 500 4.4 4600 18 6.3 9.4 3100 880 B.2 500 18 5 7.7 sao 3.8 300 5.75 ~ W 590 . --- -------~- .... - -. --- -- ...... --.~-- --_...---- ... -_.~ ._- -- --- -- -_..... .--- -_.--~-_. ----- ~ AVERAGE 4.70 500 CO 6 0 on Hi U 17 6 7.75 1090 6 19 liOOO 23 17 45 5.55 14 2B 4300 7 36 ..__ __ __ _ __ _ _ _ _ _ _ _ _ _ _ _ ___ _ _ ________ _4 __ _ _ _. _ _ __.. _ _. __ __ ___... ...._ ___ _ __ _.. .... ..-- --- _4. AVERAGE cev 3.8 B i 9 Buzzard 3.1 _._ ..___ ~___ _c _"_. .._ ___.. ..... _.-- -_....-- ----- _._..----------------.- .-- - -- -- ~----- -- - -- AVERAGE CO 3.45 10 3.5 Bully Hill 960 5050 2600 640 3_6 1200 180 22 26 3.55 690 74 24 8 14 14 3005 68 1620 60 2.8 4.4 4.9 Il 200 14 2.3 2.55 4.65 0.00 17 14 68 40 12 16 .._ .___ _~. _. _~_ __ ____. _ w.. _. _. -. -_. .-- _. -~- -~ -_. _ -- -- _ AVERAGE CO Corona 1 34 3.1 7.3 ....- -------..-.5.2 19 4.5 1 14 . 2000 3950 --- - .-_. .._-.. ---.. n 7.5 40 87 2975 33 16 940 480 0.2 26 45 17 18 22 26 1370 350 37 0.40 31 45 35 NO 270 1300 20 24 110 8.2 220 1aoo 27 20 NO 150 - --- -_._.. - - - - _... _. -- -- --_. -_. - --. .--_..... - --- - _. ._-------_. .-- - - - --~ --- - - ----- - _.-...-AVERAGE COy Manani ta 10 5 " 3.1 liD NO 50 llb 3.55 13 25 100 7.9 '10 NO 36 27 100 26 16 2 _.---- ------- - - -- - ---._. ---------------_._~ - ----- _.._~. ---~ -~.._. ... - _. --- --~-- -_.~ _. _..~- AVERAGE CoV Engle D.Qe 200 6.1 ....--_.. .-._...--- _. AVERAGE COY 7.00 13 lD5 90 li 110 40 51. '2 14 11 , 13 1100 '2000 4.10 -785 66 Z2 9 1.00 ,00 21' 24 0.29 1.6 '0 ll- 1.8 120 210 113C1 lit!. 100 14 ...~..-.- - ..... - ----_..-- ... ._-~-_..--- .~.-~ _. - _.- - -- - - - ---- ------_.- O.PO 6550 S3 13 12 50 100 0.95 13 23 69 165 7.90 27 77 'Table 11/.5. IIET ACID GENEMTIOII POTENTIAL of WASTE ROO: FR0l SEERAL MHIES. SOIL pH NEUTR~LiZATIGN ACIO GEHERAT iON MUlE SlTE (PASTE) POTEIlAl 11 f'OTfllHAl 2./ NET ACiOGEN~RATIOÑ POTENTIAL 11 Corona 2.6 -2.6 3.5 View 2.7 .1.6 5.5 Afterthought 4.7 -4.9 6.5 e/i5\iior 9 Grey Eiigie7.0 7.1 4.2 49 1.5 Mt.. Mme, lOl101fg area 1. 4 -3.8 6.5 Bi¡¡ Chjef 2.5 .4.1 6.5 ¡roo valley En;i1 1j As tons CaC03 equivalent per 1000 tons of mèteriat. 2/ As tons CaC03 eqivalent to neutral i ie the acid for~ by 1000 tons of material. 22 10 11 6.1 7.1 11 4.8 -48 V. MAS LOADS Loads,were caculated for Sacramento Valley mines with perennal diharges using flow aDd coocentra¡Íoii ~easuremeim taken largely between 1987 and 1992. The loads are somewhat comparable between sites because of the coooiiued drouizt conditions during that period. For smaler dichargi mies loads were caculed Vi'Ùl data collected priary dun thi surey. Estimates for West Shasta District mines were made usg 1989.92 data. further, with the exception of Iron Mi. Mine, the loads represent a mass per rime statitic duri¡ dr periods. Because of the strong correlation between loads would be hier loading and precipitation, we numbers presented here are considered to be underestiates. Actual with the ildusion or waste rock runoff/seepage contrbutions and an accounting for normal OT e'Xreme råiny seasons. Detailed load calculation methods are presented in Appendi A. lroii Mountai Mine (IM) was the sie largesiloader of mie draiage .toUutantstQ the Sacramento Valey. Loads from IMM were cacuated usiiì weekly Sprig Creek Debri Dam (SCDD) metal aid outfow data colleced by U.S. Bureau of ReclatioI! and regional board (Reridi offce) staf and are considered to be acCurate (Heîmanpers.::omm.). The SCDD collect and dicharges water fromJe Spri Cree watershed includig aWl releases, wase rock erosion and seepage, aid backou.d stream flow. Between 57 and 85 percent of th estied ccpper, cadmum and we loads cae from th source (Table V-i). Overal 67 percent of the stadard equivalent loads cae from SCDD indicati that, with respect to freshwater metal objectve it is me lages inctve mie source of I:e most toicc metal detected. Stowell about 1 percent to tota SeDD loadii (ieimani-ers, comm.). Mine alo draIns 10 thi watershed but contributes only A certain amount of the loads from SCDD are intercepted at a smal Sacramenta River rcierV01r (Keswick) ana settle out, never fully making it down the river under normal flow conditions. rock aluvium. The low pH and Leaching processes within SCDDare likely faciltatig th release of metal from waste should provide ideal habirat for acidophic bacteria to break down sulde and metal containing m.inera flusbed into the reservoir durinthe ramy s~on. Other investigators have snowni.creacd leach whensimilarcooditions. eiåte. d in. underground wodci. gs. further, SCPD water exhb. its an eleva. ted 0. xidizg potential exposed nature of the reservoir with Eb measlJementsaveragig around SOO mV. Under these conditions wate rock materi is contiuousyt:qosed to breakdown force that are greater than. wha is found in naal strea waters. The high CCuductivity of the wa~er alows the way rutigactvity inc:eas.es .¡ncoastal greater eiectc.ttanerei:ce which ence oxdalioii proces (si to . . . envionments be!:usofsalry air). AI wate roc degrades, meta4 heldwith tbem.ineralmatri are released and soiupiliedin water acidifed from sulde oxidation. Even tbou~tnnditiOXii SCl.Dprobabiyenh~ce the release of metals, mass balance estimates show that about lS percent of the incoinin~meW loads are retaed in the reservir. As might be expected, mnst of the metal leaving the reservoir are diolvd m thevrter. Mines in thel.ittle Bn.ckbonè Creek wate~bed'CCntriDutedaboiit 22 Dercentof'tJeståd.cf ~quivaeiit loads¡secoñd aiiY to. IMM (Table V-l).. Mammoth, Golinsky,iUd Sutta iÍes dr tcÎ,tbis creek whichflQwsiito Sh.a5ta R.~servoirShoeme3er Gulch dram thef,out~ern endnf the Map1oth'Mecomplex, and alo flows tò Shata Resery~.. Load below thepin~ ~al1plex and d,e ..swnof ~ mdívic,hiauy calculations, were made by averag;ngintrea (oilds. measured measured discharge;; (see Appendix A). Althiigl tlie'two methods .shotÙdintuitively produce siilarloadi values, thi was nauhe ~ebecau:e of unquantied~~o~ssgoinoni.ile wate.rsberi D~ drpt.rlodspollutedi:e dråiage sometimes neyer fuy.ar dowtrea, leadi to a ceranu;)\w ofbuid-u)l in the\Vtet'.sed w1ich is subseql1eiit1y nushedoutUIder high flow conditions (HeÎa. ,pers. CQii.).Fii~r,i:~reinà.y be. subsurfaoenow in!he shißow w.. eathered b.cdrock . (W. al.ke. r ,p. e. rscom.. a il. t.w. mild i:..ot be'vible a..it eIlte~ tle. l.. . . Tiie XD.. QvC?m... etit;Of1I. i;e pollution with ground wa~has been doeeitetÍat Pem:.le(Bolid,p:s'còtt1' R.e,gal'dl0ft:m.er.anItS, the phenom.enon ,isâ1 obsered in the WestSa,uiiW Creek waimdd.Eah~Keysone,E~YB~a:dSli Kisi¡ines (Heimai¡iers. com.ni.). WestSqu~trt;k a1enersShastaLáe andcoiitrbiied¡iut7percentofthe standard equivalent loads (Table V"l)~th cãcuaQon.mcth()id~nteatotbos~usedJøri.îteBackne Croek. With respect lOcoPRtr,cadmwn, and zic, the 3afQremeiitìClJ1ed source loctein the Wes Shasta D~ctdÏ~ed loads that were sigicatl'higler than other Vnley mies (Fige V-l). The relate maptudeof øtlei, sxaUer,acidmine sources depend$. on thepOlll1tant of cchcen¡. . With thee.ce,ptionof ¡MM, the Jpads in Tab!eV.l. arunderi:timaiesbei:USe.thcy didnotaecllp:t f~;ir dirh;!r~e inçrtases expected duriiiSthe wetscas9n. ShortdurattQnadltsurges resifrQm raial ()rsnow.ineitinGvi~o;wneleQmpiex thrpugb .P9(,0. U§lt:raèlure. d overb\ltd~ns. vertica ai ..Sh.. 8&. ' ..aid ca... y~dst~p.i es. (P.H2.MH. . il..,. 19...84.... ;...C. .rfJ..!f. lè..,. pe~.s..C9m. ro.). EvidtDccofadit Sllgesca be stcn. m TålleC"2wnere Ba1aiMie outfows WttenieasU\.êd ai.589 lls durs.Tanua 1983fr.olI an avcr¡gedrperçdflow ofabput 1.-30 l/s.,Raâl',~froin 'wasterOt alcGiit-mesto'senal pilot st¡id.Y was. canduct~d at SpelIli:'VeMiie to m~urt loaâingsurges but isdlcit to acciitely chacteri. A van.. : ouspar~ineters of fa.. infal TU1!Of. f. B. Y expapolatig I1.t.as... eie. n. tstå.C. n. ..d...Unr. . ... a. sine.stoIm. '. c. yent,su. rfa.ce.runoff was esumate. d to. a.ccotil forapproximatel.y. 5-18 p.e.l'cem 0. f the tota ai. . loads .CQin. JZ. .I.Ol1 d:iis. . ....$.lt.e... ..(W.. et.. . +.dtseas. on). in Appndi B. Most raiälùitratesiitopepnea1e wasteroc. The studyresiitsaid loadig metbods are detaied a near thesrreambed lo",tpoint.Setpage wat~r~ $trpppliutants frota wa,e ro¡;1c to greater inaterial:ad setpsout later degree Û1ansurfa~rinoff ~ecaùse of a lo¡¡geri:esidence umc. ~reforc, measung~urfa.ce ronoffWtuld n.o~aÆ:u.t for the total load Increases induçed by rainfalL. RegaipJess th relatie poUutantseontrîuttoiicausedby prti:pitationat an indi\ldualsitc would depend on the magitude of any extig perennal dischaige and, thns, wo'íâ afect cleanup priorities. For mlies with 00 perennial releases, wet seon discharges wöuld represent 100 p.ercciit or the tota1oads 23 ¡: '- CAtlMIUH CllROH lUM CoPPeR 14 ( 0.02 ) Anderson S¡¡r jOgs' ehampi on MJ ( 0.00 ) NO ( 0:00 ) 1,722 1,805 288 63,889 1.273 0.01) NO 0.00 I NO 0.01 L NO 0.00) NO 0.01) NO 0.00 L NO ( ( ( ( ( ( 0.00 0.00 0.00 0.00 0.00 0.00 ) ) ) ) ) ) ( ( ( ( ( ( ( ( 0.00) 0.00) 0.00) 0.00) 0.00) 0.00) 0.00 L 0.00) NO NO NO NO NO NO NO NO ( ( ( ( ( C ( ( 0.00 ) 0.00 ) 0.00 ) 0.00 ) 0.00 ) 0.00') 0.00 L 0.00 ) 5621 NO ( 0.00) NO ( 0.00 ) 0.18 1.1 0.22 0.98 0.10 1.8 0.78 0.16 261,128 .... .......... ..._..._..-_....... ........ _...-.....-.._.... ..--_........ -- _.. ..__.. -_.... -- --.:..'..- --- .....-----_.. ..--'-.. - _.. _._-- lI ( (L.On) NO ( 0.(0) 0.02e Ò.01 ) NI (: 0.00 ) 0.21 ( 0.00 ) 1.9(0.15) 0.07 ( 0.00 ) NDCO.DO) 0.01 ( 0.00 ) t:.36 ( 0.03 ) 9.5 ( 0.15 ) 6.' ( 0.48 ) U ( 1.09 ) ( ( ( ( ( ( NO ( 0.00 ) 0.93 ( 0.11 ) 18 NO 28 2.9 34 3.4 232 ( 0.09 ) 0.04 ( 0.01 ) 144 ( 0.06) NO ( 0.00 ) 359 ( 0.14) 0.8 ( n.15 ) NO ( 0.00) NO ( 0.00 ) NA ( 0.00) NO ( 0.00 ) 191 ( 0.01) 83 ( 15) 91 ,602 Ill\ 8.3 111\ T3 111\ 2.1 115 Nil llA ILLL 311 1,031 t.20~ 2,870 6.1 1,326 73.364 288 452 NA 334 110 1 2,290 650 ( 0.33 ) O.l~ ( 0.02 ) 110 3,008 ( 1.15) 2.5 ( O.~5 2,603 ( 1.00) 3.8 ( 0.68 ) 15,340 359 spring Creek Debriii OBmrelèIlge.. The Si:bDwlitenhed driiins Iron Mt.-,iind StoweU Hines. III LOBding viilues do not exclud urei-tiiin digits. 71 Excludes SRCSD lORds. 5/ The 1:00 of tne loeds eÒllnø fronBiiliikllllft.Keynòne. flirt)' BIrd, iind Siuistll King iilnes. the lMdø comûii Iroo Kentli, Gotiniiley. aoo Sutro Klnea. 61 ihê sum of 1,/ SèDO = 31 Sacrøiintõ lleglot\BICountYSlil'ltil:HOn Iflstrict..lifBlItewBter treiitemot phmt loads, 1985. ( 0.1)(0.1) AMENDED: 3/29/93 563.900 5 (0.001 )(0.00 ) 5 (0.001 )(0.00 ) (, (0.001 )(0.00 ) 4 (0.00\ )(0.00 ) 3 (0.001 )(0.00 ) 0.3 (0.000 )(0.00 ) 0.00 (0.000 )(0.00 ) 9 CO.002 )(0.00 ) 28 (0.005 )(0.00.) 21 (0.004 )(0.00 ) ì2 ( 0.0! )(0.01 ) 73 ( 0.01 )(0.01 ) 174 ( 0.03 )(0.03 ) 122 ( 0.02 )(0.02 ) A1 ( 0.01 )(0.01 ) 326 765 ( 0.1 )( 0.1 ) 94:2 ( O. 2 ) ( O. 1 ) 2,461 ( 0.4 )( 0.4 ) 1,294 ( 0.2)( O.l ) 1,192 ( 0.2)( O.~ ) 3,469 ( 0.6)( 0.5 ) 3,013 ( 0.5)( 0.5 ) :3 , 800 ( 0 . 7 ) ( 0.6 ) 34,872 (6 ) 4,640 ( 0.8)( 0.7 ) 39,674 ( 7) ( 6) 123,559 ( 22)( 20) 376.162 ( 67)( 6U) LOADS 11 sn\fIOlllO EOUIVAU:iH sum of HBver-age còfeltrstiontH*BVIrè'äeftowO))/lntlioo Surface \.llter. Plan Oljeetlveii(1)) for each metßl excluding iron. lliirdnesli " 50 mgll. 11 The 2/ loiids were ciiculiited using dahifrom 198. TOTAL loADS 71 Turkty Run GreBt lJestèrn Reed 110 ( 0.00) NO (O~OO) 0.04 (0.01 ) 0.16 ( 0.01) NO ( 1l.DO) 0.02 (0.01 ) nD ( 0.00) I).OS (o.ooi ) ND (-0.00 ) Pick: It Shovel tl ( 0.00 ) NI ( 0.00 ) Nil ( 0.00 ) 1.3 (0.002 ) NO ( D .00 ) 0.001 (0.000) O.M (0.01 ) 0.11 (0.006) NO t '0.60) 0.05' ( 0.02 ) 0.30 (ChOZ) ND ( O.ÓO) 0.23.( 0.08 ) Iron Dyke(Tøytors Cr) NO ( G.DG ) 0.032 (0.002) NO (0.00 ) ND ( 0.00 ) 4 ( 0.01 ) NO ( 0.00 ) a.DOl (0,00) 110 ( 0.00 ) liD ( 0.00 ) I/eilker 110 e 0..00 ) 0.37 (0.001 ) ND ( 0.00 ) NO ( 0.00 ) Il ( 0.00 ) 30 ( 2.39 ) 1.6 ( 0.12 ) 815 ( 69) Nil ( 0.00 ) 0.21 ( 0.0'0 ) 115 ( 0.21 ) 122 ( 0.19 ) 1.4 ( O. n ) NO ( 0.00 ) 0.2 ( 0.01 ) 52(4.12) 10.' ( 0.82 ) 110 ( 0.00 ) 0.60 ( 0.05 ) 2.3 ( 0.18 ) 135 ( 0.21 ) 1.3 (0.002 ) 61 ( 0.09 ) flA ('0.00 ) 428 ( 0.67 ) 260 "( 0.41 ) 8.2 ( 0.1)1 ) (LTT ( 0.04 ) 110 'C O.tiO) 2.4 ( 0.83 ) 1.513 488 ( 0.76 ) 0.81 ( 0.07 ) 2,863 111\ 111\ 7,537 ( 2.9) NO ( 0.00 IlA IROIl 36,760 (. ) 81 ( \4 lI cel.M) O.:U ( 0.02 ) ND ( 0.00 ) 10 (0.61) 0.04 (o.oo;n ND ( 0.00 ) Hi i ìi Peaks HAl) 30 ) 32 ( 2.51 ) Lucky S to I i. i lIe 6,928 (. 11) NO ( 0.00 j 18,961 ( NO ( 0.00 ) j.1CO.18) Mo (0.00 ) 24 ( EL.2) 27 C 1.6) ND ( 0.00) 0.23 ( 0.08 ) 0.02 (0.001) liD ( 0.00) 4.0(1.38) 0.3 ( 0.01 ) 1 ( 0..(5) 0.01(0.003) 0.67 (0.04 ). 0.09 (0.005) NO ( 0.00 ) NO ( 0.00 ) 7 ( 0.37 ) NAC 0.00 ) 200 ( 12) Ili) ( 0.00) 3.6( 1.24 ) 1.7 ( n.m) tl.66 (0.031) 0.06 ( 0.02 ) l;r4 ( 28) IIA (nJIO) 2~( 8.3) ( 0..02 ) ~,( 4.2) 12 (,0.66) 11.25 (0.09) 0.26 ( 0.02) 19 ( 1.1) 0.59 (0.20 ) 0.7 ( 0.04) 12 ( 0..66) 0.06 NÓ 60 1.flT6 NO( 0.00) 38 ( 2.1) 110 ( 0.00 ) 59 ( 3;,4) 186 ( 10) 15 ( 5.21 ) 13 ( 0.73' ) NlL ( .0.00 ) NO ( 0.00 ) Lava Caii NICKEL 658 i SO) 1,529 ( 85) 214 ( 74) 36,lOO ( 57) 234 ( 18) 20~, 352 ( 30) 390 ( 69 ARSENIC Empi re foalakoff Diggings Greenhorn Corona PI umaiio Bully HIli spencevtlle Brush Creek Spiinish (uppr:+lower) K8naka Creek mines Riiiing Star Valley Vieil Afterthóught 2/ ~st Squé~ Crt. mines 5/ SRCSP (1985) 31 shoemaker Gut i:li mj M!l 6J Little Bßckbone erlc. & scoo 4/ HIllE Sire DiscliiiRGE rÔTAl ANilUAl LOAbs INl(llOGRAHS (Pi:CEltt 01" TOTAL ni PAREllTHESES) OIA=NOt AVAILABLE: 1l0:=NOT DETECTED) 8/ Table V~l. LOADING ESTIMATES FR~ IUACIIVE MINES UIT" PERENH1AL DISCHARGES DURING A DROUGHT PERIOD, 1987.91. ~( a o 100000 .. ZINC ! 1 0000 : ~ a . II a; 1000 !l B 100 i I i f. .., i i .1 Iron Mt lit Bckbn Wst Sqw Greenhorn Rising Star Afthertho. Vall$Y V. Bully Hil LOADING SOURCE Figu V.I. VARD.IT OF COPPER, CAMI AN ZIC LOADING ESTE. 25 ~mi f.~ tht site, At other mies, W8re roc ruoff is Dot as sicat as ami releases - e.g., West Shasta Dist.ct mmes (Hemian pers. comm.), The load estiates presented in Table Vol lagely do not accunt for thes and oter ram)' ~ea01 surges. It would be dicult to predct wate roc ruoff loads because of the numer of panimeters involved lDch.ldi surface area, permeabi, meta content, slope, :rai characteritics, etc. 'lhe present drougl.n conditions alo skew the load estiates in Table V-I to the low end, Past estiates for SCDD snow zic loads have vane~ from lS to 4 . the 2! thousd kg es!:ate (ca 45-52 inches precpitl:o~ in 1989-90) in T,able V.i for a Dormal rai 60 mches m 1984) and an extemely wet year (ca 115 inches m 1983), respectively (Heiman UDpub. data). these load increaes to other mies and metal to aecut for the effect of var anual precipitation may Loads from Sacramento Regional County Santation. Ditrct (SRCSD) wastewater ¡sewage. treatment plant were included for comparon. It raed fourth in stadard equivant loads (ca 6 %) due, in part, to hi lead dichares and made up about 3- percent of the comhined copper, cadmum, and zmc loaàs. Alost al or the mi :regions are dred by watersheds interceted with one or inore major reservoir whicb have the potent to retai a cert fraction of the pollutants comig in from u.pstrea. Pollutants attached to heavy paniculate matter in feeer streams ca settle our and become pan of the sedent. The mas bace of pollutants thoug a :reservoir is litte is because da releases have a substanti inuence OD the qu.alty of downtream waters. better defie tnport compoent, the mas balce of copper into, aKd out of, Shasta Res~rv~ir "vas estiated using data collected dung the current w.0ugt period. The major mputs to the lae included 3 mme iiuenced streas (Shoemaker Gulch West Squaw and Litte Backne Creeks) aDO f"'1T "f il1aest stream Rivers). The volumes and loads were used to caculate the concentration of copper eiieced in the iireleases,siulatithe reservoir as a lage mig bov;l where inputs without mine impact (Big Backbone,Pit, McCud, and Sacramento produce a fial cocetration with no ph)'co-chemcâ interactons. Tbe comPar to nie cqpper ÇQcentration acty measuredmTeleas water . betwee198S and 191. Th caculated C(pp ooutrmiofSha Dam relejle water (5.74 ngft wa ~ertb.a. the avee lUu. conçentrwon repo by otr studies (2.4 tol; e. V.2 . detai of the grapbare Fesented multiple inputs of dierig qua are mied to loadi ÎI~ were made largely for 19 an is in 'fabIeG-1). The5.14 vâle was cacutedwi dataè.etò . ..g 1989 and inore coinparab1etothe4.2 ugli coppe aveage takt-Jromficayear ~9da relea data (&pmHeÎ;ai 1989). The ~.4 ugl value was averaged from fi Y~ar19"91 data. No steasicacecouidbêiürnedi)cae th cacUiateøcoDcentratioD was estiated ~in$ onJY 2 flv¡i~lt m~urelJents. causg the Clnf(ieiice ÌltenrID to wi(.D to u,lessproportioIl ev,n tho:ugbthere1tivestandarddevia.lioli warat:er low. CQvetselY,theaêtcoptr concentrationof.Shta ReservoIr releasesstatiticay deded byah9st.haJ ol/ra. 2 Yeaperiod.(J~e V-i). Th .ilecle may have resulted from drougbtinduced loaaigreductions wlikb are. st.o~Ycoe1att;dt() atnaP1eçipitati()n(H~i1'1ln;-mpl1b. data), Furer, when feeder strea loads were ched t() :sulteno miedraie thecacuei. coppeconceQttationof O~7 Sacramento (0.20. . .Pk J024'ill;and McCloud RiversJO,2~5 uglhimply ret1ectedupst.ea rierqnalty (upper ug/l); from Connor,impl1b.. Table H~i). Ðamrelease ~ter is. not apctcl .to exacùYinimi~ ~pstea inputif thel:. ~ih~~r~n~iJ:er~;::~uncl~~t~~ct~~o~waJ:c~~iliiti:à~å~~j~e::~g~t:~.;;;:', ~ievationphaéd tieditrence of inputs iø0utpts, wiittntrationòie.rences,etc. Al ofth'esecombinedpreclud~ ., the value of sPec~.a i:a$ baiantt.statitic based OD. th data.'R.e~dle~, Shas Damn~leass. CQnta lev.el of copper~tis a¡pr9~telYan.. order. pf xi~~HlClegleatertl.w4at. ìspr~nt . m. . the incomig . stramw:eced 'Q)' nuc thame. Tiidietenc~ispr~1y~nceL\l()SOmeC#ent, l?$Üe.die from Li(tleBackbe .andWest ~~tr~.i6~~~~o~J:l:~1:~i::if~.::wit:=.~~~~ui:nfI~~l~.tg~bo~::rigi~' SlJpcI1ODoflitert1oe andoth~rParç. 'çausedby~ve .act(:n:fie~ ~.taonthelow~rS~creIlto ~iver shoy¡s .aiincr~~ nietal~adie . .lieiy re1ått9 19W deaty.patute5and collQids ttvel~ lIea the mi-rbottoD;. ..AJoiigb thereis more . .. .. .i-Dergy in.aJ:~:tbe:reai:y bca re:latede)flantioiitbatdesbts so.lids (~;:r:~~fY~âjir';~es:rd~~:n:6~Ce~~cJ~:lã~~r:iat~e~~~~fi:s~~~:~~~:T:~ _caed thug teservótr bodies (fond,pers. oomm.). -i 16 i: 8 of ä: 6 -.. :: t) _+! .i 4 "' G :' 2 0 ., T CALC. W/MINES CALC. W/O MINES i I 19a9 FY 86-89 -m -1. T FY 90-91 :¡ .. i 1991 Figue V-2. CQPPER çoNCEN'TIQl'S IN saA l).A ~E WATE. . PCA. W/MI" "" CONCENTION CATE FROM S'l AN MI mPurs; "QAC. W/O rv" '" CQNCE'lON CATE JiOM JUST -.ST INu' (N;;2). ACTAL çoN~'fONS MEURJN D.ARESE WA'lW' IDEN BY TH TI PEROP jN wmCHDA'fA WAS COLLCT (N "" 7 TO 22 PER 'l PEROD). SEE TABLE G;.i FOR MORE SPEGlC INORMTION. 26 '\'1, RECEIVG WATERS .A assessment was made of the water quaty . caused by i:ctve mies. Metal were analyzd in mine site receivig waters and compared to Ind Surface ter Pla (ISW) objectes adopted to protect both human heal and freshwater aquatic biota (S'CB, 191). Heavv meta objecties takn fr the ISWP are EPA's hardnes fact~red chome creria freshwater biot. The 5.0 ppb árseiic level for hum consumption was more conservate. A cacium caboniie concetrtion of 50 mg/l was usd when sie-specic hanlnes level were iivaW1e. Most strea s;m:r1es were coDeced durg dr weater coditions at a ditance below the mie where draie was sucientl:m. l-u!ple sample concentrations were averaged and presnted in Table V1~1. To indicate which compounds exceed the objeces and the relative magntude, the concentratin/objecive ratio is shown in paentheses to the right of the average. Twenty-one or 31 receivi stream monored were impacted by one or more meta ex:cedi isw objectives In general the copper objective was most frequently exceeded followe by zic and cadmum. Ten stemshowed exceei:ce for led, nickeL, and arsenic and none were measured for clonuum or silver. Exemely high levels (100-1,50 ties the objectives) were measured in stream wi low diulon and m.al buferig caacity. at al mie sites but ca be inerrd strea flow and mine data. Where acid the bueri capacity of a sLre;m, metal and other pollutats in solution. At in the these conditions resul in impact th extnd the lengt of the stream .from the site (e.g., West Baclone Creeks), Impact leng at mie sites with atyica drage ::::e~~ o~o;s~~~O~t~:~I~:l ~:,~~~~~e~J~ei~rl:d:~:n:~-::~~~~;~r w; the mie, to 3 ppm decreas in James Creek from 5 ppm, diec below lice, m~el in draiage from Corona mi apprmdately 1.5 mies dov.'lstream. Tle. decrease wa largely. due 10 diuton from two oiler stream input as the preval~ce of. iroD.b.Ydr0xidescoa~ .the streambed. indicate. that llQ signcatcoprecj)itaon or adsorpti~ was occi.g. Furer, natu streams with umatualyhigh.Iltallevelsloosetñabiltyforsorpon whljnal the avaa~le th Yub Rier watershed(AJ~l!y-Down~vie ~;ai:~:Ïif:1~.~~~1~~ti~~:&~~i;t~~~C:~~ltr'j:e:d::~:~~~2:~~ bindi sites are ßied (Chaii~ etal, 1983)' . Arsemc f:r0m. ines. in increaing contrute about O.3ppb to the N.F. Yub ~rconcntrQn(Table Vl-2j_ Th arsenicCQcentraton from ~~t:s~p~~JtIf.~~::~:o~;aUtak~j~Jilb':~~:l6l8~.~it~~roB=e~1~~~;~r.p~~: is ear trportedmstlamiaot alcted.b¥a.c:d~e.~ ~calleiti5p~ntl~gè1Yinthe~lved~hase (50-90 :~~t=ri~:1:i.J1t~a~~~ iir:disb;1~m;tJ~1~g¿r~ey~~la.~~f~~~re~~ ".: "b:i::~~~:::~~~~=o:iinC:\:~~iu~th::~6:~it~~ait~:~=~(lól:iîon to OYeral . ;:.' "iThe Sacramero p.er peridiy~riimce objecteiccee#nces(forcopper~ cadmand .~c)both below IMM :~~~;a~;~~~#es.~~3;i~e~e:l1;~~~ei:~=~::=x::;~::'.:f~eiÅ;: totheItra1ol. tts leng mew.. ..acutue.aduraniruoltbiit.i: draige ha .be~n. previousyslow to ~:a~l:cl:Jif':~~~~~~:~=~a1oa~('i~~~il~ :;~l::i:=i~~=l:~:i~;. ~~i:."::~:cìtlilt1:ipiQ::~Wa~:r;:;~~f;¡n1S¥d q\Ù~Tl:t:;Jr:ib~dï:ÓnAa1Ó:¡t;; level .niCkel i: . ~easedto.~oiidGttçbl~ iiboutoiie .iie mstaice,at.. the Pick .aml. Shove !\ low beImvthemm.e.Sìly, cpppr1eyil$iJtceasír~m .~løwc.è.Ol (c;l wb~. over a2 niestretclof Devi ~yon Creek (1romupr $Pa.~~Mi .... .,~er~ e wÐiyhicr3Sbv4t.cs. able C-l)'.'lerore, stream ri1h~:~.,~n~fgi:si0:iãvi:e~~nce1~r~t~=.~I~~~o:;tthe met.. ()rmeta1oid. diution capaCity Reci1Jg water'cpncåûo.suges aree~d1welperiodsfrom ~am tesDSoian increaed mies!te di~ Met d~sjted.hi theSteamDeddnrglO\-flowperiodarescOed andtranrte4 dOwntre; dung higb.t1.pws. ' .l!?W bini;~dd.0si(jíi~te. . F~i fam~and snpw.meJarekiGW.to flshø'l.1t i:el ~6;lh~g~isrpinf3~~:eesl;¡(~:ll6ll .. .'Qf~~~~~i§;i~~::;J~~:á . abßve andbelSm;rVieMidurgaaii.rev~nt. ... ... .. .Øriip;äw;i greaheçusefiewaste IQc:.Ðte'Wci. . .l1yenncbed y. severali:êt Dryerei CGP~r . vCl)Sbêl()'Wthe~1'a: betWeèn" 23nid 12ii.J?bandexce.~ th l-hour, badn(lfactated ~()b~(~ppb).by~to8ties fG1la1()howr~irod (see AppiidiB). ThC9P~rQOnceIlat.i bi.DrCreek.ups~th.~..rem~ Jnsta1Vttbd~t:()1itt(d.= .-1 ppb) lhOiiout theistomiAI0~ thestre¡f~cbeaanex~ineiy i:gi tlop staeCniiç1tiondurt:e storm, it ~ not eiiot! tØcoPl~1yòitecoppel!di~.~from.thm.sieWt a,,~dartlu.d 3;ppm. Mùé~ll alo 'Iesiútedina 4fokimcea mthtßt.~de soJiCtntt~upea ~ve (CS5..~~gflUPS.l.eaa.d ~ U4 i,g!l ~elow tbmie; see Appt~ .8). Tycâ~. i;m incrt8 in~dem1îdS'w0maindi~agreate; capacity for th wal to coPlex freemetåI tons. Howevr. most wae roe ~cr nittef is.aleadysatuated wi .meta d?~~r~=;:iI~Psl:°::~=~:ir~;'~~:: dl:smt~=~=ij¡y~'.~;~f~ 27 RECEiVING WATERS ABOVE AND BELa~ SAC~IENI0 VALLEY HINES (FROM APPENOIX C). MINE Creek neiir West adit Anerson Balaklala, Keystone, Early Bird, an aOOVE Wet Squaii Crk abve llosseLkus Crl: above Wooruff Crk above below above Brush CreeK ¡:ll)' Hill "lown i:rli Coron¡ Jams beloli Engle/Suprior 41 Gl"eat Western St. Greenhorn Wi Llo;i Ci-k i ron Dyke ~/ Taylors Crk Lucky-S 41 Mamth below below belOl abe 99 OI aboe below abve below Peters Crk above 3/ Humg Crk PicK & Shovel ?llts Gulch below below abo..e 110 " NO NO 1m 3 NO lI ) NO NO NO NO NO 28 lI Rising Star llorseCrk Spanish Poormn Crk pelow 13D below 820 47 lI NO NO 110 lI 3.5 liD 7 NO 110 NO NO 5 859 110 liD NO NO NO NO 110 NO NA NO ND NA 299 963 6 lI (5.3) i.o IIA 2.1 ( 5 ) NA Il NO NO 15 (3.1) ) NO V.S lI NO NO 1 lI 10 9 NA NO NO NO NO NO NO i2 i 16 abve be lOl abve below above below abòvl! below ili: be L 'Ow ábve D.1 D.ll NO NO ILO lI 0:1 (1.1) li Nt 71 1tJ2 79 84 18 ) i93(444) NO Z2 NO NO 10 (15 " 1 il;. below '2 m; .belCl aboye ~ 51 2.3 4.2 .llO lI li Ii li lI below NO 110 )10 lI ¡NO 9 ItO NO ND NO NO mi NO 4.4 llA IlD NO 110 NO 1 NO NO 2 10 , 446 9 ~O ND NO NO 110 ( 17 ) AA Nl' NO ND 16 (1.3 ) NO (31 ) NO 36 2.4 li ) 18 60 40000 (678) NO 5 NO 15 63 (5.0 ) NO NO " NO NO lI NO NO llt) lI , 1 NO 115 4.4 )lI liD NO NO NO NO NO 4.6 5 5 He NO 20 (3.1 ) i 1Z9 (195) 1.8 .Nt .lO WI) 6.7(1.D)ßO 3010 (463 , li on e uptri:am ow 15..co .om upr li t. iscarge. !lot lie Crl: 8 JlO HD 110 NO 59 ND 1 till NO (8.3) (i5 ) " IlO NO NO lI .9933 (1528)38 (29 \\ 0;5 Mil NO NO AA 3 NO NO 0.1 NO NO WI 1S 15 NO NO NO 1 (8.2) 9.6 38.8 (2.4) 10 NO NO NO NO ND liD NA 1 110 NO HI NO 67 ( 14 ) 597 ( 135 ) 110 é.2 (8.9) \\ ) 1.1 (1.4 ) 4 ) Nil NO (3.2 21 .19 .53 (2.4) 60 ( 4 619 ( 53 ) 1 NO NO (¡.S Nil belOl irrigation water NO ND beloli Valley View lI NO 11ve Ilin:ei Crk NO NO liP ilve Ti.10 Peaks ND 78 Ward Crk Dry Crk 12 (Ï .8 ) NO ND 0.9 170 (3.4 ) NO lI NO above 2/ NO ND NO NO be L oi aQve 11 A s gn ICllt port Nil NO NO NO NO Davi s Crk lJalker 2 NO NO NO 110 NO 110 NO Reed Little Dry Crk :2 20 t " abve Spencevi tle (95) ) 83 (64 ) i 62 below Devils Canyon Crt( lI NO NO NP l.uckeye Ravine #1 11 I/O ;2 liD NO above bel Gi above below PLumago Reward NO ;: NO NO NO ébove Jamison Crk; liD NO 61 51 mi. bel01 4/ PlumaS Eureka 4/ NO NO NO 341 (536 1947 (33 ) ND Nil be L OI ELder Crk (3.1) 4 2 140 (212) 23 (4.6 Kanaka i:k i M.F.Y~ Rbelow BI II. f. NO NO above 3/ Sacramento R. l KesWick Res. Noble Electric 4/ 22 (4.4 ) 3 abve bel Harrison Gulch NO lI below Midas 4/ ND 110 alve l ittle Backbne Crk Malakoff 01ggn'5 NO 55 NA AA liD 4/ beloli Marys Crk (11 ) 11 NO 110 liD 32 (4.9 ) 1653 (254 ) IIA NO Nfl abve 3 il\. 4 (6.1 ) Ill) below below i. 19nts i:rk cllM Crk Kanaka creek ooines 100 abve Yott Crk Gladstone 41 Iron Mt. 7/ il 0.5 1.5 110 IlA beLow CrK .5 EW~l re (Nev. Co. lI below below Shasta King 8eardsley 4/ 110 160 Anderson Springs Crk 3.5 59 (9.1 ) NO 30 2 5.B 299 ( 1.9) 1 43 i 2.3 IlD 8650 (147) 12 5 be an enelytiçel error. . . 2/ 11.0 upstreæ site was discerrmle. 31 The upt. reaJ..portion .wasepeiral. 4/ Based on one sampie. 5/ On higli detectable value was considered to 6/ 4-day, hardnss corrected ÈPA freshwater qulditY criteria. A hi:rdnss of 50 mg/l was used when no stream-speedH:: hardness was available. The hi. i:or\:tion l'l$enic hwel = 5.0 ue/l, 71 Froi Heima, 1988, 1990 øn site specH; i: objectives for the upp Sacramto River. _._"-----~._--~...._-----"----- 8/ K.ana\(¡i Creek belOl at L mines in the watershed. ~"".'M"~__"" ~,_,..._"'_....."~._~-"'_._---_...._'- 28 rock pil mOVes at a slower . runoff flows. Furer, intrted water emantig from a wate' and probably e:iends the duraton of impact beyond the peod of raial. Runoff from waste rock mcreased the downtieam concenttion of toæl metal and liely increasd the streambed meta content. Other nte i:uenced rec.Ivg waters are expected to experence siar impacts imd, therefore, Table VI-L is an underestiate of the act average concentation the streams experience year-round as a result of mie draiage. ¡ Stream conceiitions are alo infbieiiced by diec contact with waste roc pies regadl of the seaon. For ince, at Iron Dyke Mie, Taylors Creek dippears under a waste :roc pile tht was deposied dieCÙY in the streambed. The , stream emerges from the other side wi levels of cadmum (05 ug/l), copper (21 ug/l) and zic (18 ug/l) above what was meaed upstream (.ç 0.1, .ç 1, and .ç 10 ug/L, respecvely). Therefore, vi..te rock piles have the poter. to. ei:ch stream wi an eay and freely leachble fraction. not dent on pH decles. Simple dion p¡,oceses brm tle solution upon cotact with water. Mi opertions commonly removed unwated waste rock from the me meta ino by dumpmg it .iio stream watercourses and alowig hi w:er flows to was it away. At may :me sites waste rock sti composes a porton of the strea ban. Alost al streams inuenced by draiage eventualy pas thoug one or more major reservoirs. Reservoirs have the ¡itential to alter balance between metal comlg in from natual/man-causd sources and those leavmg via dam releaes. West, a reservoir in the Sierra-Nevada footh range, upslream inputs from Bear River and Rock Creek were with relea Arsenic levels were very slghtly elevated in the release water (1.6 vcrsil 1.3 and 1.1 chomium (3.8 versUS 2.8 and :5.. ppb) and copper (2.9 versus 2.8 and 1.4 ppb) remaied essentialy unched On iaboI'atory vaabllty measurements (or tht batch submision. Sampli conditions with no obsrvble tubidity. It would appea that these inputs ",ere simply pasg though the reservoir system with very little concentration change. However, when occued in June when the streams exhibited low flow metal streams are highy nibid, metals associated wi heavy particue m.atter are expeced to settle out to the lakebed. Afer ca beme eVen more tightly bom:d tp caboiite,sulde, and depoition,m:cftibed metal organc cabon matenal and are not eay leached from the sedent (Bnigamet ai., 1988; DiToro tt al, 199). By the ti¡eincomigparticuate of the leachble met. have Oel"released to the water colu matter has ben tranorted to the lae bottom, most (Bn: et al., 1988). Reservoir chaacteritics such as temperatue and flow dierential draw point ~levation, ditance a storm event, inuence releaqualty. For .inance~. durg to the. da. releae, strtication, ete. are alo exected 10 Caanche Resrvoira1ong. the Ù!undated Mókelumne riverbed raial niofffrom Penn Mie travelled the lengt of ~:~L:~dr~~;:8Je r:~~~b~l~~~~d;:~~t~::i~:t~d~e~n~;:=~~~~~ti;nOV:if~;~=s~~ the fracton of metal transported tliough a l"eservoii depends on a vanety of factors m.dudig dam chaactensucs and the qualty of upstream Ù!puts. Mies ~ alo cau,e receivi water impact frolGmcreased siltation. Waste rock sedents flushed into adjacent stream ca produce a tranitory bentc envionment prone to movement and scurg. Th ca sh thç: macro-invertebra.te pOPcultiotl to more sedient tolerant species such as the mayfy and caddiy (Duba a. Pen¡osi;, 190). Further, sedient: :fom inctve mie.s ca prevent tihes suc .asscu!pí.daers andtioiit:fOlG inabitig astran because of the lack of clean gravel (Rea et al., 1988). Althoug acid and meta may bediuted.tolevels tQleratedby resdent biota, the long~term inpa~ from increaed siltatn are more subte and ca resu m a faunalsbi to inore sedient tolerant organms. TabteVI-Z. ARSENIC LEVELS HI TilE NORTH FORI( FEìi.HER RIVER, 9 .iUlE 19S9 (FROM TABL.E c-U. FEEDER ST1EAM TR18UTi\RV ARSEIHC(UG/L) N. f. YUBA .RIVER LOCATION ARSEJIC (u¡;ìL.) 10 llo\.ar!Î Cree~ Sa lmon Creel: Siel"l"a Buttes stream 1-2 Downie River 2.1 1.8 GoClear:s Creek Woodruff Creek nddLl! Creel: 1.2 Bassett 1.1 Downieville 1.3 Hwy 49 1.6 21 1.7 29 S. 1988. Penn Mie Toxc Pits Act technca investiation Report. 3 ___ Persona ComøllmicaÛoii. Engieerig gelogt VJth the CVRWQCB, Sacramento, CA Bouads, R'iand A Colmer. 1972. of th kitics of oxdati by thee iron-snler Ca. J. Microbio.. 18:73-740. for coal in !.e by Brugam, R., S. Chakavery, and J. La. 1988. Sedient chemitr of laks midwestem U.SA. Hydrobiologia. 164:221-233. CA. lO BS.w~ 'hS. Colman and S.1. Betts. 1988. Arsemc in iration water in San Joaqui IIJI u.C. Davi. Apri Butz R. Personal Communcation. Area enger with th CVWQCß, Sacramento, CA. Caorna State Bureau (CSMB). 1918. Mì and mira resources of Nevada Co. San Francico, CA area, Sierra Coun CA CDMG mines of the December. Calson, D. and W. Clark. 1956. Lode The Eclog pp. 52(3):237-247. Ca:ccio F. , 196, Mie'al ,.., of C.ioúa, Bul, 191, Sa F""cieo, ~orna Di,jon nl Mi", and Geology (CDMG) -_~ 190a. Bulet 193. __ 1942. Quarerly chater of state mieralogits. Report xx Vo13, #1. San Fraicico, CA. Jan. ___ 197Gb. Trace elements in the Plumas copper belt, Plwn Co., CA. Speci Report 103. Sacramento, CA. Calorna Joural of Mis and Geolog (CJG), 1946. State mieralogits report. Vol. 4~ #3. San Francico, CA July. ___ 1936a. Gold mines of Placer Co. Vö132, #1. San Fraicico, CA. Janua. __ 1936. Mineral resources of Lasen Co. Vol. 32, #4. San Francisco, CA October. _ 193Th. :Meral resources of Plumas Co. Vol 33,. #2. SaiFiaicÎsco. CA .Apri. 43, #4. San Francico, CA October. _ 1947a. Mies and mineral resources of Sisldyou Co. Vol --197a. The geology of quic:ksver ore deposit. Vol. 33, #1. San Fracico, CAlanuar. 43, #1. San Franci, CA. Janua. _ 197b. Mies and minera resources of La Co. Vol 52, #3. San Francico. CA July. -~-19S6. Lode gold mines of the aleghany-Downevi area, SierCo'l CA Vol __ 1915. Mies and mier resourcesm Shasta Sislâyou and Trity Counties. San Francico, CA. July. ~t~~~~"i.;e"'.=J~~ff~d''fJL~ "'.,,,,,"" or Cói- Gl.. La Mo Nap Laen .Modoc Suttr, and TeneJJa. San Francico, Butte, __ 1916.. Mies and mieral reso1lces aBhe counties of CA DeceJJber. ___ 1908. San Frano, CA Sept. Copper resource of Caorna. Buleti 50. C. en. ln... valey Regional Wa.ter Qiial!Y Control Boad (CVRWQCB, i)... J.1. An .an¡ùYsis of th toxc ~r!l~~ impaieitsmlheSaeraiento-San Joaqui DeltalE. CVRWQÇB, Standads Polici, and SpeC1il StUWW Secton (SPSS). Sacramento, CA. Decemoei:. __ 1988.Ai:ass loadi as~ment of :i~j()rpoitandnon-pain soi.ces diargig to surace waters in tbe Central Valey,Caon: 1985. CYRWQCB, SPSSSecûon. Sacramento, CA October. __ UDpubledData. Database of mies inNapa, Sierr Butte, and 1.e counes. CVRWQCB, Sacralento, CA. ~ 1F~~.:~A ~~ A:t li ML i- "oa, a.. CA Rood Pi. ChaP!an B.. D. Jones and:R. Jm:.1983.f'¡:ocess cotroll meion attiioiin acid mi draiag stream. 47:1957-1973. Geoëca et Cosochica Acta. Conor, V. Unpublihed Data Metals concetrtion data for the Sacranento Valey. 30 Croyle, W. Personal Communcation. Area ".1th the CVRWQCB, Sacramento, CA Daniels, D. Personal Communcation. Area engeer with the CVRWQCB, Sacramento, CA. Di Tor~ D: et aI. 1989 (DRA, Toxicity of cadnum in seents: the role of acid volatie sulde. Draf U.S.EPA report l=Dwomnenta Itesearch laboratory, Naraganett, RI. Augt Diviion of Mies. 1957. Mi.iicral commoditis of CA Revion of 156. Buleti 15. San CA. December. on water Duba, A and D. Penrose. 1980. 1980. Impact of in western Nort Caroli Water Resources Buleti. AWR 16(6):1034104. Doyle, F. and A. Miza 1989. Understanding the mechanms and kietcs of acid and heavy meta releae frODl pyc Material Science and Mieral Engeerm, waste.I! Mig and Mieral Processing Wastes. D.C. Berkeley Depl of CA. Drever, J. 1988. The geochemistr of natural waters. Second Ed. Prentice Englewood Cll-, New Jersey. 1964. Bacterial oxidation of arsenopyte and ellgite. Economic Geology. 59:13-1312 West in the West calorna.. D. Nordstrom, Ineraction sedients of Good, D. 1970. The relation of refu pile hydrology to acid producton. 3.d Symposium on Coal Mie Dnimage Research. Mellon Institute. May. Hares, J. and A. Ritchie. 1983. Runoff fracton and pollution levels in n.ioff from a waste rock dump widergomg pyrc oxidaon. Waier, Ai, and Soil Pollution. 19:1.5-170. Ha D. 1982. Quantitative Chemica Analysis. Secnd Edion. W.H. Freeman and Compan. New York. and cly Harn, J. and V. Berkheiser. 1982 Aion interaction with freshly prepared hydrous iron oxdes. Clys mieral. 3O(2):97-1Q2. Heiman D. :Personal Communication. Area engieer with the CVWQCB, Reddig, CA ---1991.lroD Mt. :report, July 1990 though .run 191. CVRWQCB, Reddig, Caorna. __ 1989. hon Mt. I\fie report, July 1988 though Jui 1989. CVWQCB, Reddi Calorna. _ Unpublihed Data. 1(1-year databas from IM. CVWQCB, Reddi CA Paper 224. . l:, J.1985. Stuy an interpretai:on of the chemica Higg M. Personal characterics of natual waters. Thd Ed. D.S.aS Water Supply Communication. Area enger with th CVRWQCB, Sacramento, CA lvarsqn, K. 1973. Microbiologica formation of basic ferc suates. Ca J. Soil Sci 53:315.,323. Augt. ~~~~~. ' Jenke,D. ., G. F.a~e$o.pf. aad F. Di~bod,i!' CI:.changein concentrated, acidic, metal b~arg wastewaters when treated with lie. Én.on. Sa. Teio111(4):2J7-22. . ;Johnon, C. .1. Thre.giation of. trílceelementCQncettlía.Qnsinriver andeswar waters cintit~ )Vll acid mi. e.dr. .ai. e: the adsorption of copper and zi on ~Oqhousoaydro:ide Geochca et CosmoCbca Act. 1ohnon, C. and 1. Thornton. 1987. H. ydrol~ca aD. cl~mica fact9rsco. ntroll the cocentrations of Fe, Cu, Zn and As in a river system contaminated by acid mmedraie. Wat. Re. 21(3)~59=3S. Jones., It 1986. The mie ditribution andpartitioxig ().~i1'Ver and . ollel heavy meta in sedent asocted wi an acid draiage strea. Envion. Po1llt. Ser. B. 12:249-262. KigSle, . B. 1984. Qualil). assurance in a contract laboratory. .I A\VVlA water qualty tecbog confrence. 12, 1984,I1enver, co. December. Macionalti, D. andR. Clak. 1970. The oxidation of aqueous ferroosulate by Thobacius ferrooxidas. Th Caadan J. ofChem. Eng. 48:669-676. Pec. M!ÙouI, E. and J. Prater. 1961. ;Role of bacLeriin the aleration Of sude mieral. J. of Metal. 1'1'. $356. May. ~¿;'¡Jëli;~~i2ti~~~'l~~~~~ M1~=,e~~dN~;i.tka~W~$t~šli.~~ci=:bi:.ctie Mi, A and L. Mallory. 1987. The comm:unity structure of::cssle heerofrophic bacternH;trcsed by acid mi draiage. Microb. Beot 14:219-232. Moore, I. and S. Ramiuoorthy. 1986. Heavy metal in natual waters. Applied Momtori and imact asessment Sprier-Verlag. New York. 31 Moore,i J. and D. Sutherland. 198.1. Distrt:utioi; of heavy meta and radionucldes in sedient, water, an li an area or Great Bear Lae conlaated with mme wate. Arch. Envion. Contam. Toxico!. 10:329-338. Nolle, T., K Nakamur~ and J. Matsumoto. 1983. Oxdation ferrous iron by from a stream receivig acid mie draiage. Water Res. 17:21-27. Nordstrom, D. 1982. Agueous pyrte oxdation and th COlleqi.~nt formation of secondar iron mieral. In: Acid Sulte Weatheri. SoifScienre Society of .Aerica. Madin, WI. - Nordstrom~ D., F. Jenne; and R. Averetb. 19TI. Heavy meta dicbarl-cs into Shasta Lake and Kesmck Reservoirs on the upper Sacramento River, Calorna: A recnnance dur low tlow. U.S.GS Water Resource Invesligations 76. 49. Menlo Parlc, CA. Marcb. Onymo, S. 1985. Chemca abatemenl of acid mie draiage formation. Disserttion, Ph.D. in Engieeri V.C. Berkeley. Potter. 196. Acid mie draiage chacteritics Balakala Mie, Shasta County, CA. U.S.GS. Professional Paper. Reash, R., J. Van Hasel an K. Wood. 1988. Eclogy of a southern Ohio stream receivig fly ash pond dicharge: cbanges from acid mie drage coi:ditimis. Arch. Envion. Cont. Toxcol. 17:543-554. the aquatic Laboratory Augut Shumate, K. E. Smith P. Du~, R. Brent, and C. RaUes. 1971. Development of a conceptual model for pyrte oxidation systems. In: Acid Mie Draiage formaton and abatement. Ohio State University Research Foundation. Study performed for thelJ.S.EPA, Program No. FWCA Grant No. 14010 FPR, ApriL. Singer, P. and W. Stum. 1970. Acidic mine draie: the rate determg step. Science. 167:1121-111. Sobek, lì W. Schulr, J. Freean and R. Smith. 1978. Field and laboratory methods applicable to overbudens and mie soil.1Ddustral EnvionmentalResarcb LaboratOry, Offce ofReseacb and Development. U .S.E A. EP A -60 /2- 7ß.54. March. Sulan P., J. Yelton, and K. Reddy. 1988. Iron sulde oxidaon and the chemitr of acid generation. Environ. Geol. Water sci 11(3):289",295. ___ 198Sb. Solubilty relationships of aluminum and iron mieral associated with acid mi draiage. Envon. Geo!. Water Sci. 11(3):281-28. . mie pollution. Basin Plang area 5A State Water Resources Control Board (S'WCBt 1972. Pnncipal ar of Sactam~nto Riv¡r. Pfeparea for the sWlCB by COMO, Sacrentu,CA. June. ---1~91. Calornia bùd surace waters plan. Water Qualty Control Plan for Inandwaters of Caumi. 91-12 WQ. SWRCB, Sacramento,'CA. Apri. TaYIQr,. E., 'M. Wheeler, and D. Nordstr.om. 1984.lsotoj!ecolXPosition of sulate wacid mie draige .as a meaure of bacteriii oxdatiOD. Natue, Leers to Nate. 30&38-541. Apri Tucker,G" .W. Bei-, and D. Gentz l987.. pH. In: J.. Wm.iams ana G: Schl1aD .eds. Rc:aiin mi~e soil and overburden m the western U.s., analytc paameters aid proC!e.. Soil COIlerv;iÜoD Soety of Amenea .Akeny, Iowa. U,s.BPA. 198. Quantities of cyande-bea and acid-genratwaste.generttd by_the mining an l?neficiati ind\lmes, and the potentita :forcontaant releas. Foom Repot. 'fA!SW/53G6/025. Versan, me. Sprield VA. June 27. __ 1983a. Guidance for prepaatioii of com. . blied workl qualty a.iiaice project plan for water montorig. Offce of Water Reguations andSi:dards. U.S.EPA. WasbigtonD.C. Zl May. _ 1982. Test method for evaluatig solid waSte, pl:ysiclchemieà method. SW-B4. 2nd Edtion, U.s.EPA _~___ 1983b. Methods forcbeniica anal~is ufwater andwasi:... U.s.EA Envi(lmnental Monitorig and Support Laboratory, Reseach and Devell)pment. EPA-600l4079-0. Revi March 1983. Waggoner, M.Per$Oiiå1 Communcation. Area engieer with theCVRWQCB, ~actameDto, CA. Waler, S.t'ersonal OowicaûOI1 Engeeri ge,ologit wi the CVRWQCB, Sacento, CA. WiclÇZ P.and R~ Unz. 1981. Acidophic, heterotrophic bacteria of acidic mme waters. Applied and Envion. 41(5):124-121. Microbiology. Windom H. J.. Byrn. R. Smitl )r.. and F. Rua. 1991.lnadeguacy of NASQAN data for assessinm.etal trends in the Nation's'river. Eñvion. Sc. TècoL .25(6):1137-1141. 32 EXHIBIT H EXHIBIT I LAWRENCE S. BAZEL, STATE BAR NO. 114641 BRISCO IVESTER & BAZEL LLP 2 155 Sansome St., Seventh Floor San Francisco, CA 94104 3 Telephone: (415) 402-2700 Facsimile: (415) 398-5630 4 Email: lbazel~briscoelaw.net 5 DANIEL P. COSTA, State Bar No. 110919 THE COSTA LAW FIRM 6 2489 Sunrise Blvd., Ste. A Gold River, California 95670 7 Telephone: (916) 400-2734 Facsimile: (916) 400-2744 8 Email: dpc~costalaw.net 9 Attorneys for Petitioner ROBERT LEAL 10 11 12 STATE WATER RESOURCE CONTROL BOARD 13 STATE OF CALIFORNIA 14 15 In Matter of ) PETITION NO.: ) 16 ROBERT LEAL, ) ) Petitioner, 17 DECLARATION OF ROBERT LEAL IN SUPPORT OF REQUEST FOR STAY ) ) 18 ) 19 For Review of Technical and Monitoring Report Order No. R5-2010-0049 of the California Regional Water Quality Control 20 Board, Central Valley Region, for the ) Wide Awake Mercury Mine ) 21 ) ) ) ) ) 22 23 I, ROBERT LEAL, declare: 24 1. I am a person named in the Technical and Monitoring Report Order No. R5-2010-0049 . 25 adopted by the California Regional Water Quality Control Board - Central Valley Region on May 27, 26 2010. My business address is 950 Tharp Road, Suite 201, Yuba City, California 95993. DECLARTION OF R08ERT LEAL IN SUPPORT OF REQUEST FOR STAY 2. I respectfully request that the State Board consider the prior declarations I have made 2 and submitted to the California Regional Water Quality Control Board - Central Valley Region on June 3 30, 2009, a copy of which is attached to this Declaration as "Exhibit i." 4 3. If a stay is not granted by the State Board, I wil suffer substantial harm since the Order 5 requires the preparation of reports by July 26, 2010 and continuing thereafter which wil cost a 6 considerable amount of money and take a considerable amount of time to prepare. Obviously, i am 7 not qualified to prepare the reports specified in the Order. I will have to hire consultants to prepare 8 the report. These consultants will require payment regardless of the outcome of this Petition. 9 Furthermore, no other party identified in the Order has expressed to me any wilingness to pay for the 10 reports required by the Order. The Regional Board has not offered to reimburse me for these 11 expenses if I prevail and I do not believe the Regional Board will reimburse if I prevaiL. Since the 12 Order requires the hiring of consultants at significant costs, and since the Regional Board cannot be 13 expected to reimburse me for these costs, I will be significantly harmed if I am required to comply with 14 the order before the Petition is considered. 15 4. In addition, there will be no substantial harm to the other interested person or to the 16 public interest if a stay is granted. i have persistently objected to the Order. None of the other 17 persons named in the Order should expect me to proceed without the filing of a Petition. None of the 18 other persons named in the Order have informed me of any willingness to proceed with the Order. 19 I expect that other parties who have appeared wil file similar Petiions. As a result, a stay would not 20 interfere with the expectations of any other interested parties or otherwise harm any other interested 21 parties. 22 5. Furthermore, the public interest will not be harmed because the stay would merely 23 maintain the status quo. Regional Board staff have concluded that the mining waste piles have been 24 on the property for more than 100 years. The Regional Board has been working on the issue 25 identified in the Order for more than 15 years. Concentrations of mercury in the waste piles on site 26 are within natural background levels and are too low to cause violations of ambient water quality DECLARTION OF ROBERT LEAL IN SUPPORT OF REQUEST FOR STAY standards. Since the site cannot cause a violation of water quality standards, there is no pressing 2 need for any action on the property. As such, the public interest will not be harmed. 3 6. Finally, there are substantial questions of fact in law regarding the disputed action. 4 I have asserted that the Regional Board has acted beyond its statutory authority, contrary to black 5 letter law and even in violation of my due process rights pursuant to the United States Constitution. 6 This Order goes beyond any previous order and any State Board order identified by Regional Board 7 staff. The issues raised in this proceeding are novel and should be resolved before I am required to 8 comply with the Order. 9 I declare under penalty of perjury under the laws of the State of California that the statements 10 made in this Declaration are true and correct and I could and would testify competently thereto. 11 Executed this~ß'l~ day of June, 2010. 12 13 14 ~-. r-37 ROBERT LEAL I i ! 15 16 17 18 19 20 21 22 23 24 25 26 DECLARATION OF ROBERT LEAL IN SUPPORT OF REQUEST FOR STAY EXHIBIT 1 JUN-28-2010 09:27 530 751 6199 630 751 5199 LA WRENCE S. BAZEL (State Bar No. 114641) RiCHARD J. WALLACE (State Bar No. 124286) BRISCOE IVESTER & BAZELLLP 155 Sansome Street, Seventh Floor San Francisco, CA 94 i 04 (415) 402-2700 Fax (415) 398-5630 Attorneys for MR. AND MRS. ROBERT and JILL LEAL CALIFORNIA REGIONAL WATER QUALITY CONTROL BOARD CENTRAL V ALLEY REGION In the matter of: DRAFT CLEANUP AND ABATEMENT ORDER THE WIDE AWAKE MERCURY MINE COLUSA COUNTY Declaration of Robert Leal I, Robert Leal, declare: i. I am a person named in the Draft Cleanup and Abatement Order revised as of June 10,2009 (the "Draft Order"). My business address is 950 Tharp Road, Suite 201, Yuba City, California 95993. 2. During the early 19908, I owned a half interest in propert identified by Attachment B to the Draft Order as the former Wide Awake Mine (the "Site"). I never at any time conveyed any interest in the Site to my wife, Jil LeaL. P.02 JUN -28-2010 09: 27 3. As par of 530 751 5199 the sale of 530 751 5199 my interest in the parcels that make up the Site, the title company insisted that my wife sign deeds conveying any interest she might have in the Site to me, even though she did not have any interest. I understood these deeds to be a formality that title companies insist on. 4. i am a farmer. i have never studied mining, and I have no knowledge about mining issues. I do not have any specific knowledge about mercury, its occurrence or movement ~b in soil or water, its chemistry or biochemistry, o~xicOlogy or risk to human health or the environment. i never studied, and am not an expert in, chemistry, biochemistry, or toxicology. 5. I did not know that there was a former mine on the Site when i purchased my h:terest in it. I purchased a larger area of property (the "Propert"), of which the Site was a relatively small portion, for investment purposes. lleared about the Propert from Tom Nevis, who controlled Goshute Corporation. Mr. Nevis had arranged to purchase the propert from Wells Fargo Bank, but needed money to complete to transaction. I provided that money, and in return received a half interest in the Property. The other half interest went to NBC Leasing, another corporation controlled by Mr. Nevis. 6. i never conducted any operations on the Propert. I leased it out to the Harter Land Company, which used it for grazing. 7. I did not lear that there was a fonner mine on the Site until I tried to sell part of the Property to the U.S. Bureau of Land Management. The Bureau provided me with an evaluation by their geologist dated November 6, 1992, which I understand wil be submitted to the Regional Board as part of my comments. 8. After I found out about the former mine, 1 went to look for it. I had assumed that it was a gold mine, and did not understand that it was a mercury mine. i was taken there by 2 P .03 JUN-28-20 1 0 09: 27 530 751 5199 530 751 5199 Roy Whiteaker, who was the real estate broker trying to sell the Site, and who owns Cal Sierra Properties, which eventually bought the Site to LIse for hunting. We never saw anything that looked like a mine. A II we saw was a remnant of a brick structure. I did not see any pi les of rock or other materials. I did not, and stil do not, know what "tailings" are. Grass had grown over the area, and there was not much to see. I did not see anything that seemed like it might contain mercury. J did not, and stil would not, know what mercury looked like even ifI saw it. Other that that one visit, J have never been to the Site. 9. During the time I partly owned the Site I did not know that mercury might be leaving the Site. I did not know that anything on the Site might be causing a nuisance. No one ever informed me, during the time of my par ownership, that mercury might be leaving the Site or that anything on the Site might be causing a nuisance. I had absolutely no idea that I should be doing anything on the Site to protect public health or the environment. I hereby declare under penalty of perjury under the laws of the State of California that the statements made in this declaration are true and correct. ~ Dated: June 30,2009 Robert Leal 3 P.04