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Polarizers θ
Polarizers Actual polarizers. Irradiance is independent of the rotation angle θ for the conversion of natural light (unpolarized) to linear polarization. In the figure below, only the component E01cosθ is transmitted I(θ) = I(0)cos2θ, which is known as Malus’s Law. If Iu = I (natural or unpolarized light), then I(0) = Iu <cos2θ>t = Iu/2. Dichroism –selective absorption of one of two orthogonal E components Dichroic polarizers are not suitable for high intensity light, because of high joule heat due to absorption 1. Absorption of E-field in the ydirection causes e’s to flow. 2. Re-radiation of waves that cancel incident waves polarized in the y-direction. This results in transmission of waves with E-fields perpendicular to the wires (i.e., along the xdirection). Polaroid sheet (H-Sheet), most commonly used linear polarizer. Contains a molecular analogue of the wire grid. 1. Sheet of clear polyvinyl alcohol is heated and stretched. 2. Then it is dipped in an ink solution rich in Iodine. 3. Iodine is incorporated into straight long-chain polymeric molecules allowing electron conduction along the chain, simulating a metal wire. HN-50 is the designation of a hypothetical, ideal H-sheet that transmits 50% of the incident natural light while absorbing the other 50%. In practice, about 4% of the light will be reflected at each surface leaving a maximum transmittance of 92% for linearly polarized light incident on the sheet. Thus, HN-46 would transmit 46% of incident natural light, and might be the optimal polarizer. In general, for HN-x, the irradiance of polarized light transmitted would be I=Io(x/50), where Io is the irradiance for the ideal case. In practice, it is possible to purchase HN-38, HN-32, and HN-22 in large quantities for reasonable prices, each differing in the amount of iodine present. Tourmaline Crystal System: Hexagonal (trigonal) Habit: As well-formed, elongate, trigonal prisms, with smaller, second order prism faces on the corners. Prism faces are often striated parallel to direction of elongation (c-axis). The rounded triangular cross-sectional shape of tourmaline crystals is diagnostic; no other gem mineral has such a shape. Hardness: 7-7.5 Cleavage: none High birefringence (Two differenct indices of refraction) Strong Dichroism Any transparent gem having a mean R.I. of 1.63 and a birefringence of 0.015-0.020 is tourmaline. Tourmaline is widespread in metamorphic, igneous and sedimentary rocks. Gem Elbaite is, however, nearly restricted to pegmatites. Literally thousands of tourmalinebearing pegmatites are known; only a few hundred apparently contain gem quality material in mineable quantities. Found in Brazil, Sri Lanka, U.S., Southern California Tourmaline Boron Silicates) Chemical Formula Specific Gravity XY Al B Si OH (X Y Na or Ca) Hardness Mg, Li, Al or Fe Refractive Index - 1) There is a specific direction within the crystal known as the principal or optic axis. 2) The E-field component of an incident wave that is perpendicular to the optic axis is strongly absorbed. 3) The thicker the crystal the more complete will be the absorption. 4) A plate cut from a tourmaline crystal parallel to its principle axis and several mm thick will serve as a linear polarizer. 5) Absorption depends on λ. 6) Advantages over H-sheet polarizers with regard to maximum irradiance permitted and can be used with high power lasers. Birefringence: Anisotropies in the index of refraction Arrangement of atoms in a crystal can lead to both a structural asymmetry and an anisotropy in the optical properties, as we just saw with tourmaline, which is a dichroic crystal. The speed of the E-M wave depends on the refractive index n, and therefore on the difference between the frequency of the E-field (ω) and the natural frequency (ωo) of the atom. ωo depends on the binding forces attracting the valence electrons to the atom. 2 qe N 1 n (ω ) = 1 + ε o me ωo2 − ω 2 2 Consider a mechanical model for the atom in which the spring stiffness, k, is directiondependent, and such that kx > ky = kz, where F = kix. The resonant frequencies for oscillation depend on the direction of polarization: E || yˆ ω0 y = k y / me E || xˆ ω0 x = k x / me kx > k y ω0 x > ω0 y As a result of the anisotropy in ωo, the refractive Light with frequency ωd will appear index will depend on the polarization direction. in the absorption band for the y polarization and will be transparent for the x polarization. This is an (a) example of a dichroic crystal which will allow transmission of light E || xˆ while strongly absorbing light with. E || yˆ 2 E || yˆ q N 1 n 2 (ω ) = 1 + e ε o me ωo2 − ω 2 (b) ωox > ωoy E || xˆ n y (ωb ) > nx (ω b ) The birefringent case is for ω = ωb in which absorption is negligible for both polarizations, but the index of refraction depends on the polarization. In the simple mechanical model, the spring stiffness is such that cx > cy = cz and thus the x-axis is the direction of the optic axis. Optic axis x Optic axis E z y Plane ⊥ optic axis Notice that for polarizations with E in a plane normal to the optic axis, the index of refraction n is independent of the polarization orientation. Let’s consider now calcite (calcium carbonate) CaCO3 which is an important birefringent material. It is also the most common material for making linear polarizers for high power lasers. NaCl Sodium Chloride fcc – Face-centered Cubic Calcite is the third most common mineral in Earth’s crust (behind feldspar and quartz). Because of its abundance, calcite can be found in many rock types. A Calcite in Sedimentary Rocks Calcite or Calcium carbonate (CaCO3) --- Rhombohedral unit cell Unit Cell The sedimentary rock limestone makes up approximately 10 percent of all sedimentary rock. Limestone consists almost entirely of calcite. It forms because many marine organisms make shells and other hard body parts out of calcium carbonate. When the organisms die, their shells or hard body parts settle to the ocean floor. Through time, they can accumulate into great thicknesses of calcite mud. This mud, if turned into rock, becomes limestone. Chalk, a form of limestone, consists of the calcium carbonate remains of innumerable microscopic floating marine organisms, such as foraminifera and coccolithophores. From MSN Encarta Calcite or Calcium carbonate (CaCO3) 3-fold symmetry CO3 carbonate groups are all in planes normal to the Optic axis. Large Birefringence The birefringent property of calcite leads to the formation of two images as shown in these examples. The images are related to the existence of ordinary rays (o-rays) and extraordinary rays (e-rays). An analysis of these rays shows that both these rays are linearly polarized. We will describe the nature of these rays in detail in the coming slides. Colorless Calcite Rhombohedron with a long edge of ~12 cm. It is possible to cleave calcite and form sharp faces that create a cleavage form (rhombohedron) as shown below possessing faces of a parallelogram with angles of 78.08° and 101.92°. There are only two blunt (not sharp) corners (labeled A and B) where the surface planes meet. A line passing through the vertex of each of these blunt corners and oriented so that it makes equal angles with each face (45.5°) and each edge (63.8°) is clearly an axis of 3-fold symmetry. The 3-fold axis is related to the 3-fold symmetry of the CO3 carbonate groups shown previously and the line representing this axis must be then parallel to the optic axis of the crystal, as shown. B A Principal Plane - Contains the optic axis. There are many planes that can be drawn in this manner, as shown. Principal Section – A principal plane that is normal to the pair of opposite surfaces of the cleavage form (rhombohedron). E E E|| When E lies in the principal section, we can express the sum in terms of ⊥ and || components, with respect to the optic axis. Optic Axis The principal section is also a parallelogram, with angles as shown. Note that the ray direction is altered (despite the normal incidence on the section) when the electric field contains non-zero components that are both parallel and perpendicular to the optic axis. This phenomenon is a result of different propagation velocities, v|| and v⊥, associated with each electric field component. We will see that we can express the propagation velocities, as follows: v|| = c/ne ne = 1.486 v = c/no no = 1.658 The o-wave, with its perpendicular polarization, exhibits a single propagation velocity, v⊥. The wave stimulates numerable atoms at the surface producing a source of radiating spherical wavelets, the summation of which leads to a plane wave propagation as in the case of an isotropic medium like glass. Rays in the center calcite crystal contain both || and ⊥ E-field components, leading to the characteristic double image of the line. KCl and NaCl are isotropic cubic crystals and are thus do not exhibit birefringence. Light emitting from a point source will be isotropically emitted in all directions leading to a spherical wave. In the above figure, E lies in the principal section, defining the e-wave, and E = E|| + E⊥, where E|| || Optic-axis. Each component will propagate with velocities, v|| and v⊥, respectively. The result is that a point at the interface emits waves that are elongated into an ellipsoid of revolution rather than a spherical shape. v|| = c/ne ne = 1.486 v = c/no no = 1.658 The anisotropic propagation v|| > v⊥ causes a distortion in the wavefront and changes the propagation (Poynting vector) direction indicated by S in the figure for the e-wave. Remember that S = v2εE×B, and represents the direction in which the irradiance of the wave propagates and thus defines the ray direction. Note that solutions to Maxwell’s equations give: k ⊥D and S⊥E. For e-waves, S||k only in propagation directions || or ⊥ to the optic-axis. For o-waves, E||D and S||k for all propagation directions. All crystals having symmetries that are hexagonal, tetragonal, and trigonal are optically anisotropic and will lead to birefringence. In such crystals, an optic axis exists and about which the atoms are arranged symmetrically. Crystals possessing only one such optic axis are known as uniaxial. As mentioned, cubic crystals like NaCl and KCl are symmetric, do not possess an optic axis, and do not exhibit birefringence. The difference ∆n = ne – no is a measure of the birefringence. For calcite ∆n = 1.486 – 1.658 = -0.172, v|| > v⊥, and the crystal is referred to as negative uniaxial. Consider hypothetical point sources of natural light embedded within negative and positive uniaxial crystals, as shown in the left and right figures. The shape of the ellipsoids depends on sign of ∆n (+ or -) as shown. Thin layer of balsam cement with n = 1.55 Other Crystallographic systems: Orthorhombic, monoclinic, and triclinic have two optic axes and are biaxial. For example, Mica KH2Al3(SiO4)3 has three different indices n. Birefringent devices – Separation of the o- and e- rays. The Nicol Prism, a Birefringent Polarizer. Thin layer of balsam cement with n = 1.55 For calcite, again, ne = 1.486, no = 1.658 A calcite crystal that is cut, polished, and painted, separates the o-ray and e-ray via TIR (total internal reflection). A thin layer of balsam glues two halves of the crystal. Balsam has an index of refraction, nb, which is between that of the o- and e-rays, i.e., ne < nb < no. Thus, the o-ray experiences TIR at the balsam interface and is absorbed by the layer of black paint on the side. The e-ray refracts normally at the balsam interface an leaves the crystal at the bottom. Therefore, the emitted ray can be used as a fully linearly polarized beam. The Wollaston Prism – Polarizing Beam-splitter A polarizing beam-splitter passes both orthogonally polarized components that can be separated. The oray becomes the e-ray and vice-versa as the rays traverse from the first to the second section. Interfaces are polished flat and optically smooth to allow rays to refract at the interfaces. For calcite, again, ne = 1.486, no = 1.658 Birefringent Polarizer (mainly for high-power lasers) where we can’t use polaroid sheet since it will melt. o-ray absorping paint e-ray no sin θ o = nair sin θ r sin θ cr −o = 1 / no = 1 / 1.658 θ cr −o = 37.1° sin θ cr −e = 1 / ne = 1 / 1.486 Air gap θ cr −e = 42.3° Figure 8.27 The Glan-Foucault prism Calcite-air interface: θcr-o < θ < θcr-e in order for the o-ray to experience TIR The e-ray will not experience TIR. This prism is similar to the Nicol, prism but without the use of balsam cement. Polarization by Reflection Fig. 8.32 At θp , the reflected beam is linearly polarized ⊥ to the plane of incidence. The transmitted beam, however, is strongly polarized || to the plane of incidence and weakly polarized ⊥ to the plane of incidence, i.e., it is partially polarized. Polarization by reflection and derivation of Brewster’s angle is found by examining the Fresnel equations: sin(θ i − θ t ) r⊥ = − sin(θ i + θ t ) 2 sin θ t cos θ i t⊥ = sin(θ i + θ t ) and tan(θ i − θ t ) , r|| = tan(θ i + θ t ) and 2 sin θ t cos θ i t|| = sin(θ i + θ t ) cos(θ i − θ t ) tan 2 (θ i − θ t ) R|| = r = →0 2 tan (θ i + θ t ) 2 || cos 2 (θ i + θ t ) = 0 θ i + θ t = 90° Thus, the reflected wave becomes entirely polarized ⊥ plane of incidence (and || to the surface) for θi = θr = θp (polarization or Brewster’s angle) when θi + θt = 90°. θ p + θ t = 90° and ni sin θ p = nt sin θ t = nt sin (90° − θ p ) = nt cos θ p tan θ p = nt / ni Brewster’s law Different approaches for using Brewster’s law to obtain polarized light by reflecting from multiple surfaces or thin films. Polarizing sunglasses take advantage of the fact that in nature "glare" consists mainly of light-having a horizontal vibration direction. The reason for this is that sunlight comes downward and hits mostly horizontal surfaces (such as the oceans). Reflection from such a surface results in polarization with a predominant horizontal vibration (i.e, normal to the plane of incidence). The sketch below shows that in polarizing sunglasses the transmission axis is vertical and thus reduces the glare reflected from horizontal surface. Transmission axis is vertical Consider a beam of unpolarized natural light striking a surface. If the incoming light is unpolarized, then I i|| = I i ⊥ = I i / 2 I r|| = R|| I i / 2 and R= I r || + I r ⊥ Ii = I r ⊥ = R⊥ I i / 2 R|| + R⊥ 2 , where the subscripts i and r refer to incident and reflected beams. For a beam containing varying amounts of polarized and unpolarized components, we can introduce a concept called “Degree of polarization” V: Ip I max − I min = , where I P = I max − I min V= I max + I min I p + I n and I n = 2 I min For polarized light – V=1 For natural light – V=0 Imax and Imin are the maximum and minimum intensities obtained by rotating the linear polarizer relative to the detector. Likewise Ip and In are the polarized and unpolarized contributions, respectively, of the beam. (Ip + In) Mixed polarization from a source Rotatable linear polarizer Light detector Retarders: Methods for changing the polarization state of a beam Cut and polish a calcite crystal so that its optic axis will be ⊥ to both the front and back surfaces, as shown below. o- and e-waves propagate without any relative changes in phases, i.e., the components with all polarization orientations will traverse the distance AB in the same amount of time and have the same speed. Suppose now that we cut the crystal so that the optic axis is || to the front and back surfaces, as shown below. Since no > ne we have v|| > v⊥ and the e-wave reaches the opposite face before the o-wave. Difference in optical path length, OPD, Λ = d| no – ne|; ∆ϕ = koΛ = (2π/λo) d| no – ne| λo is the vacuum wavelength. The final polarization state depends on the amplitudes of the o- and e-waves and on ∆ϕ. Note that the e-wave will have a higher speed in a negative uniaxial material, i.e., v|| > v⊥. The situation is reversed in a positive uniaxial material. A half-wave plate introduces a relative phase shift ∆ϕ = π between the o- and e-waves, as shown below. Therefore this phase-shift condition requires ∆ϕ = 2π λo d= d no − ne = (2m + 1)π where m = 0, 1, 2, 3, ... (2m + 1)λo 2 no − ne Before striking the plate, we have a linearly polarized beam of the form E = (E0 x xˆ + E0 y yˆ )cos ωt After reaching the second face: E = E0 x cos(ωt + ∆ϕ ) xˆ + E0 y cos(ωt ) yˆ Since ∆ϕ = (2m + 1)π E = (− E0 x xˆ + E0 y yˆ )cos ωt Therefore, the E-field vector is rotated 2θ about the y-axis. θ = tan −1 E0 x E0 y Half-wave plates are sometimes called polarization rotaters. Note that these plates will also change the handedness of circularly or elliptically polarized light by introducing a ∆ϕ = π (relative phase) between the e- and o-waves: [ ] (Right circularly polarized light) E = E0 iˆ cos(kz − ωt ) + ˆj sin (kz − ωt ) E = E0 − iˆ cos(kz − ωt ) + ˆj sin (kz − ωt ) (Left circularly polarized light) [ Note that elliptical light will similarly be flipped by an angle θ. ] Quarter Wave Plate: Linearly polarized → Circularly polarized and vice versa ∆ϕ OPD Λ d no − ne = = = 2π λ0 λ0 λ0 ∆ϕ = 2π λ0 d no − ne = (4m + 1) (4m + 1)λ0 d= 4 no −n e R π 2 m = 0, 1, 2, .. Point of observation is from behind the quarter-wave plate and so the eye sees a Right-circular wave. Since the angle is θ = 45°, Eox = Eoy. for the linearly polarized beam striking the quarter-wave plate. Quarter-wave plate converts linearly polarized light to circularly polarized light Right circular (R ) Linearly polarized light, oriented at 45° to the direction of the crystalline optic axis, is treated as an x-component and a y-component, each equal to the other. Upon entering the birefringent crystal, the y-component, aligned with the fast axis travels through the crystal faster than does the x-component, which is aligned with the slow axis The two components are thrown 90° out of phase with each other, such that upon emerging, one is always maximum while the other is always zero and vice versa. The effect is to produce right circularly polarized light, as seen by an observer looking into the crystal. The 90° phase shift is produced by a precise thickness d of the birefringent crystal, which, because of the 90° shift, is referred to as a quarter wave or λ/4 plate. Quarter Wave Plate: Linearly polarized → Circularly polarized and vice versa Again we add the phase ∆ϕ to the x-component. If the fast axis is vertical along y, then the x-component (o-wave) will lag behind the y-component (e-wave), causing ∆ϕ = π/2. v|| = c/ne ne = 1.486; v = c/no no = 1.658 E = E0 x cos(ωt − ∆ϕ ) xˆ + E0 y cos(ωt ) yˆ and E0 x = E0 y Since ∆ϕ = (4m + 1)π / 2 E = E0 (xˆ sin(ωt ) + yˆ cos(ωt ) ) E0 If the initial linear polarization had been rotated 90° (i.e., θ = -45°), then the resulting polarization state would have been left circular polarization. Therefore, left and right circular can be obtained by simply performing a 90° rotation relative to the fast axis. ω Right circular polarization, i.e. an R – state. On the other side of the plate, we again examine the wave at a point where the fast-polarized component is at maximum. At this point, the slow-polarized component will be passing through zero, since it has been retarded by a quarter-wave or 90° in phase. If we move an eighth wavelength farther, we will note that the two are the same magnitude, but the fast component is decreasing and the slow component is increasing. Moving another eighth wave, we find the slow component is at maximum and the fast component is zero. If we trace the tip of the total electric vector, we find it traces out a helix, with a period of just one wavelength. This describes circularly polarized light; right-circular light is shown in the figure below. You may produce left-hand polarized light by rotating either the wave plate or the plane of polarization of the incident light 90° in the figure below. Right circular polarization (R – state) y x z A quarter wave plate can similarly be used to transform circularly polarized light into linearly polarized light. Again, care must be taken in order to determine the resulting orientation of the linear polarization. The example below shows how two quarter wave plates will act like a half-wave plate in rotating the final polarization vector by 90° for linear polarization. Unpolarized source Fast axis Left circular (L ) Rotation of 90° Note that the rotation of linear polarizer D by 90° will filter the light, yielding zero transmission. The result is that the combination of a quarter-wave plate and a linear polarizer can be used both as a circular polarizer (A+B) and analyzer (C+D) when used in reversed orientation. 90% In2O3-10% SnO2 ! " ! ! "! " " # " ! ! ! ! " ! " The polarization state of a light beam As we saw earlier the degree of polarization is defined by: Ip I max − I min = , where I P = I max − I min V= I max + I min I p + I n and I n = 2 I min V=1 For polarized light and V=0 for natural light V can be measured by one linear polarizer. The different states of polarizations can be analyzed by measuring the beam intensity through several polarizers as will be described below: The Stokes parameters, a description of the polarization state of light using four parameters. Begin with a set of four filters. Under natural illumination, each will transmit half of the incident light. Use the following description for the filters, although the choice is not unique: Filter 1: Isotropic and passes all polarization states equally. Filter 2: Ideal linear polarizer which transmits horizontal polarizations. Filter 3: Ideal linear polarizer which transmits polarizations with θ = 45° (1st and 3rd quadrants). Filter 4: Circular polarizer filter that is opaque to left-circular light (see previous slide). Each of these filters is then placed alone in the path of a beam and the transmitted irradiances I0, I1, I2, I3 are respectively measured with a detector for each filter. Define the Stokes parameters by the following relations: S0 = 2I0, S1 = 2I1 – 2I0, S2 = 2I2 - 2I0, and S3 = 2I3 - 2I0 S0 – Reflects the incident irradiance, regardless of the beam polarization S1 – Reflects the tendency for the polarization to be linear/horizontal (S1 > 0) or linear/vertical (S1 < 0) or neither (S1 = 0). S2 - Reflects the tendency for the polarization to be linear/with θ = 45° (S2 > 0) or linear/with θ = -45°(S2 < 0) or neither (S2 = 0). S3 – Reflects the tendency of the beam for being right circular (S3 > 0), left circular (S3 < 0), or neither (S3 = 0). Consider the expressions for quasi-monochromatic light: [( ) E x (t ) = iˆE0 x (t ) cos k z − ωt + ε x (t ) ] and [( ] ) E y (t ) = ˆjE0 y (t ) cos k z − ωt + ε y (t ) , where E (t ) = E x (t ) + E y (t ) The Stokes parameters can be expressed in terms of the E-M wave parameters by time averages as S 0 = E02x T + E02y , S1 = E02x T T − E02y , S 2 = 2 E0 x E0 y cos ε , and S3 = 2 E0 x E0 y sin ε , where ε = ε y − ε x T T T (Note that we are dropping the constant ε0c/2 for convenience.) If the beam is unpolarized, then E02x T = E02y cos ε (t ) T T , S 0 = 2 E02x , S1 = S 2 = S3 = 0 because = sin ε (t ) T T = 0. Let us now normalize the Stokes parameters by dividing each one by S0. Thus the set of Stokes parameters an incident beam of unit irradiance can be expressed with 4 × 1 column vectors: S0 1 S1 , which is S0 S2 S3 1 0 0 0 for natural or unpolarized light Representations of this vector for other polarization states are in the table. For completely polarized light S 02 = S12 + S 22 + S 32 . 2 2 2 The degree of polarization is given by V = S1 + S 2 + S3 / S 0 . If we have a superposition of two quasi-monochromatic waves that are incoherent, the resulting Stokes parameters can be determined by just adding the vectors as follows: S 0' S 0'' S 0'+ S 0'' S1' S1'' S1'+ S1'' S S ' 2 ' 3 + S S ' ' 2 ' ' 3 = S 2' + S 2'' S3'+ S3'' Suppose that a unit flux density vertical P - state is added to an inchohrent L - state with flux density 2, as follows: 1 −1 0 0 + 2 0 0 −2 = 3 −1 0 −2 The resultant wave is an ellipse of flux density 3, more vertical than horizontal (S1 < 0), left-handed (S3 < 0) and has a degree of polarization V = 1 + 4 / 3 = 5 / 3. The Jones Vectors: Another representation of polarized light, being applicable to only polarized waves. The Jones vector is written as E x (t ) . E= E y (t ) In order to handle coherent waves, we will need to preserve the phase information. We can write the vector in complex form: E0 x eiϕ x ~ E= iϕ y . E0 y e Horizontal and vertical P - states are given by E 0 x e iϕ x ~ Eh = 0 and ~ Ev = 0 iϕ E0 y e y ~ ~ ~ with E = Eh + Ev The sum of two coherent beams, as with the Stokes vector, is formed by the sum of the corresponding components. ~ iϕ x 1 For example, if E0 x = E0 y , ϕ x = ϕ y , then E = E0 x e 1 which is a P - state at +45° (in the 1st quadrant), since the components have equal amplitudes and ∆ϕ = 0. In many applications it’s not necessary to know the exact amplitudes and phases. Like the Stokes case, we can normalize the irradiance to unity, which will result in a loss of phase information. This simplification leads to 1 1 E45 = , 2 1 Eh = 1 0 , and Ev = 0 1 . Similarly, we can express right circular light as ~ ER = 1 E 0 x e iϕ x iϕ x iϕ x 1 = E0 x e = E0 x e − iπ / 2 i (ϕ x −π / 2 ) e −i E0 x e Therefore, the normalized complex Jones vectors for circular polarization are 1 1 ~ ER = 2 −i 1 1 ~ . EL = 2 i and Note that 1 1+1 2 1 ~ ~ ER + EL = = 2 −i +i 2 0 The last sum is a horizontal P - state having an amplitude twice that of an Ex or Ey component in either circular wave. The orthogonality of two vectors, both real and complex, are defined as follows: ~ ~ A ⋅ B = 0 for real vectors and A ⋅ B * = 0 for complex vectors and ~ ~ ~ ~ note that ER ⋅ EL* = (1)(1)* + (−i )(i )* / 2 = 0, and Eh ⋅ Ev* = (1)(0)* + (0)(1)* = 0 , ~ ~ ~ ~ also note that ER ⋅ ER* = EL ⋅ EL* = 1. [ ] [ ] Any polarization state can therefore be described as a linear combination of the vectors in either one of the orthonormal sets. These ideas are analogous to those developed in quantum mechanics. Matrix methods for determination of the polarization state involving transmission of waves through various optical elements Let’s introduce 2 × 2 matrix A (the Jones matrix) to calculate the transformation of an incident polarized beam on an optical element into a final polarization state. That is we are going from polarization states i → t. a11 ~ ~ Then Et = AEi , where A = a21 a12 a22 The above table contains a brief listing of Jones matrices for various optical elements. Suppose that we have a P - state at +45° passing through a quarter wave plate whose fast axis is vertical (i.e., the y-direction). Then 0 ~ iπ / 4 1 Et = e 0 −i 1 1 e iπ / 4 1 0 1 e iπ / 4 1 = = 2 1 2 0 −i 1 2 −i The resulting beam is right-circular (we can ignore here additional factors). For a serious of optical elements, multiplication of the following matrices gives ~ ~ Then Et = An ... A3 A2 A1 Ei Note that the matrices do not commute and order must be maintained. Suppose that we have a P - state at +45° passing through two quarter wave plates whose fast axis is vertical (i.e., the y-direction). Then 0 iπ / 4 1 0 ~ iπ / 4 1 Et = e e 0 −i 0 −i 1 1 e iπ / 2 1 0 1 e i π / 2 1 = = 2 1 2 0 −1 1 2 −1 The transmitted beam is just a P - state at -45°, having been flipped 90° by a two quarter wave plates acting as a half-wave plate. Note that just as we did for lens matrices, we can calculate the 2 × 2 system matrix: A = An ... A3 A2 A1 System A similar method can be applied to beams that are best represented by the Stokes vector. For example, there may be optical systems involving the transmission of polarized and partially polarized light. This method involves Mueller matrices, as listed in the table. Note that the Jones method can deal with polarized waves whereas the Stokes/Mueller method deals with polarized and unpolarized superposition of waves. The Mueller matrices are used in much the same way as the Jones matrices. For example, let’s pass a unit-irradiance unpolarized wave through a linear horizontal polarizer. The Stokes vector of the transmitted wave is 1 1 0 0 1 1/ 2 1/ 2 1 1 1 0 0 0 St = = 0 2 0 0 0 0 0 0 0 0 0 0 0 Thus, the transmitted wave has an irradiance of S0 = ½ and is linearly polarized horizontally since S1 > 0. As a second example, we take a partially polarized elliptical wave whose Stokes parameters have been determined to be (S0, S1, S2, S3) = (4, 2, 0, 3). The irradiance is 4. Since S1 > 0, it is more nearly horizontal than vertical. S3 > 0 implies that it is right handed. It has a degree of polarization V = (4+0+9)1/2/4 = 90%. Since S3 is not much less than S0, the ellipse resembles a circle. Suppose that this beam now traverses a quarter-wave plate with a vertical fast axis, then 1 0 St = 0 0 0 1 0 0 0 0 0 0 0 −1 1 0 4 4 2 2 = −3 0 3 0 The transmitted beam has the same irradiance and degree of polarization but is now partially linearly polarized since S2 < 0 and reflects the tendency for the polarization to be linear with θ = -45°. Again, using the 4 × 4 Mueller matrices, it is also possible to perform calculations with a variety of optical elements leading to a system matrix: A = A ... A A A . System n 3 2 1