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Management & Engineering
Management & Engineering 03 (2011) 1838-5745 Contents lists available at SEI Management & Engineering journal homepage: www.seiofbluemountain.com Mode of Developing New Energy Sources: Garden Waste to Produce Ethanol Technology Zhi Li, Lijun Sun School of Economics and Management, Beijing Forestry University 100083, China KEYWORDS ABSTRACT Garden waste, Garden waste for ethanol production technology, New energy development model Nowadays the main processing methods about the garden waste recycling, such as incineration, landfill, composting, and rough, still have some defects and problems. On the basis of extensive experiments on the garden wastes, we are introducing a new technology to produce ethanol by garden waste ,which can not only make full use of garden waste and reduce maintenance costs of urban greening, but also provide a new energy development model, and to a certain extent, ease the energy crisis our country. It has enormous economic, social and ecological benefits. © ST. PLUM-BLOSSOM PRESS PTY LTD 1 Introduction Garden plants garden plant waste mainly refers to natural or artificial pruning litter produced by the plant debris, including wastes, clippings, pruning trees and shrubs, with its main components of wood fiber [1]. With increasing urban green coverage, the number of garden waste growing day by day , if we don’t treat it seriously, it will not only affects the appearance of the city, but also cause environmental pollution. At present the basic approach is incineration, landfill, etc. Chen Xiang, Xian Xudong, Bao Bing (2009) held the view that landfill or incineration will cause environmental pollution and resource waste, and proposed other approaches like compost, green coverage and utilization of product development approach [2]. Lv ZiWen, Fang Hailan (2007), Liang Jing (2009), Yang Hui (2010) introduced landscape waste treatment and disposal methods in U.S specifically, such as compost proportion, composition and classification, collection methods, optimization of composting process parameters (e.g.particle size, humidity, carbon and nitrogen ratio and pH value, etc.), standards of product quality and technical specifications and so on, they proposed some recommendations such as classified collection of garden waste and garbage, set up a special court for smashing the branches, compost to field and so on [3-5]. Beijing, as the country's capital, its green coverage had straight up in recent years, and in 2007 reached 43.0%. With the acceleration and expansion of green field, landscaping waste has become a huge source of pollution to urban environment .In 2007, Beijing generated 2.36 million ton landscape waste, most of which was landfilled as a solid waste, and the resource re-utilization rate is only 0.7%. In this regard, Yu Xin, Sun Xiangyang, Xu Jia (2009), through surveys, made an empirical analysis of the landscape in Beijing and its re-use of waste, presented three approaches, that is ,the re-use composting, production of new flowers matrix, covering the production of organic gardening. [6] Developing new energy, carrying out industrial revolution, is an effective way to achieve sustainable development and a low carbon Corresponding author . Email: [email protected] English edition copyright © ST. PLUM-BLOSSOM PRESS PTY LTD DOI:10.5503/J.ME.2011.03.015 87 economy [7-9]. In a variety of new energy, biomass attracted the attention of many scholars, Dong Youfu, Hou Fang’an (2007) and Liu Jianfu, Bai Yurui (2009) held that with the deterioration of the global environment and energy crisis, renewable energy represented by enhanced solar and biomass had increasingly become the focus of attention, so we should be fully aware of the value of crop straw, and promote the comprehensive utilization of straw [10, 11]. LiTao, Zhuo Haifeng (2008) describes the environmental pollution and resources waste caused by incineration of straw, and proposed several measures such as straw Production of feedstaff, straw processing, gas producing [12]. As for the way of straw utilization, scholars also discussed. Zhang Zhenhan (2006) proposed the straw power generation and plate-making technology [13]. Xie Zuqi, Liu Jianhui (2007) proposed straw gasification technology [14]. Can we combine garden waste disposal and new energy development together and propose a new low-carbon economy model to make full use of the biomass energy of garden waste? There are still no such studies. So, through the analysis of the experimental on the garden waste such as weeds and sawdust , we are exploring the this new energy technology development ,which is to use garden waste to produce ethanol. 2 The Status of Garden Waste Recycling United States, Canada, Belgium and Australia and other countries have made a very good use garden waste so far. In the U.S., urban greening has come out of the traditional methods and been replaced by producing renewable soil, compost instead of natural soil in city greening. Many studies in United States have shown that the re-use of garden plant waste is more economical and more environmentally friendly than landfill and incineration. According to statistics, the cost of puting garden waste into landfill is 350 dollars, the carbon dioxide produced by the burning of garden waste a ton is 230 kg, so many states in US have enacted laws relating to the funding security measures to implement garden waste recycling. Because of the protection policy and funding, the garden waste recycling ratio in the United States increased each year from 12.4% in 1990 to 62.0% in 2005. In 2007, Chao Yang District in Beijing established the first domestic large-scale professional garden plant waste disposal site. After reduction treatment and a series of manufacturing processes, waste disposal sites can produce the necessary bio-organic fertilize , organic substrates ground cover and other products in the urban greening. In addition, Guangzhou, Shenzhen and other economically developed regions have started the garden waste recycling as well. Management Office in Shenzhen City has been operating for 11 years since 1998. The amount disposed by the Crush site is very large. 3 The Problems of Current Methods Current treatment of plant wastes are incineration, landfill, composting, and rough and so on. 3.1 Incineration Burning garden wastes can produce large amounts of harmful gases (such as nitrogen oxides), which pollute the atmosphere. Besides, it can bring a large number of carcinogenic particles (such as dioxin, trip-benzopyrene and quadr-benzopyrene), which do harm to human health, so this kind of approach has been gradually prohibited in recent years. 3.2 Landfill and composting Landfill disposal and composting wastes is still the common means. Composting refers to the occurrence of biochemical degradation and the formation of organic fertilizer by the use of microorganisms in a certain temperature, humidity, pH and other conditions. Garden organic waste is rich in N, P, K and other nutrients. Through composting and other treatment ,it can be used as fertilizer in the soil, which can effectively restore soil nutrients, increase soil organic matter content, stimulating microbial activity, improve soil physical structure and chemical composition, increase soil porosity, and enhance soil capacity to retain water and fertilizer. At present, major cities such as Shanghai, Beijing, Guangzhou and Shenzhen, have started composting of the garden waste However, as garden wastes contain less water and are light in weight, the transport and removal costs may increase through the landfill. In addition, landfill and composting sites need a large space and a long fermentation period and the degradation and transformation is not complete, this method will not only bring about secondary pollution, but also lead to other security issues. 3.3 Plate National attitudes to protect forest resources become increasingly clear, measures such as cutting of forests to limit and logging ban have been taken more seriously. In next few years China's timber harvesting will be reduced to very low commodity level, plate production industries face enormous challenges and the supply of raw materials will become a bottleneck. To find new materials to replace natural wood may be a way out. Wastes after rough handling, can also be pressed into sheets, but these plates crushed by garden wastes are of loose granular material and are poor in bearing pressure, so there still be some challenges in their use and consumer acceptance. 3.4 Feed production Lawn can be collected and dried into hay or made into feed. However, because plant wastes and weed contain tannin, which may cause animals’ resist. Besides, the green wastes are of lower protein content and lack in vitamins, so the bioavailability is poor and 88 thus should not be used as the feed directly. 4 Garden Waste to Produce Ethanol Technology Because of the intensification of the global energy crisis, many countries are devoted to the development and utilization of renewable energy. Biomass energy gets people's special attention for its cleanliness and extensive usage. Bran, straw, chaff, weeds and industrial waste, sawdust and other celluloses has not been fully utilized except that a small amount of them are made for paper. According to foreign statistics, the total output accounts for approximately 50% of biological resources and adds up to100 ~ 50 billion t a year. The fermentation process of weed to produce fuel is shown in Figure 1. Garden wastes e.g. weed Sulfuric acid Ammonia Cooking and steaming SQY-1 Ethanol H2O SQY-2 Filtration Filtrated waste Filtrate Liquid-state fermentation Distillation Cellulose enzyme Waste liquid SSF rectification Yeast Solid state Waste distillation residue SCP Ethanol Figure 1 Fermentation process to produce fuel ethanol 4.1 Cooking and steaming As shown in Figure 1, mix the weed and 1% of sulfuric acid by a certain rate(solid to liquid is 1:10) at 121 ℃ for 120min, then filtrate and wash it by hot water, which weighs 4 times of that of garden waste .As the filtrate contains some sulfuric acid, the filtrate was re-pumped back to the cooking pot, and the waste into the solid-state fermentation pot (control the residual acidity is about pH4.8). In continuous operation, when the system starts, add 1% of sulfuric acid. Once the operating system running continuously, we can control the acidity by adding a small amount of concentrated sulfuric acid through the cooking process. 4.2 Fermentation and distillation When the concentration of reducing sugar in the filtrate reaches 5%, put some filtrate into the cooking pot, and others into the fermenting tank , and then cool it with ammonia or the neutralization of ammonium bicarbonate and sulfuric acid in the pot. As the reducing sugar in the hydrolysis fluid during the pretreatment of corn by dilute acid is mainly xylose, put activated SQY-1 which can ferment pentose to produce alcohol in the fermentation tank and start the fermentation at a stirring speed of 80r/min for 48h. When fermentation is completed, put the fermented liquid into the distillation of crude distillation tower, and we will get alcohol at the concentration of about 50% (v / v). 4.3 Fermentation and distillation in solid state 89 Solid-state fermentation (Solid-state fermentation, referred to as SSF) refers to the transformation process of the biological raw materials without free water by micro-organisms. The traditional submerged fermentation (Submerged fermentation) is to use the diluents or suspension of raw materials for fermentation. In the SSF process, there is usually a thin layer of water on the surface of the solid matrix and the weight ratio of water and solid substrate is between 4:1and 6:1 on average. Compared with submerged fermentation, the advantages of SSF are: less volume of the fermentation vessel; less energy costs of sterilization; more easily ventilated in solid substrate; less capital spending or operating expenses in wastewater treatment; less costs in the products collection and feed drying; less risk of bacterial contamination for it is less conducive to bacteria’s growth; in Add the solid residue(weighed as 25IFPU / g dry matter) into cellulase, and activated high-temperature yeast SQY-2 as well, then start the solid-state static fermentation after an even mixing. Take CO 2 out during the process to control the temperature, the amount of oxygen dissolved and the heat loss. After 60 hours’ fermentation and the process of solid-state distillation, we can obtain 50% (v / v) alcohol. 4.4 Rectification Rectify the alcohol distilled from SSF and the distillated liquid to obtain 95% (v / v) alcohol, and the alcohol obtained can be used as fuel to solve the current energy crisis. 4.5 SCP production As the liquid waste contains large amounts of distilled NH4 +, you can use it to produce feedings SCP. Mix the liquid residue distillery waste with the solid ones, access yeast to produce SCP, which can not only solve the environmental pollution problems, but also realize the comprehensive utilization of agricultural waste. 5 Conclusion Garden waste recycling is an effective approach to achieve scientific development in landscape greening and zero emissions in garden waste, which is consistent with the sustainable development. Using such a new technology as Garden waste to produce ethanol can achieve the unity of ecological, social and economic benefits .As a result we should spread it in the process of new energy development , in order to better deal with the problems in the recycling of garden waste and promote the exploration of new energy and development of low carbon economy. References [1]. Sun Kejun and Lin Honghui, Garden Organic Waste Application Prospect of Synthetic Culture Medium, 2007. 90-94 pages.(In Chinese) [2]. Chen Xiang, Xian Xudong, Baobing, Garden Organic Waste of Resources and Problems of Utilization. China Horticulture Digest, 2009. 25 (9): 173-174,112 Page. (In Chinese) [3]. Lv Ziwen, Fang Hailan and Huang Caidi, The Disposal of Garden Waste in the United States and Its Revelation to China. Chinese Garden, 2007. 23 (8): 90-94 pages. (In Chinese) [4]. Yang Hui, Garden Waste and Utilization of Resources. Anhui Agricultural Science Bulletin, 2010.16 (15): 181-182 pages. (In Chinese) [5]. Liang Jing, Lv Ziwen and Fang Hailan, Garden Green Waste Composting of Foreign Status and The Way Out. Chinese Garden, 2009.25 (4): 1-6 pages. (In Chinese) [6]. Yu Xin, etc. Survey on Beijing Landscaping and Reuse of Waste Countermeasures. Shandong Forestry Science and Technology, 2009.39 (4): 5-7, 11 Page. (In Chinese) [7]. Pengfei and Li Lei, New Energy to Lead New economy - The Fourth China New Energy International Energy Forum and the First China Expo held in Beijing. Solar, 2010. (2): 52-53 . (In Chinese) [8]. Cheng Siwei, The Adoption of New Low-carbon Energy to Llead the Industrial Revolution in Economic and Ecological Civilization - In the Development of Cross-strait Seminar on the New Energy Industry's "New Energy and Low-carbon Economy," Keynote Speech. China Petroleum and Chemical Industry, 2010. (6): 20-24. (In Chinese) [9]. Kang Shuyun, Development of New energy, to Meet the New Energy Industrial Revolution - 2009 First Asian Energy Forum Symposium. China Coal, 2009. 35 (9): 128. (In Chinese) [10]. Dong Youfu and Hou Fang’an, The Idea of Straw Stalk Development Cycle, Shandong Province Technical Conference on Mechanization of Conservation Tillage in 2007: Shandong Taian. 130-132 pages. (In Chinese) [11]. Liu Jianfu and Bai Yurui, Fully Aware of The Value for Stalk of Straw. Henan Agriculture, 2009. (4): 27-31 pages. (In Chinese) [12]. LiTao, etc., The dangers of Straw Burning and The Comprehensive Utilization of Straw. Science and Technology Information, 2008. "" (20): 35, 37 pages. (In Chinese) [13]. Zhang Zhenhan, Vigorously Develop the Straw Utilization of Technology, Promote of Rural Development of Circular Economy 90 - - The Stalk of Straw for Power Generation System BoardTechnology. Agricultural Market, 2006. (7): 26-27 pages. (In Chinese) [14]. Xie Zuqi and Liu Jianhui, The Development of Straw Gasification Technology is An Effective Way of Energy Utilization. Modern Agricultural Machinery, 2007. (9): 11-13 pages. 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