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05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 79 Name ___________________________ 9 Date ___________________ Class __________________ CHEMICAL NAMES AND FORMULAS SECTION 9.1 NAMING IONS (pages 253–258) This section explains the use of the periodic table to determine the charge of an ion. It also defines polyatomic ion and gives the names and formulas for the most common polyatomic ions. Monatomic Ions (pages 253–256) 1. What are monatomic ions? Monatomic ions are ions consisting of only one atom. 2. How is the ionic charge of a Group 1A, 2A, or 3A ion determined? The ionic charge is numerically equal to the group number. 3. How is the ionic charge of a Group 5A, 6A, or 7A ion determined? The charge of an ion in Groups 5A, 6A, or 7A is determined by subtracting 8 from the group number. 4. Circle the letter of the type of element that often has more than one common ionic charge. © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. a. alkali metal b. alkaline earth metal c. transition metal d. nonmetal Stock system 5. The ______________________ of naming transition metal cations uses a Roman numeral in parentheses to indicate the numeric value of the ionic charge. 6. An older naming system uses the suffix -ous to name the cation with the lesser ______________________ charge, and the suffix -ic to name the cation with the greater ______________________ charge. 7. What is a major advantage of the Stock system over the old naming system? The Stock system gives the actual charge of the ion. Chapter 9 Chemical Names and Formulas 79 05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 80 Name ___________________________ Date ___________________ Class __________________ CHAPTER 9, Chemical Names and Formulas (continued) 8. Use the periodic table to write the name and formula (including charge) for each ion in the table below. Element Name Formula Fluorine fluoride ion F– Calcium calcium ion Ca2+ Oxygen oxide ion O2– Polyatomic Ions (pages 257–258) 9. What is a polyatomic ion? A polyatomic ion is a tightly bound group of atoms that behaves as a unit and carries a charge. 10. Is the following sentence true or false? The names of polyatomic anions always false end in -ide. ______________________ 11. What is the difference between the anions sulfite and sulfate? The sulfite ion has one less oxygen atom than the sulfate ion. 12. Look at Table 9.3 on page 257. Circle the letter of a polyatomic ion that is a cation. b. acetate c. oxalate d. phosphate 13. How many atoms make up the oxalate ion and what is its charge? It is made up of 6 atoms (2 carbon atoms and 4 oxygen atoms) and it has a charge of 2. 14. What three hydrogen-containing polyatomic anions are essential components of living systems? hydrogen carbonate ion a. ____________________________________________ hydrogen phosphate ion b. ____________________________________________ dihydrogen phosphate ion c. ____________________________________________ 80 Guided Reading and Study Workbook © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. a. ammonium 05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 81 Name ___________________________ Date ___________________ Class __________________ 15. Look at Figure 9.5 on page 257. Identify each of the ions shown below. 3 N 1 ammonium ion a. __________________ 1 P N phosphate ion b. ______________________ nitrate ion c. ______________________ SECTION 9.2 NAMING AND WRITING FORMULAS FOR IONIC COMPOUNDS (pages 260–266) This section explains the rules for naming and writing formulas for binary ionic compounds and compounds containing a polyatomic ion. Binary Ionic Compounds (pages 260–263) property 1. Traditionally, common names were based on some ______________________ of source a compound or its ______________________ . 2. What is the general name for compounds composed of two elements? They are binary compounds. __________________________________________________ 3. When writing the formula for any ionic compound, the charges of the ions balance must ______________________ . © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. 4. What are two methods for writing a balanced formula? finding the least common multiple of the charges a. ____________________________________________________________________ using the crisscross method b. ____________________________________________________________________ 5. What are the formulas for the compounds formed by the following pairs of ions? FeCl2 a. Fe2, Cl ______________________ Cr2O3 b. Cr3, O2 ______________________ Na2S c. Na, S2 ______________________ 6. What are the formulas for these compounds? LiBr a. lithium bromide ______________________ Cu3N2 b. cupric nitride ______________________ MgCl2 c. magnesium chloride ______________________ 7. The name of a binary ionic compound is written with the name of the cation anion ______________________ first followed by the name of the ______________________ . Chapter 9 Chemical Names and Formulas 81 05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 82 Name ___________________________ Date ___________________ Class __________________ CHAPTER 9, Chemical Names and Formulas (continued) 8. How can you tell that cobalt(II) iodide is a binary ionic compound formed by a transition metal with more than one ionic charge? The name includes a Roman numeral representing the ionic charge of the transition metal cation. 9. Write the names for these binary ionic compounds. a. PbS lead(II) sulfide __________________________________ magnesium chloride b. MgCl2 __________________________________ aluminum selenide c. Al2Se3 __________________________________ Compounds with Polyatomic Ions (pages 264–266) 10. What is a polyatomic ion? A polyatomic ion contains more than one element. 11. How do you write the formula for a compound containing a polyatomic ion? Write the symbol for the cation followed by the formula for the polyatomic ion and balance the charges. 12. Why are parentheses used to write the formula Al(OH)3? 13. Complete the table for these ionic compounds containing polyatomic ions. Cation Anion Name Formula NH4+ S2 ammonium sulfide (NH4)2S Fe3+ CO32– iron(III) carbonate Fe2(CO3)3 Ag+ NO3 K+ CN– 82 Guided Reading and Study Workbook silver nitrate potassium cyanide AgNO3 KCN © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. The parentheses indicate how many polyatomic ions are needed in the formula. 05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 83 Name ___________________________ Date ___________________ Class __________________ SECTION 9.3 NAMING AND WRITING FORMULAS FOR MOLECULAR COMPOUNDS (pages 268–270) This section explains the rules for naming and writing formulas for binary molecular compounds. Naming Binary Molecular Compounds (pages 268–269) 1. Circle the letter of the type(s) of elements that form binary molecular compounds. a. two nonmetallic elements b. a metal and a nonmetal c. two metals 2. Is the following sentence true or false? Two nonmetallic elements can combine false in only one way. ______________________ 3. What method is used to distinguish between different molecular compounds Prefixes are used. that contain the same elements? _________________________________________ © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. Match the prefix with the number it indicates. c _______ 4. octa- a. 4 a _______ 5. tetra- b. 7 b _______ 6. hepta- c. 8 d _______ 7. nona- d. 9 8. What are the names of the following compounds? boron trifluoride a. BF3 ____________________________________________ dinitrogen tetroxide b. N2O4 ____________________________________________ tetraphosphorus heptasulfide c. P4S7 ____________________________________________ Writing Formulas for Binary Molecular Compounds (page 270) 9. What are the formulas for the following compounds? CBr4 a. carbon tetrabromide ______________________ NI3 b. nitrogen triiodide ______________________ ICl c. iodine monochloride ______________________ I4O9 d. tetraiodine nonaoxide ______________________ Chapter 9 Chemical Names and Formulas 83 05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 84 Name ___________________________ Date ___________________ Class __________________ CHAPTER 9, Chemical Names and Formulas (continued) Reading Skill Practice Writing a summary can help you remember the information you have read. When you write a summary, include only the most important points. Write a summary of the information in Section 9.3 on pages 268–269. Your summary should be shorter than the text on which it is based. Do your work on a separate sheet of paper. Students’ summaries should focus on the main points of each subsection and include the information given in Table 9.4. SECTION 9.4 NAMING AND WRITING FORMULAS FOR ACIDS AND BASES (pages 271–273) This section explains the three rules for naming acids and shows how these rules can also be used to write the formulas for acids. Names and formulas for bases are also explained. Naming Common Acids (pages 271–272) hydrogen 1. Acids produce ______________________ ions when dissolved in water. 2. When naming acids, you can consider them to be combinations of anions hydrogen ______________________ connected to as many ______________________ ions as are necessary to create an electrically neutral compound. 4. What are the components of phosphorous acid? What is its formula? hydrogen ion and phosphite ion; H3PO3 Writing Formulas for Acids (page 272) 5. Use Table 9.5 on page 272 to help you complete the table about acids. Acid Name Formula Anion Name acetic acid HC2H3O2 acetate carbonic acid H2CO3 carbonate hydrochloric acid HCl chloride nitric acid HNO3 nitrate phosphoric acid H3PO4 phosphate sulfuric acid H2SO4 sulfate 84 Guided Reading and Study Workbook © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. HBr 3. What is the formula for hydrobromic acid? ______________________ 05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 85 Name ___________________________ Date ___________________ Class __________________ Names and Formulas for Bases (page 273) hydroxide ions 6. A base is a compound that produces ______________________ when dissolved in water. 7. How are bases named? Name the cation first followed by the anion (hydroxide ion). SECTION 9.5 THE LAWS GOVERNING FORMULAS AND NAMES (pages 274–279) This section uses data to demonstrate that a compound obeys the law of definite proportions. It also explains how to use flow charts to write the name and formula of a compound. The Laws of Definite and Multiple Proportions (pages 274–275) 1. What is the law of definite proportions? In different samples of the same chemical compound, the masses of the elements are always present in the same proportions. 2. Circle the whole-number mass ratio of Li to Cl in LiCl. The atomic mass of Li is 6.9; the atomic mass of Cl is 35.5. © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. a. 42 : 1 b. 5 : 1 c. 1 : 5 3. Circle the whole-number mass ratio of carbon to hydrogen in C2H4. The atomic mass of C is 12.0; the atomic mass of H is 1.0. a. 1 : 6 c. 1 : 12 b. 6 : 1 d. 12 : 1 4. In the compound sulfur dioxide, a food preservative, the mass ratio of sulfur to oxygen is 1 : 1. An 80-g sample of a compound composed of sulfur and oxygen contains 48 g of oxygen. Is the sample sulfur dioxide? Explain. No; If the sample contains 48 g of oxygen, it contains 32 g of sulfur. The ratio 32 : 48 is equivalent to 2 : 3, not 1 : 1. 5. What is the law of multiple proportions? When two elements form more than one compound, the different masses of one element that combine with the same mass of the other element are in a ratio of small whole numbers. Chapter 9 Chemical Names and Formulas 85 05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 86 Name ___________________________ Date ___________________ Class __________________ CHAPTER 9, Chemical Names and Formulas (continued) 6. Complete the table using the law of multiple proportions. Mass of Cu Mass of Cl Mass Ratio Cl : Cu Whole-number Ratio of Cl Compound A 8.3 g 4.6 g 0.55 1 Compound B 3.3 g 3.6 g 1.1 2 Practicing Skills: Naming Chemical Compounds (pages 276–277) 7. How can a flowchart help you to name chemical compounds? It gives step-by-step directions for naming a compound. 8. Use the flowchart in Figure 9.20 on page 277 to write the names of the following compounds: a. CsCl cesium chloride ___________________________________ b. SnSe2 tin(IV) selenide ___________________________________ ammonium hydroxide c. NH4OH ___________________________________ d. HF hydrofluoric acid ___________________________________ e. Si3N4 trisilicon tetranitride ___________________________________ zero a. In an ionic compound, the net ionic charge is ______________________ . binary b. An -ide ending generally indicates a ______________________ compound. polyatomic c. An -ite or -ate ending means there is a ______________________ ion that includes oxygen in the formula. Prefixes d. ______________________ in a name generally indicate that the compound is molecular and show the number of each kind of atom in the molecule. Roman numeral e. A ______________________ after the name of a cation shows the ionic charge of the cation. 86 Guided Reading and Study Workbook © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. 9. Complete the following five rules for writing a chemical formula from a chemical name. 05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 87 Name ___________________________ Date ___________________ Class __________________ Practicing Skills: Writing Chemical Formulas (page 278) 10. Fill in the missing labels from Figure 9.22 on page 278. Name of Compound Contains prefixes? Molecular compound yes Uses prefixes to write formula. no Ionic compound Identify symbols Group A elements Roman numerals Polyatomic ions Use Table 9.1 for charges. Give charges for cations. Use Table 9.3 for charges. © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. Balance charges Use crisscross method. Add parentheses for any multiple polyatomic ions. 11. Use the flowchart in Figure 9.22 to write the formulas of the following compounds: K2SiO3 a. potassium silicate ______________________ PCl5 b. phosphorus pentachloride ______________________ MnCrO4 c. manganese(II) chromate ______________________ LiH d. lithium hydride ______________________ I 2O5 e. diiodine pentoxide ______________________ Chapter 9 Chemical Names and Formulas 87 05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 88 Name ___________________________ Date ___________________ Class __________________ CHAPTER 9, Chemical Names and Formulas (continued) GUIDED PRACTICE PROBLEMS GUIDED PRACTICE PROBLEM 2 (page 256) 2. How many electrons were lost or gained to form these ions? a. Fe3 b. O2 c. Cu Step 1. Determine the number of electrons based on the size of the charge. Step 2. Determine whether the electrons were lost or gained based on the sign of the charge. Fe3 lost 3 electrons. a. ________________________________________________ O 2 gained 2 electrons. b. ________________________________________________ Cu lost 1 electron. c. ________________________________________________ GUIDED PRACTICE PROBLEMS 10B AND 10C (page 263) 10. Write formulas for compounds formed from these pairs of ions. b. Li+ , O2– Analyze Step 1. Do the ions combine in a 1:1 ratio? No, the charges on the ions are not equal. Step 2. Use the crisscross method to balance the formula. Li20 Write the formula. ___________ Li Evaluate Step 3. How do you know your formula is reasonable? The positive and negative charges are equal. 88 Guided Reading and Study Workbook 2 O 2 1 © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. Solve 05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 89 Name ___________________________ Date ___________________ Class __________________ c. Ca2 , N3 Analyze Step 1. Will the calcium (Ca2+) and nitride (N3–) ions combine in a 1 : 1 ratio? How do you know? No, because then the total charge would be negative, instead of neutral. Solve Step 2. Use the crisscross method to balance the formula. Ca Ca3 N2 Write the formula. ___________ 2 N 3 3 2 Evaluate Step 3. How do you know this formula is reasonable? The positive and negative charges are equal. GUIDED PRACTICE PROBLEM 13B (page 265) © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. 13b. Write the formula for chromium(III) nitrate. • Is the compound ionic or molecular? Explain. It is ionic because it has no prefixes and it contains a metal. • Use Table 9.3 on page 257 to write the formula for NO3– the nitrate ion. ________ • Use the crisscross method to balance the formula. Cr(NO3)3 • Write the formula. ____________________________ Cr 3 1 (NO3) 3 Chapter 9 Chemical Names and Formulas 89 05_Chem_GRSW_Ch09.SE/TE 6/11/04 3:33 PM Page 90 Name ___________________________ Date ___________________ Class __________________ CHAPTER 9, Chemical Names and Formulas (continued) GUIDED PRACTICE PROBLEM 34 (page 275) 34. Lead forms two compounds with oxygen. One compound contains 2.98 g of lead and 0.461 g of oxygen. The other contains 9.89 g of lead and 0.763 g of oxygen. For a given mass of oxygen, what is the lowest whole-number mass ratio of lead in the two compounds? Complete the following steps to solve the problem. First compound Step 1. Write the ratio of lead to oxygen for each compound. 2.98 g lead 0.461 g oxygen Step 2. Divide the numerator by the denominator in each ratio. 6.46 g lead Second compound 9.89 g lead g oxygen 0.763 13.0 g lead g oxygen g oxygen Step 3. Write a ratio comparing the first compound to the second. 6.46 Step 4. Simplify. Note that this ratio has no units. 0.497 roughly 1 g lead/g oxygen 13.0 g lead/g oxygen 1 2 90 Guided Reading and Study Workbook © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. 1 : 2 ___ . The mass ratio of lead per gram of oxygen in the two compounds is ___________ 05_CTR_ch09 7/9/04 3:29 PM Page 221 Name ___________________________ 9 Date ___________________ Class __________________ CHEMICAL NAMES AND FORMULAS Practice Problems In your notebook, solve the following problems. SECTION 9.1 NAMING IONS 1. What is the charge on the ion typically formed by each element? a. oxygen c. sodium e. nickel, 2 electrons lost b. iodine d. aluminum f. magnesium 2. How many electrons does the neutral atom gain or lose when each ion forms? a. Cr3 c. Li e. Cl b. P3 d. Ca2 f. O2 3. Name each ion. Identify each as a cation or an anion. a. Sn2 c. Br e. H b. Co3 d. K f. Mn2 © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. 4. Write the formula (including charge) for each ion. Use Table 9.3 if necessary. a. carbonate ion c. sulfate ion e. chromate ion b. nitrite ion d. hydroxide ion f. ammonium ion 5. Name the following ions. Identify each as a cation or an anion. a. CN c. PO43 e. Ca2 b. HCO3 d. Cl f. SO32 SECTION 9.2 NAMING AND WRITING FORMULAS FOR IONIC COMPOUNDS 1. Write the formulas for these binary ionic compounds. a. magnesium oxide c. potassium iodide e. sodium sulfide b. tin(II) fluoride d. aluminum chloride f. ferric bromide 2. Write the formulas for the compounds formed from these pairs of ions. a. Ba2, Cl c. Ca2, S2 e. Al3, O2 b. Ag, I d. K, Br f. Fe2, O2 3. Name the following binary ionic compounds. a. MnO2 c. CaCl2 e. NiCl2 g. CuCl2 b. Li3N d. SrBr2 f. K2S h. SnCl4 Chapter 9 Chemical Names and Formulas 221 05_CTR_ch09 7/9/04 3:29 PM Page 222 Name ___________________________ Date ___________________ Class __________________ 4. Write formulas for the following ionic compounds. a. sodium phosphate c. sodium hydroxide e. ammonium chloride b. magnesium sulfate d. potassium cyanide f. potassium dichromate 5. Write formulas for compounds formed from these pairs of ions. a. NH4, SO42 c. barium ion and hydroxide ion b. K, NO3 d. lithium ion and carbonate ion 6. Name the following compounds. a. NaCN c. Na2SO4 e. Cu(OH)2 b. FeCl3 d. K2CO3 f. LiNO3 7. Name and give the charge of the metal cation in each of the following ionic compounds. a. Na3PO4 c. CaS e. FeCl3 b. NiCl2 d. K2S f. CuI SECTION 9.3 NAMING AND WRITING FORMULAS FOR MOLECULAR COMPOUNDS 1. Name the following molecular compounds. a. PCl5 c. NO2 e. P4O6 g. SiO2 b. CCl4 d. N2F2 f. XeF2 h. Cl2O7 2. Write the formulas for the following binary molecular compounds. c. sulfur dioxide b. dichlorine monoxide d. dinitrogen tetrafluoride SECTION 9.4 NAMING AND WRITING FORMULAS FOR ACIDS AND BASES 1. Name the following compounds as acids. a. HNO2 b. H2SO4 c. HF d. H2CO3 2. Write the formulas for the following bases. a. calcium hydroxide c. aluminum hydroxide b. ammonium hydroxide d. lithium hydroxide SECTION 9.5 THE LAWS GOVERNING FORMULAS AND NAMES 1. Write the formulas for these compounds. 222 a. potassium sulfide e. hydrobromic acid i. sulfur hexafluoride b. tin(IV) chloride f. aluminum fluoride j. magnesium chloride c. hydrosulfuric acid g. dinitrogen pentoxide k. phosphoric acid d. calcium oxide h. iron(III) carbonate l. nitric acid Core Teaching Resources © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. a. nitrogen tribromide 05_CTR_ch09 7/9/04 3:29 PM Page 223 Name ___________________________ Date ___________________ Class __________________ 2. Complete this table by writing correct formulas for the compounds formed by combining positive and negative ions. SO42 NO3 OH PO43 Ca2 Al3 Na Pb4 3. Name the following compounds. a. K3PO4 c. NaHSO4 e. N2O5 g. PI3 b. Al(OH)3 d. HgO f. NBr3 h. (NH4)2SO4 © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. 4. Explain the difference between the law of definite proportions and the law of multiple proportions. Chapter 9 Chemical Names and Formulas 223 05_CTR_ch09 7/9/04 3:29 PM Page 211 Name ___________________________ 9.1 Date ___________________ Class __________________ NAMING IONS Section Review Objectives • Determine the charges of monatomic ions by using the periodic table and write the names of the ions • Define a polyatomic ion and write the names and formulas of the most common polyatomic ions • Identify the two common endings for the names of most polyatomic ions. Vocabulary • monatomic ions • polyatomic ions Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. 1 © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. Ions that consist of a single atom are called Metallic elements tend to 3 2 ions. 1. electrons. Group 1A ions have a 4 charge, whereas Group 2A metals form ions with a charge, and Group 3A metals form ions with a 5 charge. The charge of a Group A nonmetal ion is determined by subtracting 6 8 Many of the 10 . 9 system naming system. Ions containing more than one atom are called or 13 . 6. 8. 9. 10. 11 The names of most common polyatomic ions end in either 12 4. 7. have more than one common ionic charge. These ions are named using either the or the 7 3. 5. from the group number. For example, the Group 7A elements form ions with a charge of 2. ions. 11. 12. 13. Chapter 9 Chemical Names and Formulas 211 05_CTR_ch09 7/9/04 3:29 PM Page 212 Name ___________________________ Date ___________________ Class __________________ Part B True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. ________ 14. The names of polyatomic ions end in -ite or -ate. ________ 15. In polyatomic ions for which there is an -ite/-ate pair, the -ite ending will always indicate one less oxygen atom than the -ate ending. ________ 16. Polyatomic ions are anions. ________ 17. The charge on Group A metal ions is determined by subtracting the group number from 8. ________ 18. The Group 6A ions have a charge of 2. Part C Matching Match each description in Column B to the correct term in Column A. Column A Column B a. negatively charged ions ________ 20. polyatomic ions b. ions formed from single atoms ________ 21. cations c. a traditional way of naming transition metal cations ________ 22. anions d. positively charged ions ________ 23. classical naming system e. ions formed from groups of atoms Part D Questions and Problems Answer the following in the space provided. 24. What is the charge on a typical ion for each of the following groups? a. 1A c. 7A b. 6A d. 2A 25. Write the name of each of the following polyatomic ions. a. HCO3 c. MnO4 b. NH4 d. OH 26. How many electrons does the neutral atom gain or lose to form each of the following ions? 212 a. Ca2 c. I b. S2 d. Mn3 Core Teaching Resources © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. ________ 19. monatomic ions 05_CTR_ch09 7/9/04 3:29 PM Page 213 Name ___________________________ Date ___________________ Class __________________ NAMING AND WRITING FORMULAS FOR IONIC COMPOUNDS 9.2 Section Review Objectives • Apply the rules for naming and writing formulas for binary ionic compounds • Apply the rules for naming and writing formulas for compounds with polyatomic ions Vocabulary • binary compound Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. Binary ionic compounds are named by writing the name of © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. the 1 followed by the name of the binary compounds end in 3 2 1. . Names of 4 . For example, NaI is 2. . 5 When a cation has more than one ionic charge, a 4. is used in the name. 5. Compounds with polyatomic ions whose names end in -ite or -ate contain a polyatomic 6 that includes 7 . In writing the formula of an ionic compound, the net ionic charge must be 8 3. 6. 7. 8. . Part B True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. ________ 9. The systematic name for baking soda (NaHCO3) is sodium bicarbonate. ________ 10. In writing a formula for an ionic compound, the net ionic charge of the formula must be zero. Chapter 9 Chemical Names and Formulas 213 05_CTR_ch09 7/9/04 3:29 PM Page 214 Name ___________________________ Date ___________________ Class __________________ ________ 11. Anions that contain oxygen end in -ite or -ate. ________ 12. The cation name is placed first when naming ionic compounds. Part C Matching Match each description in Column B to the correct term in Column A. Column A Column B ________ 13. binary compounds a. ions that consist of a single atom ________ 14. monatomic ions b. ionic compounds composed of two elements ________ 15. polyatomic ions c. Group B metals, many of which have more than one common ionic charge ________ 16. transition metals d. ions that consist of more than one atom Part D Questions and Problems Answer the following in the space provided. 17. Name the following compounds and tell what type of compound they are (binary ionic or ionic with a polyatomic ion). a. FeBr3 b. KOH 18. Write the formulas for the following compounds. a. sodium chlorate b. lead(II) phosphate c. magnesium hydrogen carbonate 214 Core Teaching Resources © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. c. Na2Cr2O7 05_CTR_ch09 7/9/04 3:29 PM Page 215 Name ___________________________ 9.3 Date ___________________ Class __________________ NAMING AND WRITING FORMULAS FOR MOLECULAR COMPOUNDS Section Review Objectives • Interpret the prefixes in the names of molecular compounds in terms of their chemical formulas • Apply the rules for naming and writing formulas for binary molecular compounds Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. 1 Binary molecular compounds are composed of two 2 elements. The name of this type of compound ends in Prefixes are used to show how many 3 of each element © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. are present in a molecule of the compound. For example, the name of As2S5 is 4 1. . 2. 3. 4. . Part B True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. ________ 5. Binary molecular compounds contain carbon. ________ 6. Charges must be balanced when writing formulas for molecular compounds. ________ 7. CO2 is named monocarbon dioxide. Chapter 9 Chemical Names and Formulas 215 05_CTR_ch09 7/9/04 3:29 PM Page 216 Name ___________________________ Date ___________________ Class __________________ Part C Matching Match each description in Column B to the correct term in Column A. Column A Column B ________ 8. binary molecular compound a. used to indicate the relative number of atoms of an element in a molecular compound ________ 9. prefix b. prefix indicating one atom of an element in a molecule ________ 10. mono- c. prefix indicating four atoms of an element in a molecule ________ 11. tetra- d. nonionic compound containing atoms of two elements Part D Questions and Problems Answer the following in the space provided. 12. Name each of the following compounds. a. PCl5 b. SO2 c. P4S10 13. Write formulas for the following compounds. a. carbon tetrabromide 216 Core Teaching Resources © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. b. dinitrogen tetroxide 05_CTR_ch09 7/9/04 3:29 PM Page 217 Name ___________________________ 9.4 Date ___________________ Class __________________ NAMING AND WRITING FORMULAS FOR ACIDS AND BASES Section Review Objectives • Apply three rules for naming acids • Apply the rules in reverse to write formulas of acids • Apply the rules for naming bases Vocabulary • acid • base Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. 1 © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. An acid is a compound that contains one or more 2 atoms and produces 1. when dissolved in water. There 2. are rules for naming acids. For example, HBr is called 3 acid, whereas HNO3 is called A base is a(n) 5 4 3. acid. 4. 6 compound that produces when dissolved in water. Ionic compounds that are bases are named in the same way as other of the 8 7 compounds, that is, the name is followed by the name of the 9 . 5. 6. 7. 8. 9. Part B True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. ________ 10. A compound that contains hydrogen atoms will be an acid when dissolved in water. Chapter 9 Chemical Names and Formulas 217 05_CTR_ch09 7/9/04 3:29 PM Page 218 Name ___________________________ Date ___________________ Class __________________ ________ 11. An acid contains one or more hydroxide ions. ________ 12. Chemists have a special system for naming bases. Part C Matching Match each description in Column B to the correct term in Column A. Column A Column B ________ 13. acid a. a compound containing hydrogen that ionizes to yield hydrogen ions in solution ________ 14. base b. a solution in which the solvent is water ________ 15. aqueous solution c. a compound that produces hydroxide ions in water Part D Questions and Problems Answer the following in the space provided. 16. Write the formula for each acid or base. a. magnesium hydroxide b. hydrofluoric acid d. lithium hydroxide 17. Name each acid or base. a. KOH b. HI c. H2SO4 218 Core Teaching Resources © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. c. phosphoric acid 05_CTR_ch09 7/9/04 3:29 PM Page 219 Name ___________________________ 9.5 Date ___________________ Class __________________ THE LAWS GOVERNING FORMULAS AND NAMES Section Review Objectives • Define the laws of definite proportions and multiple proportions • Apply the rules for writing chemical formulas by using a flowchart • Apply the rules for naming chemical compounds by using a flowchart Vocabulary • law of definite proportions • law of multiple proportions Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. [Use Figure 9.20 to complete this exercise.] © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. The law of 1 states that in samples of any chemical 1. compound, the masses of the elements are always in the same 2. 2 3 . The law of states that whenever the same two 3. elements form more than one compound, the different masses 4. of one element that combine with the same mass of the other 5. 4 6. element are in the ratio of H3PO4 is a(n) CCl4 is not a(n) 5 numbers. 6 . It is called 7 . 7. . It contains two elements, so it is a 8. 8 compound. It does not contain a metal, so it is a binary 9. 9 compound. The compound is called Pb(C2H3O2)2 is not a(n) 12 11 . 10. . It contains more than two . C2H3O2 is a polyatomic metal. The compound is called 10 13 15 . . Pb is a Group 14 11. 12. 13. 14. 15. Chapter 9 Chemical Names and Formulas 219 05_CTR_ch09 7/9/04 3:29 PM Page 220 Name ___________________________ Date ___________________ Class __________________ Part B True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. ________ 16. Roman numerals are used when naming Group B metal cations. ________ 17. Names of compounds containing polyatomic anions end in -ide. ________ 18. Prefixes are used when naming binary ionic compounds. ________ 19. Compounds containing two elements are called binary compounds. Part C Questions and Problems Answer the following in the space provided. 20. Name the following compounds. a. Pb(C2H3O2)4 b. HF c. P2O5 d. LiBr 21. Write formulas for the following compounds. a. phosphorus pentachloride b. iron(II) oxide d. potassium chloride e. calcium nitrate 220 Core Teaching Resources © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. c. nitric acid 05_CTR_ch09 7/9/04 3:29 PM Page 224 Name ___________________________ 9 Date ___________________ Class __________________ INTERPRETING GRAPHICS Use with Section 9.1 Group 1A 8A 1 2 H He Hydrogen 3 Helium 2A 3A 4A 5A 6A 7A 4 5 6 7 8 9 10 Li Be B C N O F Ne Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon 11 12 13 14 15 16 17 18 Na Mg Al Si P S Cl Ar Sodium Magnesium Aluminum Silicon Phosphorus Sulfur Hydrogen Argon 19 20 K Ca Potassium Calcium Use the abbreviated periodic table above to answer the following questions. 1. Which group on the periodic table contains magnesium (Mg)? 2. How many electrons does a magnesium atom lose to form a magnesium cation? 4. How many electrons does a magnesium cation contain? 5. Which group on the periodic table contains fluorine (F)? 6. How many electrons does a fluorine atom gain to form a fluoride anion? 7. How many electrons does a neutral fluorine atom contain? 224 Core Teaching Resources © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. 3. How many electrons does a neutral magnesium atom contain? 05_CTR_ch09 7/9/04 3:29 PM Page 225 Name ___________________________ Date ___________________ Class __________________ 8. How many electrons does a fluoride anion contain? 9. How many electrons does a sodium cation contain? 10. How many electrons does an oxide anion contain? 11. How many electrons does each of the following ions contain? a. S2 b. Ca2 c. K © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. d. Cl Chapter 9 Chemical Names and Formulas 225 05_CTR_ch09 7/9/04 3:29 PM Page 226 Name ___________________________ 9 Date ___________________ Class __________________ CHEMICAL NAMES AND FORMULAS Vocabulary Review Match the correct vocabulary term to each numbered statement. Write the letter of the correct term on the line. Column A Column B a. anion ________ 2. an ionic compound that produces hydroxide ions when dissolved in water b. law of multiple proportions ________ 3. any atom or group of atoms that has a positive charge c. base ________ 4. compounds composed of metal cations and nonmetal anions d. ionic compounds ________ 5. composed of two elements and can be either ionic or molecular e. binary compound ________ 6. an ion consisting of a single atom with a positive or negative charge f. monatomic ion ________ 7. Whenever two elements form more than one compound, the different masses of one element that combine with the same mass of the other element are in the ratio of small whole numbers. g. cation ________ 8. a tightly bound group of atoms that behaves as a unit and carries a charge h. polyatomic ion ________ 9. In samples of any chemical compound, the masses of the elements are always in the same proportions. i. acids ________ 10. any atom or group of atoms that has a negative charge j. law of definite proportions 226 Core Teaching Resources © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. ________ 1. compounds that contain one or more hydrogen atoms and produce hydrogen ions in solution 05_CTR_ch09 7/9/04 3:29 PM Page 227 Name ___________________________ 9 Date ___________________ Class __________________ CHEMICAL NAMES AND FORMULAS Chapter Quiz Fill in the word(s) that will make each statement true. 1. 9.1 2. 9.3 3 3. A(n) is any atom or group of atoms with a negative charge. 3. 9.1 4 4. The law of states that in any chemical compound, the elements are always combined in the same proportion by mass. 4. 9.5 5. The charge on an ion of a Group A nonmetal is determined 5 by subtracting 8 from . 5. 9.1 6. 9.1 7. 9.1 8. 9.1 9. 9.3 10. What is the formula for iron(II) chloride? 10. 9.2 11. Name the compound whose formula is SnS2. 11. 9.2 12. Name the compound N2O5. 12. 9.3 13. Name the compound NaHCO3. 13. 9.2 14. Write the formula for copper(II) hydroxide. 14. 9.2 15. Name the compound HNO3 as an acid. 15. 9.4 1. 1 tend to lose electrons when they react to form compounds. 2 2. The formula for phosphorus pentachloride is 6. The metals in Groups 1A, 2A, and 3A when they form ions. 6 . electrons © Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. 7. The two common polyatomic ions whose names end in -ide 7 are the cyanide ion and the ion. 8 8. The formula for the dihydrogen phosphate ion is 9. The systematic name for laughing gas (N2O) is 9 . . Write your answer in the space provided. Chapter 9 Chemical Names and Formulas 227