February 25, 2015 Katie Erny Montana Department of Environmental Quality

February 25, 2015
Katie Erny
Montana Department of Environmental Quality
Petroleum Technical Section
P.O. Box 200901
Helena, Montana 59620-0901
RE:
Groundwater Monitoring Report
Former Stimson Lumber Millsite, Bonner, Montana
Facility ID #32-04262, Release #4161
Dear Ms. Erny,
Please find enclosed a groundwater monitoring report summarizing monitoring well sampling activities
completed at the former Stimson Lumber Millsite facility in Bonner, Montana. Please call me at (406)
549-8270 to discuss the results presented in this report.
Sincerely,
Tyler Etzel
Senior Geologist
cc:
Steven Petrin, Stimson Lumber Company
Keith Large, DEQ
Jim Carlson, Missoula County Sanitarian
www.NewFields.com
1120 Cedar Street, Missoula, Montana 59802-3911
T. 406.549-8270
F. 406.549.8277
Groundwater Monitoring Report
Former Stimson Lumber Bonner Millsite
Bonner, Montana 59702
Facility ID #33-00047, Release #235
Prepared for:
Steven Petrin
Stimson Lumber Company
520 SW Yamhill, Suite 700
Portland, OR 97204-1330
Prepared by:
NewFields
1120 Cedar Street
Missoula, Montana 59802
February 2015
Project No. 350.0033.002
Groundwater Monitoring Report  Former Stimson Lumber Bonner Millsite  February 2015
TABLE OF CONTENTS
1.0
ACTIVITY SUMMARY ...............................................................................................................1
2.0
SOIL LABORATORY ANALYTICAL REPORTS ................................................................................1
3.0
CONCLUSIONS AND RECOMMENDATIONS ...............................................................................1
4.0
REFERENCES ...........................................................................................................................3
LIST OF FIGURES
Figure 1
Figure 2
Figure 3
Location Map
Groundwater Potentiometric Map
TEH and Aroclor 1254 concentrations
LIST OF TABLES
Table 1 Groundwater Elevations – December 2014 .................................................................................... 2
Table 2 Groundwater Analytical Results in parts per billion (µg/L) – December 2014 ............................... 2
LIST OF APPENDICES
Appendix A
Appendix B
Appendix C
Photographs
Groundwater Sampling and Field Activity Forms
Analytical Laboratory Report
Page | i
Groundwater Monitoring Report  Former Stimson Lumber Bonner Millsite  February 2015
1.0 AC TIVITY SUMMARY
This work has been performed to comply with requirements of an April 19, 2010 administrative order on
consent (AOC) issued by the Montana Department of Environmental Quality (DEQ) and a request from
the DEQ Petroleum Technical Section (PTS) in telephone and email correspondence dated October 1,
2012. The AOC required, in part, groundwater sampling at high and low groundwater elevations, with
sampling continuing until two consecutive rounds demonstrate that groundwater meets DEQ-7
standards for PCBs and meets Tier I RBSLs for petroleum hydrocarbons.
Groundwater Monitoring
On December 22 and 23, 2014, static water levels (SWLs) and groundwater samples were collected from
the following nine (9) monitoring wells: MW-10, MW-14, MW-15R, MW-18, MW-19, MW-20 and MW21. Monitoring well MW-11 was measured for light non-aqueous phase liquid (LNAPL) with a bailer to
determine if groundwater sample collection was feasible for this well. The bailer displayed a thin
(approximately 1/8 inch) layer of free product and was not sampled (Appendix A).
Prior to monitoring well sampling, depth to groundwater was measured with a groundwater interface
probe. Groundwater samples were collected with a variable rate, low-flow submersible pump. Sample
collection was performed when pH readings stabilized to within 0.1 and temperature and conductivity
stabilized to within 5% over three casing volumes. Groundwater chemistry was recorded on NewFields
groundwater sampling forms. The water samples were collected and preserved with appropriate acid
preservative. The samples were submitted under appropriate custody and seals to Energy Laboratory in
Billings, Montana for extractable petroleum hydrocarbon screen (EPH-Screen) and polychlorinated
biphenyls (PCBs – EPA Method 8082). Results of the water analyses are discussed in Section 3.0, below.
Copies of groundwater sampling forms and field activity forms are included as Appendix B.
2.0 SOIL LABORATORY ANALY TICAL RE PORTS
The laboratory analytical report for groundwater monitoring is included as Appendix C.
3.0 C ONC LU SIONS AND RECOM ME NDATIONS
In December 2014, NewFields completed groundwater monitoring of nine (9) monitoring wells at the
Former Stimson Lumber Millsite in Bonner, Montana. An additional monitoring well (MW-11) was
measured for LNAPL to determine if groundwater sample collection was feasible for this well.
Static water level measurements were collected from monitoring wells on December 22 and 23, 2014.
SWL measurements, casing elevations, and groundwater elevations for the ten (10) monitoring wells are
given below in Table 1.
Page | 1
Groundwater Monitoring Report  Former Stimson Lumber Bonner Millsite  February 2015
Table 1 Groundwater Elevations – December 2014
Monitoring Well
MW-10
MW-11
MW-13R
MW-14
MW-15R
MW-18
MW-19
MW-20
MW-21
MW-22
Notes:
Casing Elevation
(ft amsl)
Depth to Water (ft)
3285.46
3278.55
3279.55
3281.61
3287.12
3284.29
3292.22
3292.15
3293.32
3280.11
LNAPL Thickness
GW Elevation
(ft)
(ft amsl)
0.0
< 0.01
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
3244.12
Nm
3244.51
3244.14
3244.06
3244.04
3244.04
3243.92
3243.96
3244.09
41.34
nm
35.04
37.47
43.06
40.25
48.18
48.23
49.36
36.02
nm indicates no measurement was collected
Groundwater potentiometric contours calculated from depth to water measurements in monitoring
wells (MW-10, MW-13R, MW-14, MW-15R, MW-18, MW-19, MW-20, MW-21 and MW-22) generally
showed a southerly groundwater flow direction, although some well measurements did not create
model contours and these areas show estimated contours (Figure 2). LNAPL was present in MW-11 and
was measured to be less than 0.01 feet thick using a disposable bailer. Photographs of the bailer
containing free product are included as Appendix A. Analytical results for groundwater samples
collected from all nine monitoring wells are shown in Table 2, below and in Appendix C.
Table 2 Groundwater Analytical Results in parts per billion (µg/L) – December 2014
Analysis
Regulatory
Standard
EPH
Tier 1 RBSL¹
TEH
C9-C18
Aliphatics
C19-C36
Aliphatics
C11-C22
Aromatics
MW-10
MW-13R
MW-14
MW-15R
MW-18
MW-19
MW-20
MW-21
MW-22
1,0002
<300
<300
<300
<300
<300
<300
<300
<300
<300
1,000
----
----
----
----
----
----
----
----
----
1,000
----
----
----
----
----
----
----
----
----
1,000
----
----
----
----
----
----
----
----
----
PCBs
WQB-73
Aroclor 1016
0.5
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
Aroclor 1221
0.5
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
Aroclor 1232
0.5
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
Aroclor 1232
0.5
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
Aroclor 1242
0.5
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
Aroclor 1248
0.5
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
Aroclor 1254
0.5
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
Aroclor 1260
0.5
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
Aroclor 1262
0.5
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
Aroclor 1268
0.5
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
Notes:
1
Table 3 Tier 1 Groundwater Risk-Based Screening Levels, September 2009
the indicated value is a DEQ RBCA ceiling concentration
3
Circular WQB-7, Montana Water Quality Standards, January 2004
< indicates the parameter was not detected above the laboratory reporting limit
---- indicates parameter not analyzed
2
Page | 2
Groundwater Monitoring Report  Former Stimson Lumber Bonner Millsite  February 2015
Laboratory results from the December 2014 groundwater sampling event did not detect measurable
levels of total extractable hydrocarbons (TEH) or Aroclor PCBs in all nine (9) groundwater monitoring
wells sampled. None of the samples collected from any of the nine (9) wells sampled exceeded DEQ Tier
1 RBSL or WQB-7 standards for groundwater.
These results represent the second consecutive round (one at seasonally high groundwater and one at
seasonally low groundwater) in which groundwater meets DEQ-7 and Tier 1 RBSL standards. The next
groundwater monitoring event is scheduled for June 2015.
4.0 RE FE RE NCE S
PBS&J, 2009. Sampling and Analysis Plan for the Cooling Pond, Fire Pond Lagoon and East Log Track
Area - Stimson Lumber Mill, Bonner, Montana. December 2009.
Page | 3
FIGURES
Site
14N 18W
M O N T A N A
I 90
200
MISSOULA
P:\350.0033 Stimson Cleanup\05 GIS\Projects\FIGURE 1 - Location Map.mxd
SITE
0
93
I 90
Sources: Esri, DeLorme, NAVTEQ, TomTom, Intermap, increment P
Corp., GEBCO, USGS, FAO, NPS, NRCAN, GeoBase, IGN, Kadaster
NL, Ordnance Survey, Esri Japan, METI, Esri China (Hong Kong), and
the GIS User Community
Feet
10,000
Location Map
Former Stimson Bonner Millsite
Bonner, Montana
FIGURE 1
BL
AC
K
T
FOO
RIVE
R
4.4
324
MW-11
MW-13R
3244.51
4
324
.3
4
324
@
A
MW-14
3244.14
@
A
MW-10
3244.12
.2
MW-18 3244.1
3244.04
@
A
@
A
@
A
MW-22
3244.09
@
A
MW-15R FORMER
3244.06 STUD MILL
@ LOCATION
A
.9
3243
FIRE WELL
@
A
P:\350.0033 Stimson Cleanup\05 GIS\Projects\GW_Report\FIGURE 2 - PotMapDec2014.mxd
FORMER
BOILER
LOCATION
MW-20
3243.92
MW-19
3244.04
@
A
@
A
REPOSITORY
MW-21
3243.96
@
A
Source: Google Imagery, 2013
O
0
44
32
Feet
Groundwater Flow
Direction
100
@
A
Monitoring Well Location
Potentiometric Contour (feet)
Estimated Potentiometric Contour (feet)
MW-13 Area Excavation
MW-15 Area Excavation
Groundwater Potentiometric Map
December 2014
Former Stimson Bonner Millsite
Bonner, Montana
FIGURE 2
BL
AC
KF
OOT
RIVE
R
MW-11
MW-13R
ND
ND
@
A
@
A
MW-10
ND
ND
MW-18
ND
ND
MW-14
ND
ND
@
A
@
A
@
A
MW-22
ND
ND
@
A
MW-15R
ND
FORMER
ND STUD MILL
@ LOCATION
A
FIRE WELL
P:\350.0033 Stimson Cleanup\05 GIS\Projects\GW_Report\FIGURE 3 - TEH_AroclorDec2014.mxd
FORMER
BOILER
LOCATION
MW-20
ND
ND
@
A
MW-19
ND
ND
@
A
REPOSITORY
MW-21
ND
ND
@
A
Source: Google Imagery, 2013
O
0
@
A
Feet
@
A
100
NOTE:
ND - Not Detected at
the Reporting Limit
Monitoring Well Locationw
TEH and Aroclor 1254 Concentrations
December 2014
MW-15 Area Excavation
Former Stimson Bonner Millsite
Bonner, Montana
ND - TEH Concentration (ug/L)
FIGURE 3
ND - Aroclor 1254 Concentration (ug/L)
MW-13 Area Excavation
APPENDIX A
Photographs
Groundwater Monitoring Report  Former Stimson Lumber Bonner Millsite  February 2015
Photo 1. View of upright bailer with MW-11 contents
Photo 2. Close-up view of LNAPL sheen on water surface and on surface of bailer
Appendix A |A- 1
Groundwater Monitoring Report  Former Stimson Lumber Bonner Millsite  February 2015
Photo 3. Close-up top view of LNAPL sheen on water surface on surface of bailer
Photo 4. View of LNAPL sheen on outside of bailer
Appendix A |A- 2
APPENDIX B
Groundwater Sampling Forms and
Field Activity Forms
APPENDIX C
Analytical Laboratory Report
ANALYTICAL SUMMARY REPORT
January 28, 2015
NewFields
1120 Cedar St
Missoula, MT 59802-3911
Work Order:
B14122169
Project Name:
Stimson
Energy Laboratories Inc Billings MT received the following 9 samples for NewFields on 12/30/2014 for analysis.
Lab ID
Client Sample ID
Collect Date Receive Date
Matrix
Test
B14122169-001
MW-10
12/22/14 15:40 12/30/14
Aqueous
EPH-Liquid-Liquid Extraction
Hydrocarbons, Extractable
Petroleum Screen
Polychlorinated Biphenyls (PCB's)
Separatory Funnel Liquid Liquid Ext.
B14122169-002
MW-13R
12/22/14 12:10 12/30/14
Aqueous
Same As Above
B14122169-003
MW-14
12/22/14 13:10 12/30/14
Aqueous
Same As Above
B14122169-004
MW-15R
12/22/14 16:45 12/30/14
Aqueous
Same As Above
B14122169-005
MW-18
12/22/14 15:00 12/30/14
Aqueous
Same As Above
B14122169-006
MW-19
12/23/14 12:30 12/30/14
Aqueous
Same As Above
B14122169-007
MW-20
12/23/14 11:40 12/30/14
Aqueous
Same As Above
B14122169-008
MW-21
12/23/14 10:50 12/30/14
Aqueous
Same As Above
B14122169-009
MW-22
12/22/14 14:05 12/30/14
Aqueous
Same As Above
The analyses presented in this report were performed by Energy Laboratories, Inc., 1120 S 27th St., Billings, MT
59101, unless otherwise noted. Any exceptions or problems with the analyses are noted in the Laboratory
Analytical Report, the QA/QC Summary Report, or the Case Narrative.
The results as reported relate only to the item(s) submitted for testing.
If you have any questions regarding these test results, please call.
Report Approved By:
Page 1 of 25
CLIENT:
NewFields
Project:
Stimson
B14122169
Work Order:
Revised Date: 01/28/15
Report Date: 01/08/15
CASE NARRATIVE
Revised Report:
The report was revised per client request to correct reporting limits.
This revised report replaces any previous report in its entirety.
Page 2 of 25
LABORATORY ANALYTICAL REPORT
Prepared by Billings, MT Branch
Client:
Project:
Lab ID:
Client Sample ID:
Revised Date:
Report Date:
Collection Date:
DateReceived:
Matrix:
NewFields
Stimson
B14122169-001
MW-10
Analyses
Result Units
Qualifiers
RL
MCL/
QCL Method
01/28/15
01/08/15
12/22/14 15:40
12/30/14
Aqueous
Analysis Date / By
EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN
Total Extractable Hydrocarbons
Surr: o-Terphenyl
ND ug/L
92.0 %REC
300
40-140
1000
SW8015M
SW8015M
01/03/15 22:27 / tmc
01/03/15 22:27 / tmc
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
12/31/14 21:33 / jem
12/31/14 21:33 / jem
12/31/14 21:33 / jem
12/31/14 21:33 / jem
12/31/14 21:33 / jem
12/31/14 21:33 / jem
12/31/14 21:33 / jem
12/31/14 21:33 / jem
12/31/14 21:33 / jem
12/31/14 21:33 / jem
12/31/14 21:33 / jem
- Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time.
POLYCHLORINATED BIPHENYLS (PCBS)
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Aroclor 1262
Aroclor 1268
Surr: Decachlorobiphenyl
Surr: Tetrachloro-m-xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
95.0
73.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%REC
%REC
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
44-119
40-120
- The extraction prep hold time was exceeded by 0.757 days.
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Report
Definitions:
RL - Analyte reporting limit.
MCL - Maximum contaminant level.
QCL - Quality control limit.
ND - Not detected at the reporting limit.
Page 3 of 25
LABORATORY ANALYTICAL REPORT
Prepared by Billings, MT Branch
Client:
Project:
Lab ID:
Client Sample ID:
Revised Date:
Report Date:
Collection Date:
DateReceived:
Matrix:
NewFields
Stimson
B14122169-002
MW-13R
Analyses
Result Units
Qualifiers
RL
MCL/
QCL Method
01/28/15
01/08/15
12/22/14 12:10
12/30/14
Aqueous
Analysis Date / By
EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN
Total Extractable Hydrocarbons
Surr: o-Terphenyl
ND ug/L
85.0 %REC
300
40-140
1000
SW8015M
SW8015M
01/03/15 23:10 / tmc
01/03/15 23:10 / tmc
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
12/31/14 21:59 / jem
12/31/14 21:59 / jem
12/31/14 21:59 / jem
12/31/14 21:59 / jem
12/31/14 21:59 / jem
12/31/14 21:59 / jem
12/31/14 21:59 / jem
12/31/14 21:59 / jem
12/31/14 21:59 / jem
12/31/14 21:59 / jem
12/31/14 21:59 / jem
- Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time.
POLYCHLORINATED BIPHENYLS (PCBS)
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Aroclor 1262
Aroclor 1268
Surr: Decachlorobiphenyl
Surr: Tetrachloro-m-xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
103
67.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%REC
%REC
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
44-119
40-120
- The extraction prep hold time was exceeded by 0.903 days.
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Report
Definitions:
RL - Analyte reporting limit.
MCL - Maximum contaminant level.
QCL - Quality control limit.
ND - Not detected at the reporting limit.
Page 4 of 25
LABORATORY ANALYTICAL REPORT
Prepared by Billings, MT Branch
Client:
Project:
Lab ID:
Client Sample ID:
Revised Date:
Report Date:
Collection Date:
DateReceived:
Matrix:
NewFields
Stimson
B14122169-003
MW-14
Analyses
Result Units
Qualifiers
RL
MCL/
QCL Method
01/28/15
01/08/15
12/22/14 13:10
12/30/14
Aqueous
Analysis Date / By
EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN
Total Extractable Hydrocarbons
Surr: o-Terphenyl
ND ug/L
90.0 %REC
300
40-140
1000
SW8015M
SW8015M
01/04/15 00:37 / tmc
01/04/15 00:37 / tmc
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
12/31/14 22:25 / jem
12/31/14 22:25 / jem
12/31/14 22:25 / jem
12/31/14 22:25 / jem
12/31/14 22:25 / jem
12/31/14 22:25 / jem
12/31/14 22:25 / jem
12/31/14 22:25 / jem
12/31/14 22:25 / jem
12/31/14 22:25 / jem
12/31/14 22:25 / jem
- Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time.
POLYCHLORINATED BIPHENYLS (PCBS)
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Aroclor 1262
Aroclor 1268
Surr: Decachlorobiphenyl
Surr: Tetrachloro-m-xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
92.0
77.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%REC
%REC
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
44-119
40-120
- The extraction prep hold time was exceeded by 0.861 days.
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Report
Definitions:
RL - Analyte reporting limit.
MCL - Maximum contaminant level.
QCL - Quality control limit.
ND - Not detected at the reporting limit.
Page 5 of 25
LABORATORY ANALYTICAL REPORT
Prepared by Billings, MT Branch
Client:
Project:
Lab ID:
Client Sample ID:
Revised Date:
Report Date:
Collection Date:
DateReceived:
Matrix:
NewFields
Stimson
B14122169-004
MW-15R
Analyses
Result Units
Qualifiers
RL
MCL/
QCL Method
01/28/15
01/08/15
12/22/14 16:45
12/30/14
Aqueous
Analysis Date / By
EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN
Total Extractable Hydrocarbons
Surr: o-Terphenyl
ND ug/L
73.0 %REC
300
40-140
1000
SW8015M
SW8015M
01/04/15 01:20 / tmc
01/04/15 01:20 / tmc
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
12/31/14 22:51 / jem
12/31/14 22:51 / jem
12/31/14 22:51 / jem
12/31/14 22:51 / jem
12/31/14 22:51 / jem
12/31/14 22:51 / jem
12/31/14 22:51 / jem
12/31/14 22:51 / jem
12/31/14 22:51 / jem
12/31/14 22:51 / jem
12/31/14 22:51 / jem
- Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time.
POLYCHLORINATED BIPHENYLS (PCBS)
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Aroclor 1262
Aroclor 1268
Surr: Decachlorobiphenyl
Surr: Tetrachloro-m-xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
104
76.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%REC
%REC
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
44-119
40-120
- The extraction prep hold time was exceeded by 0.712 days.
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Report
Definitions:
RL - Analyte reporting limit.
MCL - Maximum contaminant level.
QCL - Quality control limit.
ND - Not detected at the reporting limit.
Page 6 of 25
LABORATORY ANALYTICAL REPORT
Prepared by Billings, MT Branch
Client:
Project:
Lab ID:
Client Sample ID:
Revised Date:
Report Date:
Collection Date:
DateReceived:
Matrix:
NewFields
Stimson
B14122169-005
MW-18
Analyses
Result Units
Qualifiers
RL
MCL/
QCL Method
01/28/15
01/08/15
12/22/14 15:00
12/30/14
Aqueous
Analysis Date / By
EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN
Total Extractable Hydrocarbons
Surr: o-Terphenyl
ND ug/L
93.0 %REC
300
40-140
1000
SW8015M
SW8015M
01/04/15 02:04 / tmc
01/04/15 02:04 / tmc
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
12/31/14 23:17 / jem
12/31/14 23:17 / jem
12/31/14 23:17 / jem
12/31/14 23:17 / jem
12/31/14 23:17 / jem
12/31/14 23:17 / jem
12/31/14 23:17 / jem
12/31/14 23:17 / jem
12/31/14 23:17 / jem
12/31/14 23:17 / jem
12/31/14 23:17 / jem
- Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time.
POLYCHLORINATED BIPHENYLS (PCBS)
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Aroclor 1262
Aroclor 1268
Surr: Decachlorobiphenyl
Surr: Tetrachloro-m-xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
103
78.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%REC
%REC
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
44-119
40-120
- The extraction prep hold time was exceeded by 0.785 days.
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Report
Definitions:
RL - Analyte reporting limit.
MCL - Maximum contaminant level.
QCL - Quality control limit.
ND - Not detected at the reporting limit.
Page 7 of 25
LABORATORY ANALYTICAL REPORT
Prepared by Billings, MT Branch
Client:
Project:
Lab ID:
Client Sample ID:
Revised Date:
Report Date:
Collection Date:
DateReceived:
Matrix:
NewFields
Stimson
B14122169-006
MW-19
Analyses
Result Units
Qualifiers
RL
MCL/
QCL Method
01/28/15
01/08/15
12/23/14 12:30
12/30/14
Aqueous
Analysis Date / By
EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN
Total Extractable Hydrocarbons
Surr: o-Terphenyl
ND ug/L
102 %REC
300
40-140
1000
SW8015M
SW8015M
01/04/15 04:14 / tmc
01/04/15 04:14 / tmc
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
12/31/14 23:44 / jem
12/31/14 23:44 / jem
12/31/14 23:44 / jem
12/31/14 23:44 / jem
12/31/14 23:44 / jem
12/31/14 23:44 / jem
12/31/14 23:44 / jem
12/31/14 23:44 / jem
12/31/14 23:44 / jem
12/31/14 23:44 / jem
12/31/14 23:44 / jem
- Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time.
POLYCHLORINATED BIPHENYLS (PCBS)
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Aroclor 1262
Aroclor 1268
Surr: Decachlorobiphenyl
Surr: Tetrachloro-m-xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
96.0
77.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%REC
%REC
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
44-119
40-120
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Report
Definitions:
RL - Analyte reporting limit.
MCL - Maximum contaminant level.
QCL - Quality control limit.
ND - Not detected at the reporting limit.
Page 8 of 25
LABORATORY ANALYTICAL REPORT
Prepared by Billings, MT Branch
Client:
Project:
Lab ID:
Client Sample ID:
Revised Date:
Report Date:
Collection Date:
DateReceived:
Matrix:
NewFields
Stimson
B14122169-007
MW-20
Analyses
Result Units
Qualifiers
RL
MCL/
QCL Method
01/28/15
01/08/15
12/23/14 11:40
12/30/14
Aqueous
Analysis Date / By
EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN
Total Extractable Hydrocarbons
Surr: o-Terphenyl
ND ug/L
103 %REC
300
40-140
1000
SW8015M
SW8015M
01/04/15 04:58 / tmc
01/04/15 04:58 / tmc
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
01/01/15 00:10 / jem
01/01/15 00:10 / jem
01/01/15 00:10 / jem
01/01/15 00:10 / jem
01/01/15 00:10 / jem
01/01/15 00:10 / jem
01/01/15 00:10 / jem
01/01/15 00:10 / jem
01/01/15 00:10 / jem
01/01/15 00:10 / jem
01/01/15 00:10 / jem
- Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time.
POLYCHLORINATED BIPHENYLS (PCBS)
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Aroclor 1262
Aroclor 1268
Surr: Decachlorobiphenyl
Surr: Tetrachloro-m-xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
104
77.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%REC
%REC
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
44-119
40-120
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Report
Definitions:
RL - Analyte reporting limit.
MCL - Maximum contaminant level.
QCL - Quality control limit.
ND - Not detected at the reporting limit.
Page 9 of 25
LABORATORY ANALYTICAL REPORT
Prepared by Billings, MT Branch
Client:
Project:
Lab ID:
Client Sample ID:
Revised Date:
Report Date:
Collection Date:
DateReceived:
Matrix:
NewFields
Stimson
B14122169-008
MW-21
Analyses
Result Units
Qualifiers
RL
MCL/
QCL Method
01/28/15
01/08/15
12/23/14 10:50
12/30/14
Aqueous
Analysis Date / By
EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN
Total Extractable Hydrocarbons
Surr: o-Terphenyl
ND ug/L
98.0 %REC
300
40-140
1000
SW8015M
SW8015M
01/04/15 05:41 / tmc
01/04/15 05:41 / tmc
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
01/01/15 01:03 / jem
01/01/15 01:03 / jem
01/01/15 01:03 / jem
01/01/15 01:03 / jem
01/01/15 01:03 / jem
01/01/15 01:03 / jem
01/01/15 01:03 / jem
01/01/15 01:03 / jem
01/01/15 01:03 / jem
01/01/15 01:03 / jem
01/01/15 01:03 / jem
- Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time.
POLYCHLORINATED BIPHENYLS (PCBS)
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Aroclor 1262
Aroclor 1268
Surr: Decachlorobiphenyl
Surr: Tetrachloro-m-xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
104
75.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%REC
%REC
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
44-119
40-120
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Report
Definitions:
RL - Analyte reporting limit.
MCL - Maximum contaminant level.
QCL - Quality control limit.
ND - Not detected at the reporting limit.
Page 10 of 25
LABORATORY ANALYTICAL REPORT
Prepared by Billings, MT Branch
Client:
Project:
Lab ID:
Client Sample ID:
Revised Date:
Report Date:
Collection Date:
DateReceived:
Matrix:
NewFields
Stimson
B14122169-009
MW-22
Analyses
Result Units
Qualifiers
RL
MCL/
QCL Method
01/28/15
01/08/15
12/22/14 14:05
12/30/14
Aqueous
Analysis Date / By
EXTRACTABLE PETROLEUM HYDROCARBONS-SCREEN
Total Extractable Hydrocarbons
Surr: o-Terphenyl
ND ug/L
103 %REC
300
40-140
1000
SW8015M
SW8015M
01/04/15 06:25 / tmc
01/04/15 06:25 / tmc
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
SW8082
01/01/15 00:36 / jem
01/01/15 00:36 / jem
01/01/15 00:36 / jem
01/01/15 00:36 / jem
01/01/15 00:36 / jem
01/01/15 00:36 / jem
01/01/15 00:36 / jem
01/01/15 00:36 / jem
01/01/15 00:36 / jem
01/01/15 00:36 / jem
01/01/15 00:36 / jem
- Note: Total Extractable Hydrocarbons are defined as the total hydrocarbon responses regardless of elution time.
POLYCHLORINATED BIPHENYLS (PCBS)
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Aroclor 1262
Aroclor 1268
Surr: Decachlorobiphenyl
Surr: Tetrachloro-m-xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
99.0
77.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%REC
%REC
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
44-119
40-120
- The extraction prep hold time was exceeded by 0.823 days.
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Report
Definitions:
RL - Analyte reporting limit.
MCL - Maximum contaminant level.
QCL - Quality control limit.
ND - Not detected at the reporting limit.
Page 11 of 25
QA/QC Summary Report
Prepared by Billings, MT Branch
Client:
NewFields
Report Date: 01/08/15
Project: Stimson
Result
Analyte
Method:
Work Order: B14122169
Units
RL %REC Low Limit High Limit
RPD RPDLimit
Batch: 85897
SW8015M
Lab ID:
LCS-85897
Total Extractable Hydrocarbons
Laboratory Control Sample
6560
ug/L
Run: GCFID-HP3-B_150102B
300
Surr: o-Terphenyl
Lab ID:
MB-85897
Total Extractable Hydrocarbons
Method Blank
ND
Surr: o-Terphenyl
60
140
96
40
140
94
Sample Matrix Spike
13300
ug/L
ug/L
01/03/15 18:06
40
140
Run: GCFID-HP3-B_150102B
600
107
60
140
74
40
140
Sample Matrix Spike Duplicate
13600
01/03/15 17:22
300
Surr: o-Terphenyl
Lab ID:
B14121909-001AMSD
Total Extractable Hydrocarbons
106
Run: GCFID-HP3-B_150102B
ug/L
Surr: o-Terphenyl
Lab ID:
B14121909-001AMS
Total Extractable Hydrocarbons
Qual
01/03/15 19:33
Run: GCFID-HP3-B_150102B
600
110
60
140
74
40
140
01/03/15 20:16
2.5
20
Qualifiers:
RL - Analyte reporting limit.
ND - Not detected at the reporting limit.
Page 12 of 25
QA/QC Summary Report
Prepared by Billings, MT Branch
Client:
NewFields
Report Date: 01/08/15
Project: Stimson
Result
Analyte
Method:
Lab ID:
n-Nonane
Work Order: B14122169
Units
RL %REC Low Limit High Limit
Continuing Calibration Verification Standard
01/03/15 15:55
208
ug/L
104
75
125
n-Decane
208
ug/L
104
75
125
n-Dodecane
214
ug/L
107
75
125
n-Tetradecane
n-Hexadecane
210
214
ug/L
ug/L
105
107
75
75
125
125
n-Octadecane
215
ug/L
107
75
125
n-Nonadecane
215
ug/L
108
75
125
n-Eicosane
215
ug/L
108
75
125
n-Docosane
215
ug/L
108
75
125
n-Tetracosane
216
ug/L
108
75
125
n-Hexacosane
n-Octacosane
216
216
ug/L
ug/L
108
108
75
75
125
125
n-Triacontane
217
ug/L
109
75
125
n-Hexatriacontane
216
ug/L
108
75
125
109
75
125
Surr: o-Terphenyl
Lab ID:
n-Nonane
n-Decane
CCV_0102HP348r-W
Continuing Calibration Verification Standard
01/04/15 02:47
211
204
ug/L
ug/L
106
102
75
75
125
125
n-Dodecane
213
ug/L
106
75
125
n-Tetradecane
208
ug/L
104
75
125
n-Hexadecane
213
ug/L
106
75
125
n-Octadecane
213
ug/L
106
75
125
n-Nonadecane
213
ug/L
107
75
125
n-Eicosane
n-Docosane
213
214
ug/L
ug/L
107
107
75
75
125
125
n-Tetracosane
214
ug/L
107
75
125
n-Hexacosane
214
ug/L
107
75
125
n-Octacosane
214
ug/L
107
75
125
n-Triacontane
215
ug/L
108
75
125
n-Hexatriacontane
214
ug/L
107
75
125
109
75
125
Surr: o-Terphenyl
Qual
Analytical Run: R236224
SW8015M
CCV_0102HP333r-W
RPD RPDLimit
Qualifiers:
RL - Analyte reporting limit.
ND - Not detected at the reporting limit.
Page 13 of 25
Batch ID: 85897
MW-10
1500
500
7.43
7.50
7.60
7.71
8.20 n-Dodecane
8.60
8.65
8.75
8.81
8.88
8.94
9.18
9.29
9.42
9.54 n-Tetradecane
9.93
10.02
10.14
10.54
10.65 n-Hexadecane
10.76
10.93
11.00
11.09
11.19
11.34
11.45
11.51
11.68
n-Octadecane
11.87
12.03
12.15 n-Nonadecane
12.43
12.51
12.64
12.81
12.86 n-Eicosane
13.36
13.45 n-Docosane
13.75
13.85
13.96
14.02
14.41
14.55 n-Tetracosane
14.84
15.06 n-Hexacosane
15.61
15.93
16.07 n-Octacosane
n-Triacontane
17.18
17.41
17.66
17.79
4.18
4.57
4.64
4.70
5.06
5.15
5.29
5.38
n-Nonane
5.47
5.56
5.68
5.79
5.89
5.99
6.10
6.29
6.40 n-Decane
6.55
6.61
6.69
1000
21.57
2000
19.91
2500
18.44
18.68
18.92 n-Hexatriacontane
19.20
12.28 *o-Terphenyl
B14122169-001B ;0102HP3 , $HC-EPH-SCRN-W, V42
13.12 *1-Chloro-octadecane
G:\org\HP3\DAT\HP3010215_b\0102HP3.0042.RAW
3000
0
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM
Sample Name: B14122169-001B ;0102HP3 ,
$HC-EPH-SCRN-W, V42
Raw File: G:\org\HP3\DAT\HP3010215_b\0102HP3.0042.RAW
Date & Time Acquired: 1/3/2015 10:27:12 PM
Method File: g:\org\HP3\Methods\SR_SCN-LI-L%.met
Calibration File: G:\Org\HP3\Cals\SC140226LI.CAL
Sample Weight: 1.05
Dilution: 2
S.A.: 1
Mean RF for C9 to C18 Hydrocarbons: 30979.57
Mean RF for C19 to C36 Hydrocarbons: 30994.75
Mean RF for Total Extractable Hydrocarbons: 30987.16
Rt range for Diesel Range Organics: 6.313 to 16.684
Rt range for C9 to C18 Hydrocarbons: 5.273 to 12.239
Rt range for C19 to C36 Hydrocarbons: 12.274 to 19.076
SURROGATE COMPOUND
RT
*o-Terphenyl_____________12.283
*1-Chloro-octadecane_____13.12
DRO Area:309742.5
TEH Area:484754
C9-C18 Area:273878
C19-C36 Area:164511
ACTUAL
190.476
190.476
MEASURED
174.946
160.982
%REC
91.85
84.52
-
DRO Amount: 19.03969
TEH Amount: 29.79754
C9-C18 Amount: 16.83924
C19-C36 Amount: 10.10992
Page 14 of 25
Batch ID: 85897
MW-13R
4.08
4.18
4.36
4.57
4.64
4.70
4.99
5.07
5.15
5.28
5.38
n-Nonane
5.47
5.56
5.69
5.79
5.90
6.00
6.10
6.40
n-Decane
6.54
6.69
7.24
7.65
7.71
8.06
n-Dodecane
8.11
8.18
8.33
8.64
8.75
8.87
8.94
9.04
9.18
9.27 n-Tetradecane
9.48
9.52
9.61
9.68
9.81
9.91
10.02
10.11
10.25
10.31
10.36
10.44
10.57
10.65
10.75 n-Hexadecane
10.86
10.92
11.00
11.08
11.18
11.27
11.32
11.37
11.42
11.50
11.67
11.75
n-Octadecane
11.87
11.94
12.02
12.14 n-Nonadecane
12.42
12.51
12.64
12.77 n-Eicosane
12.87
12.99
13.35
13.44 n-Docosane
13.55
13.74
13.82
13.88
13.96
14.02
14.17
14.22
14.33
14.40 n-Tetracosane
14.55
14.62
14.73
14.84
14.97
15.06 n-Hexacosane
15.22
15.51
15.61
15.92
16.07 n-Octacosane
n-Triacontane
17.18
17.41
17.65
1000
500
27.04
1500
22.31
2000
18.68
18.93 n-Hexatriacontane
19.20
12.28 *o-Terphenyl
2500
B14122169-002B ;0102HP3 , $HC-EPH-SCRN-W, V43
13.12 *1-Chloro-octadecane
G:\org\HP3\DAT\HP3010215_b\0102HP3.0043.RAW
3000
0
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM
Sample Name: B14122169-002B ;0102HP3 ,
$HC-EPH-SCRN-W, V43
Raw File: G:\org\HP3\DAT\HP3010215_b\0102HP3.0043.RAW
Date & Time Acquired: 1/3/2015 11:10:38 PM
Method File: g:\org\HP3\Methods\SR_SCN-LI-L%.met
Calibration File: G:\Org\HP3\Cals\SC140226LI.CAL
Sample Weight: 1.05
Dilution: 2
S.A.: 1
Mean RF for C9 to C18 Hydrocarbons: 30979.57
Mean RF for C19 to C36 Hydrocarbons: 30994.75
Mean RF for Total Extractable Hydrocarbons: 30987.16
Rt range for Diesel Range Organics: 6.313 to 16.684
Rt range for C9 to C18 Hydrocarbons: 5.273 to 12.239
Rt range for C19 to C36 Hydrocarbons: 12.274 to 19.076
SURROGATE COMPOUND
RT
*o-Terphenyl_____________12.282
*1-Chloro-octadecane_____13.119
DRO Area:653343.3
TEH Area:803575.3
C9-C18 Area:396754.9
C19-C36 Area:361046.8
ACTUAL
190.476
190.476
MEASURED
160.998
134.698
%REC
84.52
70.72
-
DRO Amount: 40.16061
TEH Amount: 49.39529
C9-C18 Amount: 24.39426
C19-C36 Amount: 22.18789
Page 15 of 25
Batch ID: 85897
MW-14
29.12
n-Dodecane
8.65
8.75
8.81
8.94
9.05
9.18
9.28
9.47
9.54 n-Tetradecane
9.93
10.02
10.14
10.25
10.30
10.41
10.54
10.65 n-Hexadecane
10.77
10.93
11.00
11.09
11.19
11.32
11.37
11.43
11.51 n-Octadecane
11.68
11.88
12.03
12.15 n-Nonadecane
12.43
12.51
12.64
12.82
12.86 n-Eicosane
13.36
13.45 n-Docosane
13.56
13.76
13.84
13.96
14.02
14.40 n-Tetracosane
14.85
15.06
15.22 n-Hexacosane
15.59
15.93
16.08 n-Octacosane
n-Triacontane
17.18
17.43
17.66
500
7.48
7.72
4.09
4.18
4.36
4.49
4.65
5.06
5.15
5.28
5.36
5.48
5.56 n-Nonane
5.68
5.78
5.90
6.00
6.10
6.30
6.40
n-Decane
6.54
6.70
1000
25.88
1500
22.29
2000
19.96
2500
18.43
18.92
n-Hexatriacontane
19.12
19.21
12.28 *o-Terphenyl
B14122169-003B ;0102HP3 , $HC-EPH-SCRN-W, V45
13.12 *1-Chloro-octadecane
G:\org\HP3\DAT\HP3010215_b\0102HP3.0045.RAW
3000
0
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM
Sample Name: B14122169-003B ;0102HP3 ,
$HC-EPH-SCRN-W, V45
Raw File: G:\org\HP3\DAT\HP3010215_b\0102HP3.0045.RAW
Date & Time Acquired: 1/4/2015 12:37:32 AM
Method File: g:\org\HP3\Methods\SR_SCN-LI-L%.met
Calibration File: G:\Org\HP3\Cals\SC140226LI.CAL
Sample Weight: 1.05
Dilution: 2
S.A.: 1
Mean RF for C9 to C18 Hydrocarbons: 30979.57
Mean RF for C19 to C36 Hydrocarbons: 30994.75
Mean RF for Total Extractable Hydrocarbons: 30987.16
Rt range for Diesel Range Organics: 6.313 to 16.684
Rt range for C9 to C18 Hydrocarbons: 5.273 to 12.239
Rt range for C19 to C36 Hydrocarbons: 12.274 to 19.076
SURROGATE COMPOUND
RT
*o-Terphenyl_____________12.283
*1-Chloro-octadecane_____13.12
DRO Area:321987.5
TEH Area:511540.5
C9-C18 Area:288657.1
C19-C36 Area:161476.5
ACTUAL
190.476
190.476
MEASURED
171.078
166.32
%REC
89.82
87.32
-
DRO Amount: 19.79238
TEH Amount: 31.44409
C9-C18 Amount: 17.74792
C19-C36 Amount: 9.923433
Page 16 of 25
Batch ID: 85897
MW-15R
G:\org\HP3\DAT\HP3010215_b\0102HP3.0046.RAW
3000
B14122169-004B ;0102HP3 , $HC-EPH-SCRN-W, V46
4.05
4.19
4.38
4.57
4.70
4.98
5.14
5.29
5.37
n-Nonane
5.48
5.56
5.68
5.79
5.90
6.01
6.10
6.40
n-Decane
6.56
6.60
6.71
1000
500
19.91
1500
18.42
18.66
18.91 n-Hexatriacontane
19.12
2000
7.41
7.72
8.23 n-Dodecane
8.60
8.65
8.74
8.89
8.94
9.18
9.29 n-Tetradecane
9.54
9.63
9.93
10.02
10.11
10.30
10.51
10.54
10.65 n-Hexadecane
10.93
11.01
11.10
11.19
11.34
11.43
11.51
11.68
11.78
n-Octadecane
11.86
11.94
12.04
12.15
12.22
n-Nonadecane
12.28 *o-Terphenyl
12.43
12.51
12.70
n-Eicosane
12.77
12.87
12.90
12.96
13.12 *1-Chloro-octadecane
13.35
13.44
13.55
13.65
n-Docosane
13.72
13.76
13.87
13.95
14.02
14.22
14.34
14.40
n-Tetracosane
14.55
14.74
14.83
15.06
15.22
15.34 n-Hexacosane
15.59
15.92
16.07 n-Octacosane
16.29
16.63 n-Triacontane
17.18
17.42
17.65
17.78
2500
0
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM
Sample Name: B14122169-004B ;0102HP3 ,
$HC-EPH-SCRN-W, V46
Raw File: G:\org\HP3\DAT\HP3010215_b\0102HP3.0046.RAW
Date & Time Acquired: 1/4/2015 1:20:55 AM
Method File: g:\org\HP3\Methods\SR_SCN-LI-L%.met
Calibration File: G:\Org\HP3\Cals\SC140226LI.CAL
Sample Weight: 1.05
Dilution: 2
S.A.: 1
Mean RF for C9 to C18 Hydrocarbons: 30979.57
Mean RF for C19 to C36 Hydrocarbons: 30994.75
Mean RF for Total Extractable Hydrocarbons: 30987.16
Rt range for Diesel Range Organics: 6.313 to 16.684
Rt range for C9 to C18 Hydrocarbons: 5.273 to 12.239
Rt range for C19 to C36 Hydrocarbons: 12.274 to 19.076
SURROGATE COMPOUND
RT
*o-Terphenyl_____________12.282
*1-Chloro-octadecane_____13.119
DRO Area:523518.3
TEH Area:651712.8
C9-C18 Area:204610.7
C19-C36 Area:405988.3
ACTUAL
190.476
190.476
MEASURED
139.249
84.638
%REC
73.11
44.44
-
DRO Amount: 32.18035
TEH Amount: 40.06039
C9-C18 Amount: 12.58038
C19-C36 Amount: 24.94975
Page 17 of 25
Batch ID: 85897
MW-18
25.98
n-Dodecane
8.65
8.75
8.83
8.88
8.94
9.18
9.33
9.43
n-Tetradecane
9.54
9.64
9.92
10.02
10.13
10.65 n-Hexadecane
10.93
11.00
11.10
11.19
11.35
11.43
11.51
11.71 n-Octadecane
11.87
12.03
12.15
12.22 n-Nonadecane
12.43
12.51 n-Eicosane
12.64
12.70
12.81
12.86
13.36
13.45 n-Docosane
13.55
13.77
13.85
13.96
14.02
14.18
14.40 n-Tetracosane
14.55
14.85
15.06 n-Hexacosane
15.22
15.62
15.93
16.08 n-Octacosane
n-Triacontane
17.18
17.41
17.66
17.79
500
7.43
7.71
4.57
4.64
4.70
5.06
5.14
5.29
5.37
5.48
5.56 n-Nonane
5.68
5.78
5.90
6.00
6.10
6.40
n-Decane
6.55
6.72
1000
22.27
1500
20.98
2000
19.93
2500
18.44
18.68
18.93
n-Hexatriacontane
19.12
19.21
12.28 *o-Terphenyl
B14122169-005B ;0102HP3 , $HC-EPH-SCRN-W, V47
13.12 *1-Chloro-octadecane
G:\org\HP3\DAT\HP3010215_b\0102HP3.0047.RAW
3000
0
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM
Sample Name: B14122169-005B ;0102HP3 ,
$HC-EPH-SCRN-W, V47
Raw File: G:\org\HP3\DAT\HP3010215_b\0102HP3.0047.RAW
Date & Time Acquired: 1/4/2015 2:04:18 AM
Method File: g:\org\HP3\Methods\SR_SCN-LI-L%.met
Calibration File: G:\Org\HP3\Cals\SC140226LI.CAL
Sample Weight: 1.05
Dilution: 2
S.A.: 1
Mean RF for C9 to C18 Hydrocarbons: 30979.57
Mean RF for C19 to C36 Hydrocarbons: 30994.75
Mean RF for Total Extractable Hydrocarbons: 30987.16
Rt range for Diesel Range Organics: 6.313 to 16.684
Rt range for C9 to C18 Hydrocarbons: 5.273 to 12.239
Rt range for C19 to C36 Hydrocarbons: 12.274 to 19.076
SURROGATE COMPOUND
RT
*o-Terphenyl_____________12.282
*1-Chloro-octadecane_____13.119
DRO Area:299294.8
TEH Area:479457.3
C9-C18 Area:243081.4
C19-C36 Area:178412.8
ACTUAL
190.476
190.476
MEASURED
176.694
165.492
%REC
92.76
86.88
-
DRO Amount: 18.39747
TEH Amount: 29.47195
C9-C18 Amount: 14.94572
C19-C36 Amount: 10.96424
Page 18 of 25
Batch ID: 85897
MW-19
12.28 *o-Terphenyl
B14122169-006B ;0102HP3 , $HC-EPH-SCRN-W, V50
2500
2000
13.12 *1-Chloro-octadecane
G:\org\HP3\DAT\HP3010215_b\0102HP3.0050.RAW
3000
19.95
13.37
13.46
13.56 n-Docosane
13.96
14.02
14.41
14.55 n-Tetracosane
14.85
15.07 n-Hexacosane
15.22
15.61
15.94
16.08 n-Octacosane
16.61 n-Triacontane
17.18
17.44
17.66
17.79
500
7.72
8.25 n-Dodecane
8.65
8.74
8.88
8.94
9.19
9.28
9.46
9.54 n-Tetradecane
9.85
9.92
10.02
10.13
10.65 n-Hexadecane
10.93
11.00
11.19
11.32
11.35
11.43
11.51
11.71
11.87 n-Octadecane
12.15
12.22 n-Nonadecane
12.52 n-Eicosane
12.64
12.70
12.86
4.18
4.63
4.70
5.14
5.29
5.37
n-Nonane
5.47
5.56
5.68
5.78
5.89
5.99
6.10
6.29
6.40 n-Decane
6.54
6.61
6.69
1000
18.67
18.93 n-Hexatriacontane
19.21
1500
0
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM
Sample Name: B14122169-006B ;0102HP3 ,
$HC-EPH-SCRN-W, V50
Raw File: G:\org\HP3\DAT\HP3010215_b\0102HP3.0050.RAW
Date & Time Acquired: 1/4/2015 4:14:38 AM
Method File: g:\org\HP3\Methods\SR_SCN-LI-L%.met
Calibration File: G:\Org\HP3\Cals\SC140226LI.CAL
Sample Weight: 1.05
Dilution: 2
S.A.: 1
Mean RF for C9 to C18 Hydrocarbons: 30979.57
Mean RF for C19 to C36 Hydrocarbons: 30994.75
Mean RF for Total Extractable Hydrocarbons: 30987.16
Rt range for Diesel Range Organics: 6.313 to 16.684
Rt range for C9 to C18 Hydrocarbons: 5.273 to 12.239
Rt range for C19 to C36 Hydrocarbons: 12.274 to 19.076
SURROGATE COMPOUND
RT
*o-Terphenyl_____________12.282
*1-Chloro-octadecane_____13.119
DRO Area:314328
TEH Area:480663.5
C9-C18 Area:299916.2
C19-C36 Area:143971
ACTUAL
190.476
190.476
MEASURED
193.617
203.18
%REC
101.65
106.67
-
DRO Amount: 19.32155
TEH Amount: 29.5461
C9-C18 Amount: 18.44018
C19-C36 Amount: 8.847644
Page 19 of 25
Batch ID: 85897
MW-20
12.28 *o-Terphenyl
B14122169-007B ;0102HP3 , $HC-EPH-SCRN-W, V51
2500
2000
13.12 *1-Chloro-octadecane
G:\org\HP3\DAT\HP3010215_b\0102HP3.0051.RAW
3000
19.92
n-Dodecane
8.56
8.60
8.65
8.74
8.88
8.94
9.18
9.28
9.46
9.54 n-Tetradecane
9.83
9.94
10.02
10.13
10.54
10.65 n-Hexadecane
10.93
11.00
11.10
11.19
11.32
11.35
11.51
11.68
11.88 n-Octadecane
12.15 n-Nonadecane
12.51
12.64
12.81
12.86 n-Eicosane
13.36
13.44 n-Docosane
13.96
14.02
14.41
14.55 n-Tetracosane
14.84
15.06 n-Hexacosane
15.22
15.62
15.93
16.07 n-Octacosane
16.62 n-Triacontane
17.18
17.41
17.66
17.79
500
7.49
7.63
7.71
7.85
4.12
4.18
4.35
4.45
4.51
4.59
4.65
4.70
5.14
5.28 n-Nonane
5.47
5.56
5.68
5.78
5.90
6.00
6.10
6.30
6.40 n-Decane
6.70
1000
18.43
18.68
18.92 n-Hexatriacontane
19.21
1500
0
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM
Sample Name: B14122169-007B ;0102HP3 ,
$HC-EPH-SCRN-W, V51
Raw File: G:\org\HP3\DAT\HP3010215_b\0102HP3.0051.RAW
Date & Time Acquired: 1/4/2015 4:58:08 AM
Method File: g:\org\HP3\Methods\SR_SCN-LI-L%.met
Calibration File: G:\Org\HP3\Cals\SC140226LI.CAL
Sample Weight: 1.05
Dilution: 2
S.A.: 1
Mean RF for C9 to C18 Hydrocarbons: 30979.57
Mean RF for C19 to C36 Hydrocarbons: 30994.75
Mean RF for Total Extractable Hydrocarbons: 30987.16
Rt range for Diesel Range Organics: 6.313 to 16.684
Rt range for C9 to C18 Hydrocarbons: 5.273 to 12.239
Rt range for C19 to C36 Hydrocarbons: 12.274 to 19.076
SURROGATE COMPOUND
RT
*o-Terphenyl_____________12.282
*1-Chloro-octadecane_____13.119
DRO Area:373817
TEH Area:570514
C9-C18 Area:292227.9
C19-C36 Area:207527
ACTUAL
190.476
190.476
MEASURED
197.113
208.607
%REC
103.48
109.52
-
DRO Amount: 22.97831
TEH Amount: 35.06915
C9-C18 Amount: 17.96747
C19-C36 Amount: 12.75344
Page 20 of 25
Batch ID: 85897
MW-21
2000
1500
n-Dodecane
8.65
8.75
8.89
8.94
9.19
9.35
9.47
9.54 n-Tetradecane
9.84
9.92
10.02
10.13
10.65 n-Hexadecane
10.93
11.00
11.19
11.34
11.51
11.71
11.88 n-Octadecane
12.15 n-Nonadecane
12.22
12.52 n-Eicosane
12.64
12.70
12.82
12.86
13.36
13.45 n-Docosane
13.95
14.02
14.40
14.45 n-Tetracosane
14.84
15.06 n-Hexacosane
15.22
15.58
15.79
15.93
16.07 n-Octacosane
16.16
16.61 n-Triacontane
17.18
17.42
17.66
17.79
500
7.42
7.61
7.72
4.36
4.57
4.64
4.70
5.00
5.05
5.08
5.14
5.29
5.37
n-Nonane
5.47
5.56
5.68
5.78
5.90
6.00
6.10
6.40 n-Decane
6.54
6.69
1000
19.91
2500
18.70
18.93 n-Hexatriacontane
19.21
12.28 *o-Terphenyl
B14122169-008B ;0102HP3 , $HC-EPH-SCRN-W, V52
13.12 *1-Chloro-octadecane
G:\org\HP3\DAT\HP3010215_b\0102HP3.0052.RAW
3000
0
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM
Sample Name: B14122169-008B ;0102HP3 ,
$HC-EPH-SCRN-W, V52
Raw File: G:\org\HP3\DAT\HP3010215_b\0102HP3.0052.RAW
Date & Time Acquired: 1/4/2015 5:41:37 AM
Method File: g:\org\HP3\Methods\SR_SCN-LI-L%.met
Calibration File: G:\Org\HP3\Cals\SC140226LI.CAL
Sample Weight: 1.05
Dilution: 2
S.A.: 1
Mean RF for C9 to C18 Hydrocarbons: 30979.57
Mean RF for C19 to C36 Hydrocarbons: 30994.75
Mean RF for Total Extractable Hydrocarbons: 30987.16
Rt range for Diesel Range Organics: 6.313 to 16.684
Rt range for C9 to C18 Hydrocarbons: 5.273 to 12.239
Rt range for C19 to C36 Hydrocarbons: 12.274 to 19.076
SURROGATE COMPOUND
RT
*o-Terphenyl_____________12.282
*1-Chloro-octadecane_____13.119
DRO Area:314462.5
TEH Area:487412
C9-C18 Area:292709.6
C19-C36 Area:148417
ACTUAL
190.476
190.476
MEASURED
187.199
192.461
%REC
98.28
101.04
-
DRO Amount: 19.32982
TEH Amount: 29.96092
C9-C18 Amount: 17.99709
C19-C36 Amount: 9.120871
Page 21 of 25
Batch ID: 85897
MW-22
12.28 *o-Terphenyl
B14122169-009B ;0102HP3 , $HC-EPH-SCRN-W, V53
2500
2000
13.12 *1-Chloro-octadecane
G:\org\HP3\DAT\HP3010215_b\0102HP3.0053.RAW
3000
22.27
500
19.94
20.47
20.99
4.11
4.18
4.35
4.51
4.57
4.65
5.06
5.14
5.29
5.34
5.38
n-Nonane
5.48
5.56
5.68
5.78
5.90
6.00
6.10
6.29
6.40 n-Decane
6.56
6.71
7.24
7.41
7.71
n-Dodecane
8.60
8.74
8.84
8.87
8.94
9.18
9.27
9.46
9.53
9.63 n-Tetradecane
9.93
10.02
10.11
10.24
10.37
10.42
10.49
10.54
10.59
10.65
n-Hexadecane
10.75
10.82
10.92
11.00
11.06
11.13
11.19
11.27
11.34
11.43
11.51
11.68
n-Octadecane
11.87
11.94
12.02
12.10
12.15 n-Nonadecane
12.42
12.51
12.64 n-Eicosane
12.69
12.76
12.86
12.98
13.35
13.44 n-Docosane
13.96
14.02
14.27
14.31
14.41
n-Tetracosane
14.55
14.59
14.63
14.67
14.73
14.84
14.98
15.06 n-Hexacosane
15.22
15.59
15.92
16.07 n-Octacosane
n-Triacontane
17.17
17.41
17.65
1000
18.42
18.68
18.92 n-Hexatriacontane
19.21
1500
0
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
EXTRACTABLE PETROLEUM HYDROCARBONS (EPH) SCREENING ANALYSIS CHROMATOGRAM
Sample Name: B14122169-009B ;0102HP3 ,
$HC-EPH-SCRN-W, V53
Raw File: G:\org\HP3\DAT\HP3010215_b\0102HP3.0053.RAW
Date & Time Acquired: 1/4/2015 6:25:00 AM
Method File: g:\org\HP3\Methods\SR_SCN-LI-L%.met
Calibration File: G:\Org\HP3\Cals\SC140226LI.CAL
Sample Weight: 1.05
Dilution: 2
S.A.: 1
Mean RF for C9 to C18 Hydrocarbons: 30979.57
Mean RF for C19 to C36 Hydrocarbons: 30994.75
Mean RF for Total Extractable Hydrocarbons: 30987.16
Rt range for Diesel Range Organics: 6.313 to 16.684
Rt range for C9 to C18 Hydrocarbons: 5.273 to 12.239
Rt range for C19 to C36 Hydrocarbons: 12.274 to 19.076
SURROGATE COMPOUND
RT
*o-Terphenyl_____________12.281
*1-Chloro-octadecane_____13.118
DRO Area:806888
TEH Area:1025795
C9-C18 Area:407861.7
C19-C36 Area:545454
ACTUAL
190.476
190.476
MEASURED
196.364
205.091
%REC
103.09
107.67
-
DRO Amount: 49.59892
TEH Amount: 63.05497
C9-C18 Amount: 25.07715
C19-C36 Amount: 33.52052
Page 22 of 25
QA/QC Summary Report
Prepared by Billings, MT Branch
Client:
NewFields
Report Date: 01/08/15
Project: Stimson
Result
Analyte
Method:
Work Order: B14122169
Units
RL %REC Low Limit High Limit
RPD RPDLimit
Batch: 85856
SW8082
Lab ID:
MB-85856
Aroclor 1016
Qual
Method Blank
Run: HECD.I_141231B
ND
ug/L
0.50
Aroclor 1221
ND
ug/L
0.50
Aroclor 1232
ND
ug/L
0.50
Aroclor 1242
Aroclor 1248
ND
ND
ug/L
ug/L
0.50
0.50
Aroclor 1254
ND
ug/L
0.50
Aroclor 1260
ND
ug/L
0.50
Aroclor 1262
ND
ug/L
0.50
Aroclor 1268
ND
ug/L
12/31/14 15:50
0.50
Surr: Decachlorobiphenyl
0.050
102
44
119
Surr: Tetrachloro-m-xylene
0.050
73
40
120
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Lab ID:
AR1254-85856
Aroclor 1254
Laboratory Control Sample
10.0
ug/L
Run: HECD.I_141231B
0.50
100
73
111
Surr: Decachlorobiphenyl
0.050
105
44
119
Surr: Tetrachloro-m-xylene
0.050
73
40
120
12/31/14 16:17
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Lab ID:
B14122169-008AMB
Aroclor 1254
Sample Matrix Spike
10.7
ug/L
Run: HECD.I_141231B
0.50
107
73
111
Surr: Decachlorobiphenyl
0.050
105
44
119
Surr: Tetrachloro-m-xylene
0.050
74
40
120
01/01/15 01:29
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Lab ID:
B14122169-008ADB
Aroclor 1254
Surr: Decachlorobiphenyl
Surr: Tetrachloro-m-xylene
Sample Matrix Spike Duplicate
9.98
ug/L
Run: HECD.I_141231B
0.50
0.050
100
103
73
44
111
119
0.050
67
40
120
01/01/15 01:55
7.0
40
- Sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Sulfur Clean-up (EPA Method 3660) prior to analysis.
Qualifiers:
RL - Analyte reporting limit.
ND - Not detected at the reporting limit.
Page 23 of 25
Workorder Receipt Checklist
NewFields
B14122169
Login completed by:
Randa Nees
Reviewed by:
BL2000\jmueller
Reviewed Date:
12/30/2014
Date Received: 12/30/2014
Received by: dlf
Carrier name: FedEx NDA
Shipping container/cooler in good condition?
Yes
No
Not Present
Custody seals intact on all shipping container(s)/cooler(s)?
Yes
No
Not Present
Custody seals intact on all sample bottles?
Yes
No
Not Present
Chain of custody present?
Yes
No
Chain of custody signed when relinquished and received?
Yes
No
Chain of custody agrees with sample labels?
Yes
No
Samples in proper container/bottle?
Yes
No
Sample containers intact?
Yes
No
Sufficient sample volume for indicated test?
Yes
No
All samples received within holding time?
(Exclude analyses that are considered field parameters
such as pH, DO, Res Cl, Sulfite, Ferrous Iron, etc.)
Yes
No
Temp Blank received in all shipping container(s)/cooler(s)?
Yes
No
Not Applicable
Container/Temp Blank temperature:
°C On Ice
Water - VOA vials have zero headspace?
Yes
No
No VOA vials submitted
Water - pH acceptable upon receipt?
Yes
No
Not Applicable
Standard Reporting Procedures:
Lab measurement of analytes considered field parameters that require analysis within 15 minutes of sampling such as
pH, Dissolved Oxygen and Residual Chlorine, are qualified as being analyzed outside of recommended holding time.
Solid/soil samples are reported on a wet weight basis (as received) unless specifically indicated. If moisture corrected,
data units are typically noted as –dry. For agricultural and mining soil parameters/characteristics, all samples are dried
and ground prior to sample analysis.
Contact and Corrective Action Comments:
Container temperature for Cooler 1 was 0.6°C, Cooler 2 was 2.2°C and Cooler 3 was 2.6°C.
Samples for PCBs taken on 12/22/14 are past the EPA holding time of 7 days, continue with analysis per phone call
with Tyler Etzel.
Page 24 of 25
Page 25 of 25