Tabella 05 - Polymer Technology Group

Parametri per l'equazione di Antoine ed altre proprietà
sat
Tensione di vapore ( P ) dall ’equazione di Antonie:
" P sat %
B
ln$
'= A(
T °C + C
# kPa &
Calore latente normale di evaporazione (H n ), temperatura normale di ebollizione (T n )
Parametri dell’!eq. di Antoine
Name
Acetone
Acetic acid
Acetonitrile
Ammonia
Benzene
iso-Butane
n-Butane
1-Butanol
2-Butanol
iso-Butanol
tert-Butanol
Carbon
tetrachloride
Chlorobenzene
1-Chlorobutane
Chloroform
Cyclohexane
Cyclopentane
n-Decane
Dichloromethane
Diethyl ether
1,4-Dioxane
n-Eicosane
Ethanol
Ethylbenzene
Ethylene glycol
n-Heptane
n-Hexane
Methanol
Methyl acetate
Methyl ethyl
ketone
Nitromethane
n-Nonane
iso-Octane
n-Octane
n-Pentane
Phenol
1-Propanol
2-Propanol
Toluene
Water
o-Xylene
m-Xylene
p-Xylene
Formula
A
B
C
Interv. di
temp
◦C
kJ/mol
◦C
C3H6O
C2H4O2
C2 H3 N
NH3
C6H6
C4H10
C4H10
C4H10O
C4H10O
C4H10O
C4H10O
14.3145
15.0717
14.2724
15.3671
13.7819
13.8254
13.6608
15.3144
15.1989
14.6047
14.8445
14.0572
2756.22
3580.80
2945.4
2308.83
2726.81
2181.79
2154.70
3212.43
3026.03
2740.95
2658.29
2914.23
228.060
224.650
224.010
247.885
217.572
248.870
238.789
182.739
186.500
166.670
177.650
232.148
−26 — 77
24 — 142
−13 — 117
−83 — 60
6 — 104
−83 — 7
−73 — 19
37 — 138
25 — 120
30 — 128
10 — 101
−14 — 101
29.10
23.70
30.19
23.36
30.72
21.30
22.44
43.29
40.75
41.82
39.07
29.82
56.2
117.9
81.6
-33.5
80.0
−11.9
−0.5
117.6
99.5
107.8
82.3
76.6
13.8635
13.7965
13.7324
13.6568
13.9727
13.9748
13.9891
14.0735
15.0967
14.4575
16.8958
13.9726
15.7567
13.8622
13.8193
16.5785
14.2456
14.1334
3174.78
2723.73
2548.74
2723.44
2653.90
3442.76
2463.93
2511.29
3579.78
4680.46
3795.17
3259.93
4187.46
2910.26
2696.04
3638.27
2662.78
2838.24
211.700
218.265
218.552
220.618
234.510
193.858
223.240
231.200
240.337
132.100
230.918
212.300
178.650
216.432
224.317
239.500
219.690
218.690
29 — 159
−17 — 79
−23 — 84
9 — 105
−35 — 71
65 — 203
−38 — 60
−43 — 55
20 — 105
208 — 379
3 — 96
33 — 163
100 — 222
4 — 123
−19 — 92
−11 — 83
−23 — 78
−8 — 103
35.19
30.39
29.24
29.97
27.30
38.75
28.06
26.52
34.16
57.49
38.56
35.57
50.73
31.77
28.85
35.21
30.32
31.30
131.7
78.5
61.1
80.7
49.2
174.1
39.7
34.4
101.3
343.6
78.2
136.2
197.3
98.4
68.7
64.7
56.9
79.6
14.7513
13.9854
13.6703
13.9346
13.7667
14.4387
16.1154
16.6796
13.9320
16.3872
14.0415
14.1387
14.0579
3331.70
3311.19
2896.31
3123.13
2451.88
3507.80
3483.67
3640.20
3056.96
3885.70
3358.79
3381.81
3331.45
227.600
202.694
220.767
209.635
232.014
175.400
205.807
219.610
217.625
230.170
212.041
216.120
214.627
56 — 146
46 — 178
2 — 125
26 — 152
−45 — 58
80 — 208
20 — 116
8 — 100
13 — 136
0 — 200
40 — 172
35 — 166
35 — 166
33.99
36.91
30.79
34.41
25.79
46.18
41.44
39.85
33.18
40.66
36.24
35.66
35.67
101.2
150.8
99.2
125.6
36.0
181.8
97.2
82.2
110.6
100.0
144.4
139.1
138.3
CCl4
C6H5Cl
C4H9Cl
CHCl3
C6H12
C5H10
C10H22
CH2Cl2
C4H10O
C4H8O2
C20H42
C2H6O
C8H10
C2H6 O2
C7H16
C6H14
CH4O
C3H6O2
C4H8O
CH3NO2
C9H20
C8H18
C8H18
C5H12
C6H6O
C3H8O
C3H8O
C7H8
H2 O
C8H10
C8H10
C8H10
Hn
Tn