APPENDICE I Proprietà critiche, fattori acentrici e costanti di Rackett
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APPENDICE I Proprietà critiche, fattori acentrici e costanti di Rackett
APPENDICE I Proprietà critiche, fattori acentrici e costanti di Rackett di alcune sostanze Sostanza Normal paraffine Metano Etano Propano n-Butano n-Pentano n-Esano n-Eptano n-Ottano n-Nonano n-Decano n-Undecano n-Dodecano n-Tridecano n-Tetradecano n-Pentadecano n-Esadecano n-Eptadecano n-Ottadecano n-Nonadecano n-Icosano Isomeri paraffinici 2-Metilpropano 2-Metilbutano 2,3-Dimetilbutano 2-Metilpentano 2,3-Dimetilpentano 2,3,3-Trimetilpentano 2,2,4-Trimetilpentano Olefine Etilene Propilene 1-Butene cis-2-Butene trans-2-Butene 1-Pentene 1-Esene 1-Eptene 1-Octene 1-Nonene 1-Decene 2-Metilpropene 2-Metil-1-butene 2-Metil-2-butene Formula ω ZRA 99 146 200 255 315 373 428 486 540 601 658 718 779 830 888 943 998 105.9 111.9 116.9 0.011 0.098 0.149 0.197 0.251 0.304 0.346 0.396 0.446 0.488 0.530 0.577 0.617 0.643 0.685 0.721 0.771 0.806 0.851 0.912 0.2892 0.2808 0.2766 0.2730 0.2684 0.2635 0.2604 0.2571 0.2543 0.2507 0.2499 0.2466 0.2473 35.73 33.26 30.89 29.81 28.42 27.73 25.27 261 304 358 366 396 455 465 0.177 0.226 0.246 0.279 0.292 0.289 0.301 0.2754 0.2717 0.2705 0.2672 0.2703 49.64 45.69 39.87 41.85 40.27 35.13 30.99 27.83 25.36 23.00 21.81 39.28 34.05 33.36 132 188 241 233 237 295 354 413 460 528 584 238 292 292 0.086 0.137 0.190 0.204 0.216 0.236 0.280 0.330 0.377 0.417 0.478 0.192 0.237 0.272 0.2815 0.2779 0.2736 0.2701 0.2720 0.2899 0.2658 0.2611 0.2600 0.2539 0.2546 Tc °C Pc atm cm3/mol Vc CH4 C2H6 C3H8 C4H10 C5H12 C6H14 C7H16 C8H18 C9H20 C10H22 C11H24 C12H26 C13H28 C14H30 C15H32 C16H34 C17H36 C18H38 C19H40 C20H42 -82.6 32.17 96.68 152.0 196.6 234.5 267.1 295.6 321.5 344.6 365.9 384.9 401.9 419.9 434.9 449.9 462.9 473.9 484.9 494.9 45.30 47.87 41.55 37.21 33.16 30.00 26.84 24.38 22.80 20.63 19.25 17.96 16.58 15.49 14.51 13.92 13.22 12.44 11.94 11.55 C4H10 C5H12 C6H14 C6H14 C7H16 C8H18 C8H18 135.0 187.3 226.9 224.4 264.2 300.4 270.8 C2H4 C3H6 C4H8 C4H8 C4H8 C5H10 C6H12 C7H14 C8H16 C9H18 C10H20 C4H8 C5H10 C5H10 9.190 92.42 146.8 162.4 155.5 191.6 230.9 264.1 293.5 320.1 343.3 144.8 191.9 197.9 0.2388 0.2343 0.2275 0.2236 0.2341 0.2739 0.2592 376 APPENDICE I – PROPRIETÀ CRITICHE E FATTORI ACENTRICI Sostanza ω ZRA 220 220 277 0.166 0.192 0.158 0.2675 0.2712 60.70 55.47 48.06 41.45 41.15 39.67 35.92 34.84 34.94 30.89 27.83 48.26 113 164 221 275 277 276 322 331 334 386 441 205 0.188 0.216 0.239 0.308 0.290 0.174 0.335 0.221 0.219 0.272 0.323 0.109 0.2709 0.2706 0.2693 238.6 259.6 296.4 280.4 299.0 336.0 233.9 268.9 287.2 44.41 37.31 33.56 40.46 34.34 30.00 47.47 40.76 43.33 257 319 374 308 368 430 245 303 291 0.196 0.230 0.271 0.212 0.236 0.246 0.196 0.232 0.216 0.2745 0.2711 C6H6 C7H8 C8H10 C8H10 C8H10 C8H10 C9H12 C9H12 C10H14 C10H8 C8H8 289.0 318.7 357.2 343.9 343.1 344.1 365.2 357.9 380.0 475.2 362.8 48.16 40.46 36.91 34.84 34.54 35.53 31.58 31.38 27.63 39.38 37.70 261 314 374 377 381 375 440 429 497 413 352 0.209 0.262 0.311 0.325 0.320 0.301 0.344 0.322 0.366 0.296 0.295 0.2698 0.2644 0.2620 0.2625 0.2592 CH4O C2H6O C3H8O C4H10O C4H10O C3H8O C4H10O C5H12O C5H12O C5H12O C6H14O 239.5 240.8 263.6 289.9 262.9 235.2 233.1 313.0 291.9 304.1 338.2 80.34 60.40 50.53 42.83 41.45 47.27 39.38 38.19 38.19 38.49 34.15 117 168 220 276 270 221 276 327 327 327 381 0.566 0.643 0.617 0.585 0.574 0.670 0.613 0.592 0.678 0.586 0.572 0.2334 0.2502 0.2541 0.2538 Tc °C Pc atm cm3/mol C4H6 C4H6 C5H8 178.9 152.0 210.9 43.03 42.44 38.00 Alchini Acetilene Metilacetilene Dimetilacetilene 3-Metil-1-butino 1-Pentino 2-Pentino 1-Esino 2-Esino 3-Esino 1-Eptin0 1-Ottino Vinilacetilene C2H2 C3H4 C4H6 C5H8 C5H8 C5H8 C6H10 C6H10 C6H10 C7H12 C8H14 C4H4 35.17 129.2 200.1 190.1 208.1 245.9 243.1 275.9 270.9 285.9 311.9 180.9 Idrocarburi ciclici Ciclopentano Metilciclopentano Etilciclopentano Cicloesano Metilcicloesano Etilcicloesano Ciclopentene 1-Metilciclopentene Cicloesene C5H10 C6H12 C7H14 C6H12 C7H14 C8H16 C5H8 C6H10 C6H10 Idrocarburi aromatici Benzene Toluene o-Xilene m-Xilene p-Xilene Etilbenzene Propilbenzene Isopropilbenzene p-Isopropiltoluene Naftalene Stirene Alcoli Metanolo Etanolo 1-Propanolo 1-Butanolo 2-Butanolo 2-Propanolo 2-Metil-2-propanolo 1-Pentanolo 2-Metil-1-butanolo 3-Metil-1-butanolo 1-Esanolo Dieni 1,2-Butadiene 1,3-Butadiene 2-Metil-1,3-butadiene Formula Vc 0.2729 0.2704 0.2599 0.2634 0.2493 0.2596 APPENDICE I – PROPRIETÀ CRITICHE E FATTORI ACENTRICI Sostanza Formula Tc °C Pc atm cm3/mol Vc 377 ω ZRA Fenoli Fenolo o-Cresolo m-Cresolo p-Cresolo C6H6O C7H8O C7H8O C7H8O 421.1 424.4 432.7 431.5 59.81 49.94 44.61 50.83 229 282 312 277 0.438 0.438 0.444 0.507 0.2780 Eteri Dimetil etere Metil etil etere Metil n-propil etere Metil isopropil etere Metil n-butil etere Dietil etere Etil propil etere Etil isopropil etere Metil fenil etere C2H6O C3H8O C4H10O C4H10O C5H12O C4H10O C5H12O C5H12O C7H8O 126.6 164.7 203.2 191.4 236.9 193.6 227.1 215.9 372.5 52.01 44.12 37.21 38.39 32.67 35.92 33.26 33.65 42.14 171 221 276 276 329 281 336 329 337 0.192 0.229 0.264 0.280 0.335 0.281 0.347 0.306 0.353 0.2742 0.2673 Composti carbonilici Formaldeide Acetaldeide Acetone Metil etil chetone 2-Pentanone Di isopropil chetone Cicloesanone Metil fenil chetone CH2O C2H4O C3H6O C4H8O C5H10O C7H14O C6H10O C8H8O 134.9 192.9 235.1 262.3 287.9 302.9 379.9 436.3 65.04 54.97 46.48 40.66 36.61 30.20 39.58 38.00 115 154 210 267 301 416 311 386 0.282 0.292 0.307 0.320 0.345 0.411 0.308 0.365 Sostanze inorganiche Elio* Idrogeno* Neon* Argon Fluoro Cloro Bromo Ossigeno Azoto Ammoniaca Idrazina Protossido di azoto Ossido di azoto Cianogeno Monossido di carbonio Anidride carbonica Solfuro di carbonio Acido fluoridrico Acido cloridrico Acido bromidrico Acido ciandirico Acido solfidrico Anidride solforosa Anidride solforica Acqua H2 Ne Ar F2 Cl2 Br2 O2 N2 NH3 N2H4 N2O NO C2N2 CO CO2 CS2 HF HCl HBr HCN H2S SO2 SO3 H2O -268 -240. -229. -122. -129. 144.0 311.0 -119. -147. 132.5 380.0 36.42 -93.0 127.0 -140. 31.06 278.9 188.0 51.50 90.00 183.5 100.4 157.6 217.7 374.0 2.245 13.03 26.35 48.36 51.02 76.88 101.5 49.54 33.46 111.5 145.4 71.85 64.35 58.62 34.44 72.93 79.35 64.05 82.51 83.49 52.80 88.82 77.57 80.83 216.5 58 64 42 75 67 124 135 74 89 72 158 98 58 195 95 95 160 69 82 100 139 99 123 127 56 -0.39 -0.21 -0.04 0.000 0.053 0.073 0.128 0.020 0.037 0.253 0.315 0.143 0.585 0.276 0.048 0.224 0.118 0.383 0.134 0.069 0.407 0.096 0.244 0.423 0.343 * nel caso della correlazione di Lyckman et al. porre ω = 0. 0.2269 0.2477 0.3060 0.3085 0.2922 0.2887 0.2767 0.2905 0.2900 0.2465 0.2640 0.2758 0.2896 0.2722 0.2808 0.1415 0.2653 0.2855 0.2661 0.2515 0.2338 APPENDICE II Correlazioni generalizzate di Lee-Kesler basate sul teorema degli stati corrispondenti a tre parametri ( Tr , Pr , ω ) Fattore di compressibilità: Z = Z (0) + ω ⋅ Z (1) Z (0) : per fluidi semplici Z (1) : deviazioni per fluidi normali (0) Entalpia residua: ∆H R RTc = ª¬ ∆H R RTc º¼ + ω ⋅ ª¬ ∆H R RTc º¼ (0) ª¬ ∆H R RTc º¼ : per fluidi semplici (1) ª¬ ∆H R RTc º¼ : deviazioni per fluidi normali (0) Entropia residua: ∆S R R = ª¬ ∆S R R º¼ + ω ⋅ ª¬ ∆S R R º¼ (1) (0) ª¬ ∆S R R º¼ : per fluidi semplici (1) ª¬ ∆S R R º¼ : deviazioni per fluidi normali Coefficiente di fugacità: log10 ϕ = [log10 ϕ ] + ω ⋅ [ log10 ϕ ] (0) [log10 ϕ ] : per fluidi semplici [log10 ϕ ] : deviazioni per fluidi normali (0) (1) (1) (1) 380 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di Z (0) Pr Tr 0.01 0.05 0.10 0.20 0.40 0.60 0.80 0.30 0.35 0.40 0.45 0.50 0.0029 0.0026 0.0024 0.0022 0.0021 0.0145 0.0130 0.0119 0.0110 0.0103 0.0290 0.0261 0.0239 0.0221 0.0207 0.0579 0.0522 0.0477 0.0442 0.0413 0.1158 0.1043 0.0953 0.0882 0.0825 0.1737 0.1564 0.1429 0.1322 0.1236 0.2315 0.2084 0.1904 0.1762 0.1647 0.55 0.60 0.65 0.70 0.75 0.9804 0.9849 0.9881 0.9904 0.9922 0.0098 0.0093 0.9377 0.9504 0.9598 0.0195 0.0186 0.0178 0.8958 0.9165 0.0390 0.0371 0.0356 0.0344 0.0336 0.0778 0.0741 0.0710 0.0687 0.0670 0.1166 0.1109 0.1063 0.1027 0.1001 0.1553 0.1476 0.1415 0.1366 0.1330 0.80 0.85 0.90 0.93 0.95 0.9935 0.9946 0.9954 0.9959 0.9961 0.9669 0.9725 0.9768 0.9790 0.9803 0.9319 0.9436 0.9528 0.9573 0.9600 0.8539 0.8810 0.9015 0.9115 0.9174 0.0661 0.0661 0.7800 0.8059 0.8206 0.0985 0.0983 0.1006 0.6635 0.6967 0.1307 0.1301 0.1321 0.1359 0.1410 0.97 0.98 0.99 1.00 1.01 0.9963 0.9965 0.9966 0.9967 0.9968 0.9815 0.9821 0.9826 0.9832 0.9837 0.9625 0.9637 0.9648 0.9659 0.9669 0.9227 0.9253 0.9277 0.9230 0.9222 0.8338 0.8398 0.8455 0.8509 0.8561 0.7240 0.7360 0.7471 0.7574 0.7671 0.5580 0.5887 0.6138 0.6353 0.6542 1.02 1.05 1.10 1.15 1.20 0.9969 0.9971 0.9975 0.9978 0.9981 0.9842 0.9855 0.9874 0.9891 0.9904 0.9679 0.9707 0.9747 0.9780 0.9808 0.9343 0.9401 0.9485 0.9554 0.9611 0.8610 0.8743 0.8930 0.9081 0.9205 0.7761 0.8002 0.8323 0.8576 0.8779 0.6710 0.7130 0.7649 0.8032 0.8330 1.30 1.40 1.50 1.60 1.70 0.9985 0.9988 0.9991 0.9993 0.9994 0.9926 0.9942 0.9954 0.9964 0.9971 0.9852 0.9884 0.9909 0.9928 0.9943 0.9702 0.9768 0.9818 0.9856 0.9886 0.9396 0.9534 0.9636 0.9714 0.9775 0.9083 0.9298 0.9456 0.9575 0.9667 0.8764 0.9062 0.9278 0.9439 0.9563 1.80 1.90 2.00 2.20 2.40 0.9995 0.9996 0.9997 0.9998 0.9999 0.9977 0.9982 0.9986 0.9992 0.9996 0.9955 0.9964 0.9972 0.9983 0.9991 0.9910 0.9929 0.9944 0.9967 0.9983 0.9823 0.9861 0.9892 0.9937 0.9969 0.9739 0.9796 0.9842 0.9910 0.9957 0.9659 0.9735 0.9796 0.9886 0.9948 2.60 2.80 3.00 3.50 4.00 1.0000 1.0000 1.0000 1.0001 1.0001 0.9998 1.0000 1.0002 1.0004 1.0005 0.9997 1.0001 1.0004 1.0008 1.0010 0.9994 1.0002 1.0008 1.0017 1.0021 0.9991 1.0007 1.0018 1.0035 1.0043 0.9990 1.0013 1.0030 1.0055 1.0066 0.9990 1.0021 1.0043 1.0075 1.0090 381 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di Z (0) Pr 1.00 1.20 1.50 2.00 3.00 5.00 7.00 10.0 0.2892 0.2604 0.2379 0.2200 0.2056 0.3470 0.3123 0.2853 0.2638 0.2465 0.4335 0.3901 0.3563 0.3294 0.3077 0.5775 0.5195 0.4744 0.4384 0.4092 0.8648 0.7775 0.7095 0.6551 0.6110 1.4366 1.2902 1.1758 1.0841 1.0094 2.0048 1.7987 1.6373 1.5077 1.4017 2.8507 2.5539 2.3211 2.1338 1.9801 0.1939 0.1842 0.1765 0.1703 0.1656 0.2323 0.2207 0.2113 0.2038 0.1981 0.2899 0.2753 0.2634 0.2538 0.2464 0.3853 0.3657 0.3495 0.3364 0.3260 0.5747 0.5446 0.5197 0.4991 0.4823 0.9475 0.8959 0.8526 0.8161 0.7854 1.3137 1.2398 1.1773 1.1241 1.0787 1.8520 1.7440 1.6519 1.5729 1.5047 0.1626 0.1614 0.1630 0.1664 0.1705 0.1942 0.1924 0.1935 0.1963 0.1998 0.2411 0.2382 0.2383 0.2405 0.2432 0.3182 0.3132 0.3114 0.3122 0.3138 0.4690 0.4591 0.4527 0.4507 0.4501 0.7598 0.7388 0.7220 0.7138 0.7092 1.0400 1.0071 0.9793 0.9648 0.9561 1.4456 1.3943 1.3496 1.3257 1.3108 0.1779 0.1844 0.1959 0.2901 0.4648 0.2055 0.2097 0.2154 0.2237 0.2370 0.2474 0.2503 0.2538 0.2583 0.2640 0.3164 0.3182 0.3204 0.3229 0.3260 0.4504 0.4508 0.4514 0.4522 0.4533 0.7052 0.7035 0.7018 0.7004 0.6991 0.9480 0.9442 0.9406 0.9372 0.9339 1.2968 1.2901 1.2835 1.2772 1.2710 0.5146 0.6026 0.6880 0.7443 0.7858 0.2629 0.4437 0.5984 0.6803 0.7363 0.2715 0.3131 0.4580 0.5798 0.6605 0.3297 0.3452 0.3953 0.4760 0.5605 0.4547 0.4604 0.4770 0.5042 0.5425 0.6980 0.6956 0.6950 0.6987 0.7069 0.9307 0.9222 0.9110 0.9033 0.8990 1.2650 1.2481 1.2232 1.2021 1.1844 0.8438 0.8827 0.9103 0.9308 0.9463 0.8111 0.8595 0.8933 0.9180 0.9367 0.7624 0.8256 0.8689 0.9000 0.9234 0.6908 0.7753 0.8328 0.8738 0.9043 0.6344 0.7202 0.7887 0.8410 0.8809 0.7358 0.7761 0.8200 0.8617 0.8984 0.8998 0.9112 0.9297 0.9518 0.9745 1.1580 1.1419 1.1339 1.1320 1.1343 0.9583 0.9678 0.9754 0.9865 0.9941 0.9511 0.9624 0.9715 0.9847 0.99436 0.9413 0.9552 0.9664 0.9826 0.9935 0.9275 0.9456 0.9599 0.9806 0.9945 0.9118 0.9359 0.9550 0.9827 1.0011 0.9297 0.9557 0.9772 0.0094 1.0313 0.9961 1.0157 1.0328 1.0600 1.0793 1.1391 1.1452 1.1516 1.1635 1.1728 0.9993 1.0031 1.0057 1.0097 1.0115 0.9998 1.0042 1.0074 1.0120 1.0140 1.0010 1.0063 1.0101 1.0156 1.0179 1.0040 1.0106 1.0153 1.0221 1.0249 1.0137 1.0223 1.0284 1.0368 1.0401 1.0463 1.0565 1.0635 1.0723 1.0747 1.0926 1.1016 1.1075 1.1138 1.1136 1.1792 1.1830 1.1848 1.1834 1.1773 382 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di Z (1) Pr Tr 0.01 0.05 0.10 0.20 0.40 0.60 0.80 0.30 0.35 0.40 0.45 0.50 -0.0008 -0.0009 -0.0010 -0.0009 -0.0009 -0.0040 -0.0046 -0.0048 -0.0047 -0.0045 -0.0081 -0.0093 -0.0095 -0.0094 -0.0090 -0.0161 -0.0185 -0.0190 -0.0187 -0.0181 -0.0040 -0.0046 -0.0048 -0.0047 -0.0045 -0.0323 -0.0370 -0.0380 -0.0374 -0.0360 -0.0484 -0.0554 -0.0570 -0.0560 -0.0539 0.55 0.60 0.65 0.70 0.75 -0.0314 -0.0205 -0.0137 -0.0093 -0.0064 -0.0043 -0.0041 -0.0772 -0.0507 -0.0339 -0.0086 -0.0082 -0.0078 -0.1161 -0.0744 -0.0172 -0.0164 -0.0156 -0.0148 -0.0143 -0.0343 -0.0326 -0.0309 -0.0294 -0.0282 -0.0513 -0.0487 -0.0461 -0.0438 -0.0417 -0.0682 -0.0646 -0.0611 -0.0579 -0.0550 0.80 0.85 0.90 0.93 0.95 -0.0044 -0.0029 -0.0019 -0.0015 -0.0012 -0.0228 -0.0152 -0.0487 -0.0319 -0.1160 -0.0715 -0.0272 -0.0268 -0.4201 -0.0391 -0.0526 -0.0509 -0.0099 -0.0075 -0.0062 -0.0205 -0.0154 -0.0126 -0.0442 -0.0326 -0.0262 -0.1118 -0.0763 -0.0589 -0.0396 -0.1662 -0.1110 -0.0503 -0.0514 -0.0540 0.97 0.98 0.99 1.00 1.01 -0.0010 -0.0009 -0.0008 -0.0007 -0.0006 -0.0050 -0.0044 -0.0039 -0.0034 -0.0030 -0.0101 -0.0090 -0.0079 -0.0069 -0.0060 -0.0208 -0.0184 -0.0161 -0.0140 -0.0120 -0.0450 -0.0390 -0.0335 -0.0285 -0.0240 -0.0770 -0.0641 -0.0531 -0.0435 -0.0351 -0.1647 -0.1100 -0.0796 -0.0588 -0.0429 1.02 1.05 1.10 1.15 1.20 -0.0005 -0.0003 -0.0000 0.0002 0.0004 -0.0026 -0.0015 0.0000 0.0011 0.0019 -0.0051 -0.0029 0.0001 0.0023 0.0040 -0.0102 -0.0054 0.0007 0.0052 0.0084 -0.0198 -0.0092 0.0038 0.0127 0.0190 -0.0277 -0.0097 0.0106 0.0237 0.0326 -0.0303 -0.0032 0.0236 0.0396 0.0499 1.30 1.40 1.50 1.60 1.70 0.0006 0.0007 0.0008 0.0008 0.0008 0.0030 0.0036 0.0039 0.0040 0.0040 0.0061 0.0072 0.0078 0.0080 0.0081 0.0125 0.0147 0.0158 0.0162 0.0163 0.0267 0.0306 0.0323 0.0330 0.0329 0.0429 0.0477 0.0497 0.0501 0.0497 0.0612 0.0661 0.0677 0.0677 0.0667 1.80 1.90 2.00 2.20 2.40 0.0008 0.0008 0.0008 0.0007 0.0007 0.0040 0.0040 0.0039 0.0037 0.0035 0.0081 0.0079 0.0078 0.0074 0.0070 0.0162 0.0159 0.0155 0.0147 0.0139 0.0325 0.0318 0.0310 0.0293 0.0276 0.0488 0.0477 0.0464 0.0437 0.0411 0.0652 0.0635 0.0617 0.0580 0.0544 2.60 2.80 3.00 3.50 4.00 0.0007 0.0006 0.0006 0.0005 0.0005 0.0033 0.0031 0.0029 0.0026 0.0023 0.0066 0.0062 0.0059 0.0052 0.0046 0.0131 0.0124 0.0117 0.0103 0.0091 0.0260 0.0245 0.0232 0.0204 0.0182 0.0387 0.0365 0.0345 0.0303 0.0270 0.0512 0.0483 0.0456 0.0401 0.0357 383 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di Z (1) Pr 1.00 1.20 1.50 2.00 3.00 5.00 7.00 10.0 -0.0806 0.0921 -0.0946 -0.0929 -0.0893 -0.0966 -0.1105 -0.1134 -0.1113 -0.1069 -0.1207 -0.1379 -0.1414 -0.1387 -0.1330 -0.1608 -0.1834 -0.1879 -0.1840 -0.1762 -0.2407 -0.2738 -0.2799 -0.2734 -0.2611 -0.3996 -0.4523 -0.4603 -0.4475 -0.4253 -0.5572 -0.6279 -0.6365 -0.6162 -0.5831 -0.7915 -0.8863 -0.8936 -0.8606 -0.8099 -0.0849 -0.0803 -0.0759 -0.0718 -0.0681 -0.1015 -0.0960 -0.0906 -0.0855 -0.0808 -0.1263 -0.1192 -0.1123 -0.1057 -0.0996 -0.1669 -0.1572 -0.1476 -0.1385 -0.1298 -0.2465 -0.2312 -0.2160 -0.2013 -0.1872 -0.3991 -0.3718 -0.3447 -0.3184 -0.2929 -0.5446 -0.5047 -0.4653 -0.4270 -0.3901 -0.7521 -0.6929 -0.6346 -0.5785 -0.5250 -0.0648 -0.0622 -0.0604 -0.0602 -0.0607 -0.0767 -0.0731 -0.0701 -0.0687 -0.0678 -0.0940 -0.0888 -0.0840 -0.0810 -0.0788 -0.1217 -0.1138 -0.1059 -0.1007 -0.0967 -0.1736 -0.1602 -0.1463 -0.1374 -0.1310 -0.2682 -0.2439 -0.2195 -0.2045 -0.1943 -0.3545 -0.3201 -0.2862 -0.2661 -0.2526 -0.4740 -0.4254 -0.3788 -0.3516 -0.3339 -0.0623 -0.0641 -0.0680 -0.0789 -0.0223 -0.0669 -0.0661 -0.0646 -0.0609 -0.0473 -0.0759 -0.0740 -0.0715 -0.0678 -0.0621 -0.0921 -0.0893 -0.0861 -0.0824 -0.0778 -0.1240 -0.1202 -0.1162 -0.1118 -0.1072 -0.1837 -0.1783 -0.1728 -0.1672 -0.1615 -0.2391 -0.2322 -0.2254 -0.2185 -0.2116 -0.3163 -0.3075 -0.2989 -0.2902 -0.2816 -0.0062 0.0220 0.0476 0.0625 0.0719 0.0227 0.1059 0.0897 0.0943 0.0991 -0.0524 0.0451 0.1630 0.1548 0.1477 -0.0722 -0.0432 0.0698 0.1667 0.1990 -0.1021 -0.0838 -0.0373 0.0332 0.1095 -0.1556 -0.1370 -0.1021 -0.0611 -0.0141 -0.2047 -0.1835 -0.1469 -0.1084 -0.0678 -0.2731 -0.2476 -0.2056 -0.1642 -0.1231 0.0819 0.0857 0.0864 0.0855 0.0838 0.1048 0.1063 0.1055 0.1035 0.1008 0.1420 0.1383 0.1345 0.1303 0.1259 0.1991 0.1894 0.1806 0.1729 0.1658 0.2079 0.2397 0.2433 0.2381 0.2305 0.0875 0.1737 0.2309 0.2631 0.2788 0.0176 0.1008 0.1717 0.2255 0.2628 -0.0423 0.0350 0.1058 0.1673 0.2179 0.0816 0.0792 0.0767 0.0719 0.0675 0.0978 0.0947 0.0916 0.0857 0.0803 0.1216 0.1173 0.1133 0.1057 0.0989 0.1593 0.1532 0.1476 0.1374 0.1285 0.2224 0.2144 0.2069 0.1932 0.1812 0.2846 0.2848 0.2820 0.2720 0.2602 0.2871 0.3017 0.3097 0.3135 0.3089 0.2576 0.2876 0.3096 0.3355 0.3459 0.0634 0.0598 0.0565 0.0497 0.0443 0.0754 0.0711 0.0672 0.0591 0.0527 0.0929 0.0876 0.0828 0.0728 0.0651 0.1207 0.1138 0.1076 0.0949 0.0849 0.1706 0.1613 0.1529 0.1356 0.1219 0.2484 0.2372 0.2268 0.2042 0.1857 0.3009 0.2915 0.2817 0.2584 0.2378 0.3475 0.3443 0.3385 0.3194 0.2994 384 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di − ª¬ ∆H R RTc º¼ (0) Pr Tr 0.01 0.05 0.10 0.20 0.40 0.60 0.80 0.30 0.35 0.40 0.45 0.50 6.045 5.906 5.763 5.615 5.465 6.045 5.906 5.906 5.906 5.906 6.045 5.901 5.757 5.609 5.459 6.034 5.895 5.751 5.603 5.453 6.022 5.882 5.738 5.590 5.440 6.011 5.870 5.726 5.577 5.427 5.999 5.858 5.713 5.564 5.414 0.55 0.60 0.65 0.70 0.75 0.032 0.027 0.023 0.020 0.017 5.312 5.162 0.118 0.101 0.088 5.309 5.159 5.008 0.213 0.183 5.303 5.153 5.002 4.848 4.687 5.290 5.141 5.991 4.838 4.679 5.278 5.129 4.980 4.828 4.672 5.265 5.116 4.968 4.818 4.664 0.80 0.85 0.90 0.93 0.95 0.015 0.014 0.012 0.011 0.011 0.078 0.069 0.062 0.058 0.056 0.160 0.141 0.126 0.118 0.113 0.345 0.300 0.264 0.246 0.235 4.507 4.309 0.596 0.545 0.516 4.504 4.313 4.074 0.960 0.885 4.499 4.316 4.094 3.920 3.763 0.97 0.98 0.99 1.00 1.01 0.011 0.010 0.010 0.010 0.010 0.054 0.053 0.052 0.051 0.050 0.109 0.107 0.105 0.103 0.101 0.225 0.221 0.216 0.212 0.208 0.490 0.478 0.466 0.455 0.445 0.824 0.797 0.773 0.750 0.728 1.356 1.273 1.206 1.151 1.102 1.02 1.05 1.10 1.15 1.20 0.010 0.009 0.008 0.008 0.007 0.049 0.046 0.042 0.039 0.036 0.099 0.094 0.086 0.079 0.073 0.203 0.192 0.175 0.160 0.148 0.434 0.407 0.367 0.334 0.305 0.708 0.654 0.581 0.523 0.474 1.060 0.955 0.827 0.732 0.657 1.30 1.40 1.50 1.60 1.70 0.006 0.005 0.005 0.004 0.004 0.031 0.027 0.024 0.021 0.019 0.063 0.055 0.048 0.043 0.038 0.127 0.110 0.097 0.086 0.076 0.259 0.224 0.196 0.173 0.153 0.399 0.341 0.297 0.261 0.231 0.545 0.463 0.400 0.350 0.309 1.80 1.90 2.00 2.20 2.40 0.003 0.003 0.003 0.002 0.002 0.017 0.015 0.014 0.012 0.010 0.034 0.031 0.028 0.023 0.019 0.068 0.062 0.056 0.046 0.038 0.137 0.123 0.111 0.092 0.076 0.206 0.185 0.167 0.137 0.114 0.275 0.246 0.222 0.182 0.150 2.60 2.80 3.00 3.50 4.00 0.002 0.001 0.001 0.001 0.000 0.008 0.007 0.006 0.004 0.002 0.016 0.014 0.011 0.007 0.005 0.032 0.027 0.023 0.015 0.009 0.064 0.054 0.045 0.029 0.017 0.095 0.080 0.067 0.043 0.026 0.125 0.105 0.088 0.056 0.033 385 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di − ª¬ ∆H R RTc º¼ (0) Pr 1.00 1.20 1.50 2.00 3.00 5.00 7.00 10.0 5.987 5.845 5.700 5.551 5.401 5.975 5.833 5.687 5.538 5.388 5.957 5.814 5.668 5.519 5.369 5.927 5.783 5.636 5.486 5.336 5.868 5.721 5.572 5.421 5.270 5.748 5.595 5.442 5.288 5.135 5.628 5.469 5.311 5.154 4.999 5.446 5.278 5.113 5.950 5.791 5.252 5.104 4.956 4.808 4.655 5.239 5.091 4.945 4.797 4.646 5.220 5.073 4.927 4.781 4.632 5.187 5.041 4.896 4.752 4.607 5.121 4.976 4.833 4.693 4.554 4.986 4.842 4.702 4.566 4.434 4.849 4.704 4.565 4.432 4.303 4.638 4.492 4.353 4.221 4.095 4.494 4.316 4.108 3.953 3.825 4.488 4.316 4.118 3.976 3.865 4.478 4.312 4.127 4.000 3.904 4.459 4.302 4.132 4.020 3.939 4.413 4.269 4.119 4.024 3.958 4.303 4.173 4.043 3.963 3.910 4.178 4.056 3.935 3.863 3.815 3.974 3.857 3.744 3.678 3.634 3.658 3.544 3.376 2.574 1.796 3.732 3.652 3.558 3.441 3.283 3.796 3.736 3.670 3.598 3.516 3.853 3.806 3.758 3.706 3.652 3.890 3.854 3.818 3.782 3.744 3.856 3.829 3.801 3.774 3.746 3.767 3.743 3.719 3.695 3.671 3.591 3.569 3.548 3.526 3.505 1.627 1.359 1.120 0.968 0.857 3.039 2.034 1.487 1.239 1.076 3.422 3.030 2.203 1.719 1.443 3.595 3.398 2.965 2.479 2.079 3.705 3.583 3.353 3.091 2.807 3.718 3.632 3.484 3.329 3.166 3.647 3.575 3.453 3.329 3.202 3.484 3.420 3.315 3.211 3.107 0.698 0.588 0.505 0.440 0.387 0.860 0.716 0.611 0.531 0.466 1.116 0.915 0.774 0.667 0.583 1.560 1.253 1.046 0.894 0.777 2.274 1.857 1.549 1.318 1.139 2.825 2.486 2.175 1.904 1.672 2.942 2.679 2.421 2.177 1.953 2.899 2.692 2.486 2.285 2.091 0.344 0.307 0.276 0.226 0.187 0.413 0.368 0.330 0.269 0.222 0.515 0.458 0.411 0.334 0.275 0.683 0.606 0.541 0.437 0.359 0.996 0.880 0.782 0.629 0.513 1.476 1.309 1.167 0.937 0.761 1.751 1.571 1.411 1.143 0.929 1.908 1.736 1.577 1.295 1.058 0.155 0.130 0.109 0.069 0.041 0.185 0.154 0.129 0.081 0.048 0.228 0.190 0.159 0.099 0.058 0.297 0.246 0.205 0.127 0.072 0.422 0.348 0.288 0.174 0.095 0.621 0.508 0.415 0.239 0.116 0.756 0.614 0.495 0.270 0.110 0.858 0.689 0.545 0.264 0.061 386 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di − ª¬ ∆H R RTc º¼ (1) Pr Tr 0.01 0.05 0.10 0.20 0.40 0.60 0.80 0.30 0.35 0.40 0.45 0.50 11.098 10.656 10.121 9.515 8.868 11.096 10.655 10.121 9.515 8.869 11.095 10.654 10.121 9.516 8.870 11.091 10.653 10.120 9.517 8.872 11.083 10.650 10.121 9.519 8.876 11.076 10.646 10.121 9.521 8.880 11.069 10.643 10.121 9.523 8.884 0.55 0.60 0.65 0.70 0.75 0.080 0.059 0.045 0.034 0.027 8.211 7.568 0.247 0.185 0.142 8.212 7.570 6.949 0.415 0.306 8.215 7.573 6.952 6.360 5.796 8.221 7.579 6.959 6.367 5.802 8.226 7.585 6.966 6.373 5.809 8.232 7.592 6.973 6.381 5.816 0.80 0.85 0.90 0.93 0.95 0.021 0.017 0.014 0.012 0.011 0.110 0.087 0.070 0.061 0.056 0.234 0.182 0.144 0.126 0.115 0.542 0.401 0.308 0.265 0.241 5.266 4.753 0.751 0.612 0.542 5.271 4.754 4.254 1.236 0.994 5.277 4.758 4.248 3.942 3.737 0.97 0.98 0.99 1.00 1.01 0.010 0.010 0.009 0.009 0.009 0.052 0.050 0.048 0.046 0.044 0.105 0.101 0.097 0.093 0.089 0.219 0.209 0.200 0.191 0.183 0.483 0.457 0.433 0.410 0.389 0.837 0.776 0.722 0.675 0.632 1.616 1.324 1.154 1.034 0.940 1.02 1.05 1.10 1.15 1.20 0.008 0.007 0.006 0.005 0.004 0.042 0.037 0.030 0.025 0.020 0.085 0.075 0.061 0.050 0.040 0.175 0.153 0.123 0.099 0.080 0.370 0.318 0.251 0.199 0.158 0.594 0.498 0.381 0.296 0.232 0.863 0.691 0.507 0.385 0.297 1.30 1.40 1.50 1.60 1.70 0.003 0.002 0.001 0.000 0.000 0.013 0.008 0.005 0.002 0.000 0.026 0.016 0.009 0.004 0.000 0.052 0.032 0.018 0.007 -0.000 0.100 0.060 0.032 0.012 -0.003 0.142 0.083 0.042 0.013 -0.009 0.177 0.100 0.048 0.011 -0.017 1.80 1.90 2.00 2.20 2.40 -0.000 -0.001 -0.001 -0.001 -0.001 -0.001 -0.003 -0.004 -0.005 -0.006 -0.003 -0.005 -0.007 -0.010 -0.012 -0.006 -0.011 -0.015 -0.020 -0.023 -0.015 -0.023 -0.030 -0.040 -0.047 -0.025 -0.037 -0.047 -0.062 -0.071 -0.037 -0.053 -0.065 -0.083 -0.095 2.60 2.80 3.00 3.50 4.00 -0.001 -0.001 -0.001 -0.002 -0.002 -0.006 -0.007 -0.007 -0.008 -0.008 -0.013 -0.014 -0.014 -0.016 -0.016 -0.026 -0.027 -0.029 -0.031 -0.032 -0.052 -0.055 -0.058 -0.062 -0.064 -0.078 -0.082 -0.086 -0.092 -0.096 -0.104 -0.110 -0.114 -0.122 -0.127 387 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di − ª¬ ∆H R RTc º¼ (1) Pr 1.00 1.20 1.50 2.00 3.00 5.00 7.00 10.0 11.062 10.640 10.121 9.525 8.888 11.055 10.637 10.121 9.527 8.892 11.044 10.632 10.121 9.531 8.899 11.027 10.624 10.122 9.537 8.809 10.992 10.609 10.123 9.549 8.932 10.935 10.581 10.128 9.576 8.978 10.872 10.554 10.135 9.611 9.030 10.781 10.529 10.150 9.663 9.111 8.238 7.598 6.980 6.388 5.824 8.243 7.605 6.987 6.396 5.832 8.252 7.615 6.999 6.408 5.845 8.266 7.632 7.018 6.430 5.868 8.296 7.668 7.059 6.475 5.918 8.359 7.744 7.147 6.573 6.027 8.426 7.825 7.239 6.677 6.141 8.531 7.950 7.383 6.837 6.317 5.285 4.763 4.249 3.934 3.713 5.292 4.771 4.255 3.937 3.713 5.306 4.784 4.268 3.951 3.730 5.330 4.810 4.298 3.987 3.773 5.384 4.871 4.371 4.073 3.873 5.506 5.008 4.530 4.251 4.068 5.632 5.149 4.688 4.422 4.248 5.824 5.358 4.916 4.662 4.498 3.471 3.332 3.164 2.382 1.375 3.467 3.327 3.164 2.952 2.595 3.492 3.363 3.222 3.065 2.880 3.551 3.434 3.313 3.186 3.051 3.670 3.568 3.464 3.358 3.251 3.886 3.795 3.705 3.615 3.525 4.077 3.992 3.908 3.825 3.743 4.336 4.257 4.178 4.100 4.023 1.180 0.877 0.617 0.459 0.349 1.723 0.878 0.673 0.503 0.381 2.650 1.496 0.617 0.487 0.381 2.906 2.381 1.261 0.604 0.361 3.142 2.800 2.167 1.497 0.934 3.435 3.167 2.720 2.275 1.840 3.660 3.418 3.023 2.641 2.273 3.947 3.722 3.362 3.019 2.692 0.203 0.111 0.049 0.005 -0.027 0.218 0.115 0.046 -0.004 -0.040 0.218 0.108 0.032 -0.023 -0.063 0.178 0.070 -0.008 -0.065 -0.109 0.300 0.044 -0.078 -0.151 -0.202 1.066 0.504 0.142 -0.082 -0.223 1.592 1.012 0.556 0.217 -0.028 2.086 1.547 1.080 0.689 0.369 -0.051 -0.070 -0.085 -0.106 -0.120 -0.067 -0.088 -0.105 -0.128 -0.144 -0.094 -0.117 -0.136 -0.163 -0.181 -0.143 -0.169 -0.190 -0.221 -0.242 -0.241 -0.271 -0.295 -0.331 -0.357 -0.317 -0.381 -0.428 -0.493 -0.535 -0.203 -0.330 -0.424 -0.551 -0.631 0.112 -0.092 -0.255 -0.489 -0.645 -0.130 -0.137 -0.142 -0.152 -0.158 -0.156 -0.164 -0.170 -0.181 -0.188 -0.194 -0.204 -0.211 -0.224 -0.233 -0.257 -0.269 -0.278 -0.294 -0.306 -0.376 -0.391 -0.403 -0.425 -0.442 -0.567 -0.591 -0.611 -0.650 -0.680 -0.687 -0.729 -0.763 -0.827 -0.874 -0.754 -0.836 -0.899 -1.015 -1.097 388 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di − ª¬ ∆S R R º¼ (0) Pr Tr 0.01 0.05 0.10 0.20 0.40 0.60 0.80 0.30 0.35 0.40 0.45 0.50 11.614 11.185 10.802 10.453 10.137 10.008 9.579 9.196 8.847 8.531 9.319 8.890 8.5061 8.157 8.841 8.635 8.205 7.821 7.472 7.156 7.961 7.529 7.144 6.794 6.479 7.574 7.140 6.755 6.404 6.089 7.304 6.869 6.483 6.132 5.816 0.55 0.60 0.65 0.70 0.75 0.038 0.029 0.023 0.018 0.015 8.245 7.983 0.122 0.096 0.078 7.555 7.294 7.052 0.206 0.164 6.870 6.610 6.368 6.140 5.917 6.193 5.933 5.694 5.467 5.248 5.803 5.544 5.306 5.082 4.866 5.531 5.273 5.036 4.814 4.600 0.80 0.85 0.90 0.93 0.95 0.013 0.011 0.009 0.008 0.008 0.064 0.054 0.046 0.042 0.039 0.134 0.111 0.094 0.085 0.080 0.294 0.239 0.199 0.179 0.168 5.026 4.785 0.463 0.408 0.377 4.649 4.418 4.145 0.750 0.671 4.388 4.166 3.912 3.723 3.556 0.97 0.98 0.99 1.00 1.01 0.007 0.007 0.007 0.007 0.007 0.037 0.036 0.035 0.034 0.033 0.075 0.073 0.071 0.069 0.067 0.157 0.153 0.148 0.144 0.139 0.350 0.337 0.326 0.315 0.304 0.607 0.580 0.555 0.532 0.510 1.056 0.971 0.903 0.847 0.799 1.02 1.05 1.10 1.15 1.20 0.006 0.006 0.005 0.005 0.004 0.032 0.030 0.026 0.023 0.021 0.065 0.060 0.053 0.047 0.042 0.135 0.124 0.108 0.096 0.085 0.294 0.267 0.230 0.201 0.177 0.491 0.439 0.371 0.319 0.277 0.757 0.656 0.537 0.452 0.389 1.30 1.40 1.50 1.60 1.70 0.003 0.003 0.002 0.002 0.002 0.017 0.014 0.011 0.010 0.008 0.033 0.027 0.023 0.019 0.017 0.068 0.056 0.046 0.039 0.033 0.140 0.114 0.094 0.079 0.067 0.217 0.174 0.143 0.120 0.102 0.298 0.237 0.194 0.162 0.137 1.80 1.90 2.00 2.20 2.40 0.001 0.001 0.001 0.001 0.001 0.007 0.006 0.006 0.004 0.004 0.014 0.013 0.011 0.009 0.007 0.029 0.025 0.022 0.018 0.014 0.058 0.051 0.044 0.035 0.028 0.088 0.076 0.067 0.053 0.042 0.117 0.102 0.089 0.070 0.056 2.60 2.80 3.00 3.50 4.00 0.001 0.000 0.000 0.000 0.000 0.003 0.002 0.002 0.001 0.001 0.006 0.005 0.004 0.003 0.002 0.012 0.010 0.008 0.006 0.004 0.023 0.020 0.017 0.012 0.009 0.035 0.029 0.025 0.017 0.013 0.046 0.039 0.033 0.023 0.017 389 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di − ª¬ ∆S R R º¼ (0) Pr 1.00 1.20 1.50 2.00 3.00 5.00 7.00 10.0 7.099 6.663 6.275 5.924 5.608 6.935 6.497 6.109 5.757 5.441 6.740 6.299 5.909 5.557 5.240 6.497 6.052 5.660 5.306 4.989 6.182 5.728 5.330 4.974 4.656 5.847 5.376 4.967 4.603 4.282 5.683 5.194 4.772 4.401 4.074 5.578 5.060 4.619 4.234 3.899 5.324 5.066 4.830 4.610 4.399 5.157 4.900 4.665 4.446 4.238 4.956 4.700 4.467 4.250 4.046 4.706 4.451 4.220 4.007 3.807 4.373 4.120 3.892 3.684 3.491 3.998 3.747 3.523 3.322 3.138 3.788 3.537 3.315 3.117 2.939 3.607 3.353 3.131 2.935 2.761 4.191 3.976 3.738 3.569 3.433 4.034 3.825 3.599 3.444 3.326 3.846 3.646 3.434 3.295 3.193 3.615 3.425 3.231 3.108 3.023 3.310 3.135 2.963 2.860 2.790 2.970 2.812 2.663 2.577 2.520 2.777 2.629 2.491 2.412 2.361 2.605 2.463 2.334 2.262 2.215 3.259 3.142 2.972 2.167 1.391 3.188 3.106 3.010 2.893 2.736 3.081 3.019 2.953 2.879 2.798 2.932 2.884 2.835 2.784 2.730 2.719 2.682 2.646 2.609 2.571 2.463 2.436 2.408 2.380 2.352 2.312 2.287 2.263 2.239 2.215 2.170 2.148 2.126 2.105 2.083 1.225 0.965 0.742 0.607 0.512 2.495 1.523 1.012 0.790 0.651 2.706 2.328 1.557 1.126 0.890 2.673 2.483 2.081 1.649 1.308 2.533 2.415 2.202 1.968 1.727 2.325 2.242 2.104 1.966 1.827 2.191 2.121 2.007 1.897 1.789 2.062 2.001 1.903 1.810 1.722 0.385 0.303 0.246 0.204 0.172 0.478 0.372 0.299 0.247 0.208 0.628 0.478 0.381 0.312 0.261 0.891 0.663 0.520 0.421 0.350 1.299 0.990 0.777 0.628 0.519 1.554 1.303 1.088 0.913 0.773 1.581 1.386 1.208 1.050 0.915 1.556 1.402 1.260 1.130 1.013 0.147 0.127 0.111 0.087 0.070 0.177 0.153 0.134 0.105 0.084 0.222 0.191 0.167 0.130 0.104 0.296 0.255 0.221 0.172 0.138 0.438 0.375 0.325 0.251 0.201 0.661 0.570 0.497 0.388 0.311 0.799 0.702 0.620 0.492 0.399 0.908 0.815 0.733 0.599 0.496 0.058 0.048 0.041 0.029 0.021 0.069 0.058 0.049 0.034 0.025 0.086 0.072 0.061 0.042 0.031 0.113 0.094 0.080 0.056 0.041 0.164 0.137 0.116 0.081 0.059 0.255 0.213 0.181 0.126 0.093 0.329 0.277 0.236 0.166 0.123 0.416 0.353 0.303 0.216 0.162 390 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di − ª¬ ∆S R R º¼ (1) Pr Tr 0.01 0.05 0.10 0.20 0.40 0.60 0.80 0.30 0.35 0.40 0.45 0.50 16.782 15.413 13.990 12.564 11.202 16.774 15.408 13.986 12.561 11.200 16.764 15.401 13.981 12.558 11.197 16.744 15.387 13.972 12.551 11.192 16.705 15.359 13.953 12.537 11.182 16.665 15.333 13.934 12.523 11.172 16.626 15.305 13.915 12.509 11.162 0.55 0.60 0.65 0.70 0.75 0.115 0.078 0.055 0.040 0.029 9.948 8.828 0.309 0.216 0.156 9.946 8.826 7.832 0.491 0.340 9.942 8.823 7.829 6.951 6.173 9.935 8.817 7.824 6.945 6.167 9.928 8.811 7.819 6.941 6.162 9.921 8.806 7.815 6.937 6.158 0.80 0.85 0.90 0.93 0.95 0.022 0.017 0.013 0.011 0.010 0.116 0.088 0.068 0.058 0.053 0.246 0.183 0.140 0.120 0.109 0.578 0.408 0.301 0.254 0.228 5.475 4.853 0.744 0.593 0.517 5.468 4.841 4.269 1.219 0.961 5.462 4.832 4.250 3.914 3.697 0.97 0.98 0.99 1.00 1.01 0.010 0.009 0.009 0.008 0.008 0.048 0.046 0.044 0.042 0.040 0.099 0.094 0.090 0.086 0.082 0.206 0.196 0.186 0.177 0.169 0.456 0.429 0.405 0.382 0.361 0.797 0.734 0.680 0.632 0.590 1.570 1.270 1.098 0.977 0.883 1.02 1.05 1.10 1.15 1.20 0.008 0.007 0.005 0.005 0.004 0.039 0.034 0.028 0.023 0.019 0.078 0.069 0.055 0.045 0.037 0.161 0.140 0.112 0.091 0.075 0.342 0.292 0.229 0.183 0.149 0.552 0.460 0.350 0.275 0.220 0.807 0.642 0.470 0.361 0.286 1.30 1.40 1.50 1.60 1.70 0.003 0.002 0.001 0.001 0.001 0.013 0.010 0.007 0.005 0.004 0.026 0.019 0.014 0.011 0.008 0.052 0.037 0.027 0.021 0.016 0.102 0.072 0.053 0.040 0.031 0.148 0.104 0.076 0.057 0.044 0.190 0.133 0.097 0.073 0.056 1.80 1.90 2.00 2.20 2.40 0.001 0.001 0.000 0.000 0.000 0.003 0.003 0.002 0.001 0.001 0.006 0.005 0.004 0.003 0.002 0.013 0.010 0.008 0.006 0.004 0.024 0.019 0.016 0.011 0.008 0.035 0.028 0.023 0.016 0.012 0.044 0.036 0.029 0.021 0.015 2.60 2.80 3.00 3.50 4.00 0.000 0.000 0.000 0.000 0.000 0.001 0.001 0.001 0.000 0.000 0.002 0.001 0.001 0.001 0.001 0.003 0.003 0.002 0.001 0.001 0.006 0.005 0.004 0.003 0.002 0.009 0.008 0.006 0.004 0.003 0.012 0.010 0.008 0.006 0.005 391 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di − ª¬ ∆S R R º¼ (1) Pr 1.00 1.20 1.50 2.00 3.00 5.00 7.00 10.0 16.586 15.278 13.896 12.496 11.153 16.547 15.251 13.877 12.482 11.143 16.488 15.211 13.849 12.462 11.129 16.390 15.144 13.803 12.430 11.107 16.195 15.011 13.714 12.367 11.063 15.837 14.751 13.541 12.248 10.985 15.468 14.496 13.376 12.145 10.920 14.925 14.153 13.144 11.999 10.836 9.914 8.800 7.810 6.933 6.155 9.907 8.795 7.807 6.930 6.152 9.897 8.788 7.801 6.926 6.149 9.881 8.777 7.794 6.922 6.146 9.853 8.759 7.784 6.919 6.149 9.806 8.735 7.778 6.928 6.174 9.770 8.723 7.785 6.952 6.213 9.732 8.720 7.811 7.002 6.285 5.458 4.826 4.238 3.893 3.658 5.455 4.822 4.232 3.885 3.647 5.452 4.820 4.230 3.883 3.648 5.452 4.822 4.236 3.896 3.669 5.461 4.839 4.267 3.941 3.728 5.501 4.898 4.351 4.046 3.851 5.555 4.969 4.442 4.151 3.966 5.648 5.083 4.578 4.300 4.125 3.406 3.264 3.093 2.311 1.306 3.391 3.247 3.082 2.868 2.513 3.401 3.268 3.126 2.967 2.784 3.437 3.318 3.195 3.067 2.933 3.517 3.412 3.306 3.200 3.094 3.661 3.569 3.477 3.387 3.297 3.788 3.701 3.616 3.532 3.450 3.957 3.875 3.795 3.717 3.640 1.113 0.820 0.577 0.437 0.343 1.655 0.831 0.640 0.489 0.385 2.557 1.443 0.618 0.502 0.412 2.790 2.283 1.241 0.654 0.447 2.986 2.655 2.067 1.471 0.991 3.209 2.949 2.534 2.138 1.767 3.369 3.134 2.767 2.428 2.115 3.565 3.348 3.013 2.708 2.430 0.226 0.158 0.115 0.086 0.067 0.254 0.178 0.130 0.098 0.076 0.282 0.200 0.147 0.112 0.087 0.300 0.220 0.166 0.129 0.102 0.481 0.290 0.206 0.159 0.127 1.147 0.730 0.479 0.334 0.248 1.569 1.138 0.823 0.604 0.456 1.944 1.544 1.222 0.969 0.775 0.053 0.043 0.035 0.025 0.019 0.060 0.049 0.040 0.029 0.022 0.070 0.057 0.048 0.035 0.027 0.083 0.069 0.058 0.043 0.034 0.105 0.089 0.077 0.060 0.048 0.195 0.160 0.136 0.105 0.086 0.355 0.286 0.238 0.178 0.142 0.628 0.518 0.434 0.322 0.254 0.015 0.012 0.010 0.007 0.006 0.018 0.014 0.012 0.009 0.007 0.021 0.018 0.015 0.011 0.009 0.028 0.023 0.020 0.015 0.012 0.041 0.035 0.031 0.024 0.020 0.074 0.065 0.058 0.046 0.038 0.120 0.104 0.093 0.073 0.060 0.210 0.180 0.158 0.122 0.100 392 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di [ log10 ϕ ] (0) Pr Tr 0.01 0.05 0.10 0.20 0.40 0.60 0.80 0.30 0.35 0.40 0.45 0.50 -3.708 -2.471 -1.566 -0.879 -0.344 -4.402 -3.166 -2.261 -1.575 -1.040 -4.696 -3.461 -2.557 -1.871 -1.336 -4.985 -3.751 -2.848 -2.162 -1.628 -5.261 -4.029 -3.128 -2.444 -1.912 -5.412 -4.183 -3.283 -2.601 -1.070 -5.512 -4.285 -3.387 -2.707 -1.177 0.55 0.60 0.65 0.70 0.75 -0.008 -0.007 -0.005 -0.004 -0.003 -0.614 -0.269 -0.026 -0.021 -0.017 -0.911 -0.566 -0.283 -0.043 -0.035 -1.204 -0.859 -0.576 -0.341 -0.144 -1.488 -1.144 -0.862 -0.627 -0.430 -1.647 -1.304 -1.023 -0.789 -0.592 -1.755 -1.413 -1.132 -0.899 -0.703 0.80 0.85 0.90 0.93 0.95 -0.003 -0.002 -0.002 -0.002 -0.002 -0.014 -0.012 -0.010 -0.009 -0.008 -0.029 -0.024 -0.020 -0.018 -0.017 -0.059 -0.049 -0.041 -0.037 -0.035 -0.264 -0.123 -0.086 -0.077 -0.072 -0.426 -0.285 -0.166 -0.122 -0.113 -0.537 -0.396 -0.276 -0.214 -0.176 0.97 0.98 0.99 1.00 1.01 -0.002 -0.002 -0.001 -0.001 -0.001 -0.008 -0.008 -0.007 -0.007 -0.007 -0.016 -0.016 -0.015 -0.015 -0.014 -0.033 -0.032 -0.031 -0.030 -0.029 -0.067 -0.065 -0.063 -0.061 -0.059 -0.105 -0.101 -0.098 -0.095 -0.091 -0.148 -0.142 -0.137 -0.132 -0.127 1.02 1.05 1.10 1.15 1.20 -0.001 -0.001 -0.001 -0.001 -0.001 -0.007 -0.006 -0.005 -0.005 -0.004 -0.014 -0.013 -0.011 -0.009 -0.008 -0.028 -0.025 -0.022 -0.019 -0.017 -0.057 -0.052 -0.045 -0.039 -0.034 -0.088 -0.080 -0.069 -0.059 -0.051 -0.122 -0.110 -0.093 -0.080 -0.069 1.30 1.40 1.50 1.60 1.70 -0.001 -0.001 -0.000 -0.000 -0.000 -0.003 -0.003 -0.002 -0.002 -0.001 -0.006 -0.005 -0.004 -0.003 -0.002 -0.013 -0.010 -0.008 -0.006 -0.005 -0.026 -0.020 -0.016 -0.012 -0.010 -0.039 -0.030 -0.024 -0.019 -0.015 -0.052 -0.040 -0.032 -0.025 -0.020 1.80 1.90 2.00 2.20 2.40 -0.000 -0.000 -0.000 -0.000 -0.000 -0.001 -0.001 -0.001 -0.000 -0.000 -0.002 -0.002 -0.001 -0.001 -0.000 -0.004 -0.003 -0.002 -0.001 -0.001 -0.008 -0.006 -0.005 -0.003 -0.001 -0.012 -0.009 -0.007 -0.004 -0.002 -0.015 -0.012 -0.009 -0.005 -0.003 2.60 2.80 3.00 3.50 4.00 -0.000 0.000 0.000 0.000 0.000 -0.000 0.000 0.000 0.000 0.000 -0.000 0.000 0.000 0.000 0.000 -0.000 0.000 0.000 0.001 0.001 -0.000 0.000 0.001 0.001 0.002 -0.001 0.000 0.001 0.002 0.003 -0.001 0.001 0.002 0.003 0.004 393 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di [ log10 ϕ ] (0) Pr 1.00 1.20 1.50 2.00 3.00 5.00 7.00 10.0 -5.584 -4.359 -3.463 -2.785 -2.256 -5.638 -4.416 -3.522 -2.845 -2.317 -5.697 -4.479 -3.588 -2.913 -2.387 -5.759 -4.547 -3.661 -2.990 -2.468 -5.810 -4.611 -3.735 -3.071 -2.555 -5.782 -4.608 -3.752 -3.104 -2.601 -5.679 -4.530 -3.694 -3.063 -2.572 -5.461 -4.352 -3.545 -2.938 -2.468 -1.835 -1.494 -1.214 -0.981 -0.785 -1.897 -1.557 -1.278 -1.045 -0.850 -1.969 -1.630 -1.352 -1.120 -0.925 -2.052 -1.715 -1.439 -1.208 -1.015 -2.145 -1.812 -1.539 -1.312 -1.121 -2.201 -1.878 -1.612 -1.391 -1.204 -2.183 -1.869 -1.611 -1.396 -1.215 -2.095 -1.795 -1.549 -1.344 -1.172 -0.619 -0.479 -0.359 -0.296 -0.258 -0.684 -0.544 -0.424 -0.361 -0.322 -0.760 -0.620 -0.500 -0.437 -0.398 -0.851 -0.711 -0.591 -0.527 -0.488 -0.958 -0.820 -0.700 -0.637 -0.598 -1.046 -0.911 -0.794 -0.732 -0.693 -1.062 -0.930 -0.817 -0.756 -0.719 -1.026 -0.901 -0.793 -0.735 -0.699 -0.223 -0.206 -0.191 -0.176 -0.168 -0.287 -0.270 -0.254 -0.238 -0.224 -0.362 -0.344 -0.328 -0.312 -0.297 -0.452 -0.434 -0.417 -0.401 -0.385 -0.561 -0.543 -0.526 -0.509 -0.493 -0.657 -0.639 -0.622 -0.605 -0.589 -0.683 -0.666 -0.649 -0.633 -0.617 -0.665 -0.649 -0.633 -0.617 -0.602 -0.161 -0.143 -0.120 -0.102 -0.088 -0.210 -0.180 -0.148 -0.125 -0.106 -0.282 -0.242 -0.193 -0.160 -0.135 -0.370 -0.327 -0.267 -0.220 -0.184 -0.477 -0.433 -0.368 -0.312 -0.266 -0.573 -0.529 -0.462 -0.403 -0.352 -0.601 -0.557 -0.491 -0.433 -0.382 -0.588 -0.546 -0.482 -0.426 -0.377 -0.066 -0.051 -0.039 -0.031 -0.024 -0.080 -0.061 -0.047 -0.037 -0.029 -0.100 -0.076 -0.059 -0.046 -0.036 -0.134 -0.101 -0.077 -0.060 -0.046 -0.195 -0.146 -0.111 -0.085 -0.065 -0.269 -0.205 -0.157 -0.120 -0.092 -0.296 -0.229 -0.176 -0.135 -0.102 -0.293 -0.226 -0.173 -0.129 -0.094 -0.019 -0.015 -0.012 -0.007 -0.003 -0.023 -0.018 -0.014 -0.008 -0.004 -0.028 -0.022 -0.017 -0.009 -0.004 -0.036 -0.028 -0.021 -0.012 -0.005 -0.050 -0.038 -0.029 -0.015 -0.006 -0.069 -0.052 -0.037 -0.017 -0.003 -0.075 -0.054 -0.037 -0.012 0.005 -0.066 -0.043 -0.024 0.004 0.024 -0.001 0.001 0.002 0.004 0.005 -0.001 0.001 0.003 0.005 0.006 -0.001 0.002 0.003 0.006 0.007 -0.001 0.003 0.005 0.008 0.010 0.001 0.005 0.009 0.013 0.016 0.007 0.014 0.018 0.025 0.028 0.017 0.025 0.031 0.038 0.041 0.037 0.046 0.053 0.061 0.064 394 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di [ log10 ϕ ] (1) Pr Tr 0.01 0.05 0.10 0.20 0.40 0.60 0.80 0.30 0.35 0.40 0.45 0.50 16.782 15.413 13.990 12.564 11.202 16.774 15.408 13.986 12.561 11.200 16.764 15.401 13.981 12.558 11.197 16.744 15.387 13.972 12.551 11.192 16.705 15.359 13.953 12.537 11.182 16.665 15.333 13.934 12.523 11.172 16.626 15.305 13.915 12.509 11.162 0.55 0.60 0.65 0.70 0.75 -0.013 -0.009 -0.006 -0.004 -0.003 -2.163 -1.644 -0.031 -0.021 -0.014 -2.165 -1.646 -1.242 -0.044 -0.030 -2.1698 -1.6505 -1.245 -0.927 -0.675 -2.177 -1.657 -1.252 -0.934 -0.682 -2.184 -1.664 -1.258 -0.940 -0.688 -2.192 -1.671 -1.265 -0.946 -0.694 0.80 0.85 0.90 0.93 0.95 -0.002 -0.001 -0.001 -0.001 -0.001 -0.010 -0.006 -0.004 -0.003 -0.003 -0.020 -0.013 -0.009 -0.007 -0.005 -0.043 -0.028 -0.018 -0.013 -0.011 -0.481 -0.321 -0.039 -0.029 -0.023 -0.487 -0.327 -0.199 -0.048 -0.037 -0.493 -0.332 -0.204 -0.141 -0.103 0.97 0.98 0.99 1.00 1.01 -0.000 -0.000 -0.000 -0.000 -0.000 -0.002 -0.002 -0.002 -0.001 -0.001 -0.004 -0.004 -0.003 -0.003 -0.003 -0.009 -0.008 -0.007 -0.006 -0.005 -0.018 -0.016 -0.014 -0.012 -0.010 -0.029 -0.025 -0.021 -0.018 -0.016 -0.042 -0.035 -0.030 -0.025 -0.021 1.02 1.05 1.10 1.15 1.20 -0.000 -0.000 -0.000 0.000 0.000 -0.001 -0.001 -0.000 0.000 0.001 -0.002 -0.001 0.000 0.001 0.002 -0.004 -0.002 0.000 0.002 0.003 -0.009 -0.005 0.001 0.005 0.007 -0.013 -0.006 0.002 0.008 0.012 -0.017 -0.007 0.004 0.011 0.017 1.30 1.40 1.50 1.60 1.70 0.000 0.000 0.000 0.000 0.000 0.001 0.002 0.002 0.002 0.002 0.003 0.003 0.003 0.003 0.004 0.005 0.006 0.007 0.007 0.007 0.011 0.013 0.014 0.014 0.014 0.017 0.020 0.021 0.021 0.021 0.023 0.027 0.028 0.029 0.029 1.80 1.90 2.00 2.20 2.40 0.000 0.000 0.000 0.000 0.000 0.002 0.002 0.002 0.002 0.002 0.003 0.003 0.003 0.003 0.003 0.007 0.007 0.007 0.006 0.006 0.014 0.014 0.013 0.013 0.012 0.021 0.021 0.020 0.019 0.018 0.028 0.028 0.027 0.025 0.024 2.60 2.80 3.00 3.50 4.00 0.000 0.000 0.000 0.000 0.000 0.001 0.001 0.001 0.001 0.001 0.003 0.003 0.003 0.002 0.002 0.006 0.005 0.005 0.004 0.004 0.011 0.011 0.010 0.009 0.008 0.017 0.016 0.015 0.013 0.012 0.023 0.021 0.020 0.018 0.016 395 APPENDICE II – CORRELAZIONI GENERALIZZATE Valori di [ log10 ϕ ] (1) Pr 1.00 1.20 1.50 2.00 3.00 5.00 7.00 10.0 -8.811 -6.567 -4.954 -3.766 -2.877 -8.818 -6.575 -4.962 -3.774 -2.884 -8.828 -6.587 -4.974 -3.786 -2.896 -8.845 -6.606 -4.995 -3.806 -2.915 -8.880 -6.645 -5.035 -3.845 -2.953 -8.953 -6.723 -5.115 -3.923 -3.027 -9.022 -6.800 -5.195 -4.001 -3.101 -9.126 -6.919 -5.312 -4.114 -3.208 -2.199 -1.678 -1.272 -0.952 -0.700 -2.207 -1.685 -1.278 -0.959 -0.705 -2.218 -1.695 -1.288 -0.968 -0.714 -2.236 -1.712 -1.304 -0.983 -0.728 -2.272 -1.746 -1.336 -1.013 -0.756 -2.342 -1.812 -1.397 -1.069 -0.809 -2.411 -1.875 -1.456 -1.123 -0.858 -2.510 -1.967 -1.540 -1.201 -0.929 -0.498 -0.338 -0.210 -0.146 -0.108 -0.504 -0.343 -0.215 -0.151 -0.114 -0.512 -0.351 -0.222 -0.158 -0.121 -0.526 -0.364 -0.234 -0.170 -0.132 -0.551 -0.388 -0.256 -0.191 -0.151 -0.600 -0.432 -0.296 -0.228 -0.187 -0.645 -0.473 -0.333 -0.262 -0.219 -0.709 -0.530 -0.384 -0.310 -0.265 -0.075 -0.059 -0.044 -0.031 -0.024 -0.080 -0.064 -0.050 -0.036 -0.024 -0.087 -0.071 -0.056 -0.042 -0.030 -0.097 -0.081 -0.066 -0.052 -0.038 -0.116 -0.099 -0.084 -0.069 -0.054 -0.150 -0.132 -0.115 -0.099 -0.084 -0.180 -0.162 -0.144 -0.127 -0.111 -0.223 -0.203 -0.184 -0.166 -0.149 -0.019 -0.007 0.007 0.016 0.023 -0.015 -0.002 0.012 0.022 0.029 -0.018 0.008 0.025 0.034 0.041 -0.026 0.007 0.041 0.056 0.064 -0.041 -0.005 0.042 0.074 0.093 -0.069 -0.029 0.026 0.069 0.102 -0.095 -0.052 0.008 0.057 0.096 -0.132 -0.085 -0.019 0.036 0.081 0.030 0.034 0.036 0.036 0.036 0.038 0.041 0.043 0.043 0.043 0.049 0.053 0.055 0.055 0.054 0.071 0.074 0.074 0.074 0.072 0.109 0.112 0.112 0.110 0.107 0.142 0.161 0.167 0.167 0.165 0.150 0.181 0.197 0.204 0.205 0.148 0.191 0.218 0.234 0.242 0.035 0.034 0.034 0.032 0.030 0.042 0.041 0.040 0.038 0.036 0.053 0.052 0.050 0.047 0.044 0.070 0.068 0.066 0.062 0.058 0.104 0.101 0.097 0.091 0.086 0.161 0.157 0.152 0.143 0.134 0.203 0.200 0.196 0.186 0.176 0.246 0.246 0.244 0.236 0.227 0.028 0.027 0.025 0.022 0.020 0.034 0.032 0.030 0.026 0.023 0.042 0.039 0.037 0.033 0.029 0.055 0.052 0.049 0.043 0.038 0.080 0.076 0.072 0.063 0.057 0.127 0.120 0.114 0.101 0.090 0.167 0.158 0.151 0.134 0.121 0.217 0.208 0.199 0.179 0.163